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topic 43365 p2

Hot dip galvanizing flux Q & A's, Problems and Solutions

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A discussion started in 2006 & continuing through 2017

July 11, 2012

Q. We have a continuous steel wire galvanizing line here in Kampala, Uganda.We are facing the following problems:
High dross formation and An acid flux bath.
We try to neutralize the flux bath by adding an ammonium solution but the rate of con termination is high.
Yes we have a rinse tank but still its not enough!
Sir, what is your advise on the above?

Collins Wasswa
- Kampala, Uganda

July 18, 2012

A. Collins:

Are you "wet" or "dry" kettle? What is too high of rate of dross? How long do your kettles last?


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

September 23, 2012

Q. Dear Dr. Cook:
I have a serious problem with bare spot because of Chinese raw material. I produce steel tower angle and plate, our flux is double salt acn 0.8 and fe+2, 0.28%, so, my supervisor tries to solve the bare spot problem by brushing the angles with ammonium chloride solution for 45 minutes, then immersing in zinc kettle. The result became okay but as per my little experience the dross will increase too much. I read an article before that every additional gm of ammonium chloride causes 20 gm of dross, is it right or not? And what's the side effects of doing it my supervisor's way?

Ahmed Hassan
technical manager - Yingkou Anshan China

simultaneous September 25, 2012

A. Sir:

Your English is excellent.

It is NOT true that 1 gram of ammonium chloride in the flux gives 20 grams of dross at the kettle.

Your question reminds me of my work 40 years ago and for this I feel badly for you. Properly formulated, tested, and used, quadraflux does an excellent and extremely effective job of galvanizing your types of steel (assuming the pickling is good). Unfortunately there are some extremely bad inhibitors in the market place that prevents proper pickling. I do have a good article in the journal titled Metal Finishing. The name of this article is something like: "Testing, Control, and Use of Hot Dip Galvanizing Flux." I looked for a copy here at home and was not able to find it to properly reference it, sorry. This website has a search engine and I have made many replies to questions like yours. So please search this website and the general web via Google.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

September 25, 2012

A. Dear Ahmed;

Is your kettle dry or wet? In dry applications, excess ammonium chloride will have no effect, just extra fumes.

Why don't you try using sandblasting -- would be quicker and cheaper.

- Ankara, TURKEY

September 26, 2012

Q. Hi Ozge,
Sorry, I forget to tell you that our kettle is dry and we have preflux double salt with temperature 50 °C and in our kettle we never use lead; we can use nickel and aluminum and bismuth alloys.
And I have good friends in Turkey, Mrs. Isik Spaci. They are good galvanizing consultant.

Ahmed Hassan
- Liaoning, China

September 26, 2012

Q. Dear Dr. Cook /Mr. Ozge.
Thanks a lot for your kind support.
1st, I suggested the shot grit blasting since the sand blasting will increase the silica in the degreasing and pickling.
Regarding the ammonium chloride, does it really only cause white fumes, or increase the dross & ash also?
Also, I think that one mole or gram from iron gives you 25 mole or grams. Am I right?
Dr. Cook, you kindly suggested me to use quadraflux, can you give me the best specifications (composition ratios, pH, temperature, etc.] Please advise.


Ahmed Hassan
- Liaoning, China

simultaneous September 27, 2012

A. Sir:

Quadraflux is 1.6 parts ammonium chloride and 1 part zinc chloride. Best baumé is 13. Best pH is 4.2. Best temperature of flux solution is 71 °C. Keep product in flux solution about 3 to 5 minutes to heat fully the steel. Take out steel and lay at an angle to promote drainage. Drying should be done within a few minutes. Fluxed steel should enter kettle with little spatter. Faster entry is best. Slower withdrawal is usually best.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

September 28, 2012

A. Dear Ahmed;

I will give Mrs. Sapci your compliments at our next meeting.

Ammonium chloride will cause increase in white fuming. Double salts are always "fumeless" but as triple (ZnCl2.3NH4Cl) or quadraflux (ZnCl2.4NH4Cl) would have higher fuming. You might also try to sprinkle ammonium chloride powder before you dip into zinc. This is very old application, causes heavy fuming but best option for poor pickled parts. It won't affect your dross and ash formation, but will cause drop in aluminum content (especially if your kettle is small).

Also you might try to agitate your acids strongly or heat them over 35 degrees. This would give better pickling.

One more option; dip your products by normal procedure, immerse, withdraw, dip into flux again without cooling, re-galvanize. I used to do it a lot with angles, I-U beams, which have very poor steel quality. But of course coating thickness will exceed 150 microns.

Dross is 96% zinc and 4% iron. Thus we can say 1 gram of iron will produce 25 gram of dross. But actually this doesn't mean that every 1 gram of excess iron will result in that much dross. Some will dissolve in zinc (if your nickel is high this solubility will be less) some will oxidize while immersing, (zinc ash may have 3% iron) etc. The rest will form dross.

Quadraflux is ZnCl2.4NH4Cl. Best ideal pH range is 4-4.5 (best will be 4.2) - use titration method, pH meters are rubbish -- and ideal Temperature would be 60-65 degrees.

- Ankara, TURKEY

September 29, 2012

A. Ozge:

35 °C (95 ° F) is too hot to heat 17% HCl. The fumes will destroy the roof and the building, which will happen anyway if a good inhibitor at the right concentration is not used.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

October 2, 2012

A. Dear Mr. Cook;

Of course I am assuming inhibitor, good ventilation system and moreover an enclosed pretreatment unit. Thanks for mentioning about all these.

galvanizer - Ankara, TURKEY

October 2, 2012

A. Sir:

HCl is a gas which is heavier than air. It fills a galvanizing plant from the floor upward. This gas along with water vapor is terribly corrosive. I have seen steel corrosion in warmer climates for areas around a galvanizing plant corrode to orange black dust over the years. The best HCl fume control that I saw exhausts the HCl gas down through the floor. Simply put the best HCl temperature range in my experiences is between 70 and 85 °F. Above 85 °F the workers and the cranes suffer.

From which country do you purchase your HCl inhibitor and at what concentration do you use it? Also do you test its effectiveness in the HCl pickle tank?


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

simultaneous October 4, 2012

A. Dear Dr. Cook;

I know all these. Because of all things you mentioned, we have good ventilation system that is sucking and blowing air 10 cm below the acid bath top edge. Thus, all acid fumes are sucked and sent to treatment unit. I guess it is forbidden to give brand name but we use an Italian famous brand, which has 2 additives (inhibitor and anti vapor). Also our environmental advisors regularly measure the acidity in the air and reports that it is very low. And also you can notice little smell, even standing in front of a fresh acid.

Even I don't usually exceed 30 °C (guess it is like 85 °F) , but in extreme cases exceeding this value does not cause problems for us.

galvanizing - Ankara, TURKEY

October 4, 2012

A. There's a lot to be said about having a good inhibitor, as Tom has said.
There are some that prevent proper pickling.
There are some that do nothing useful.
There are only a few that do what you really want them to do - allow the dissolving of oxides of iron while preventing dissolving steel.

HCl fume is an issue, dependent of temp and concentration.
In "sunny" Scotland the temperature is not much of a problem. I remember one year breaking the ice on the surface of one pickle tank!

Geoff Crowley
Geoff Crowley
galvanizing & powder coating shop
Glasgow, Scotland

October 5, 2012

Q. Dear Geoff;

Do you mind if I ask about your average pickling time during "winter" (for fresh acid and for 30 baumé)?

galvanizer - Ankara, TURKEY

October 6, 2012

A. Ozge,

You answered my question of where you get your inhibitor EXACTLY AS I EXPECTED. Regarding this supplier I respond "NO COMMENT."

Incidentally 30 °baumé FRESH HCl is NOT available, the highest concentration is 20 ° baumé (e.g. about 35.5% HCl). After being fresh the dissolving of iron and zinc causes the baum é to rise to the 30 to 40 ° baum é range. Some iron is required for good pickling in HCl.

In my inhibitor testing of 38 years ago (now published in the magazine METAL FINISHING) I did all my testing at 3 parts inhibitor/10,000 parts mixed acid (e.g. 3 liters inhibitor/10,000 liters mixed acid). For sulfuric acid I used 10% acid, 2% iron, 1% zinc and 160 °F. Only one inhibitor (produced in the USA) did everything I wanted, including NOT slowing the pickling (in a separate test). For HCl I used 1:1 HCl/water 3/10,000 and the same iron and zinc and at 90 °F. Again only one (produced in the USA) did what I wanted.

About 10 years ago I was called into a new start-up plant using sulfuric acid, which previous to my arrival had 3 (55 gallon) barrels of fume suppressant plus inhibitor put into each of three 20,000 gallon pickle tanks. The fumes were so bad that I could NOT walk across the plant floor crosswise. Simply put, my lungs closed up and I could not take a breath. The workers were having nose bleeds and quitting. I drove to a nearby galvanizer and obtained two 5 gallon buckets of the good inhibitor and put one gallon into each acid tank. The next morning I came into the plant and the workers all came up to me and were thanking me for the clean air that they could take a breath. The supplier blamed the first product on a "bad batch." RIGHT!!! With the good inhibitor the air in the plant was the same as clean outdoor air.

A few months ago I went to the East Coast of the USA and noted that the HCl was not properly pickling. A test confirmed that the acids were over-inhibited (same supplier) as the case 10 years ago. This was quite unusual because the plant manager said they had not added any inhibitor for the last 5 months. To increase pickling they had heated up the HCl tanks and the guy was there getting ready to remove and replace the roof. All the acid tanks were then hauled away and new acid brought in and inhibited with the good inhibitor. It was a pleasure having acid that pickled very well and with almost NO fumes. Thus the combination of a good inhibitor and with proper testing, fast pickling, very low fumes, and very long acid tank lifetimes are easy to attain.
Geoff has very good experience.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

simultaneous October 9, 2012

A. Pickle time?
It's like asking how long is a piece of string.
There are so many variables.

But, structural steel, (beams and columns for buildings) in winter might take 2-4 hours.
We manage to use pickle tanks where heavy long pickle time material is at the bottom, while lighter quicker material sits near the top.
In another plant further south (warmer), winter pickle time can be 1-2 hours for light material.

Geoff Crowley
Geoff Crowley
galvanizing & powder coating shop
Glasgow, Scotland

October 9, 2012

thumbs up signDear Dr. Cook,

Sorry for my rubbish English, I have asked for 2 different values; new fresh acid and 30 baumé acid (after it is used and reached to 30 baumé).

After your good response I will consider about the inhibitor and temperature. Thanks for your help.

- Ankara, TURKEY

October 9, 2012

Q. Dear Sirs:
I am really enjoying with such technical discussion, I really feel proud to be involved. Regarding my conditions --
Our acid pickling concentration always was kept between 8.0 up to 12.0 to avoid acid fumes; we have same acid suction unit as explained by our friend Ozge but from a Chinese supplier.
Regarding the inhibitors, I am a little bit worried since we are using Chinese brand and I can't trust it. It may be causing poor pickling. I hope that Dr. Tom can recommend a good brand for us from local market (China) if available. Otherwise, give us the way how to test it. Final solution we can import from international market as per his suggestion.

Ahmed Rashad
- Liaoning, China

Ed. note: Thanks, Rashad, proud to know you. We wish we could be all things to all people, but we have learned from decades on line and tens of thousands of threads that we simply can't recommend particular brands or suppliers in a public forum. It leads to the raucous hostility that has destroyed so many forums; and to race-to-the-bottom spam with shills posting with fictitious names posing as satisfied users (and even masquerading as other people); and it makes it impossible to retain advertisers to keep the forum going. The best way to preserve a forum that offers camaraderie and impartial technical answers seems to be to work towards removing all commercial benefit from the postings, even when that means an answer isn't wholly satisfactory, and keep advertising a separate issue. Sorry. We spend many hours editing or discarding hundreds upon hundreds of pieces of spam submitted as answers for posting on this forum every week.

October 10, 2012

A. Ozge:

30 some years ago I found a wetting agent for flux that I liked. I used vacuum (water aspirated) and reduced the volume of this wetting agent by 95%. I then added water back and got the same good results as a wetting agent. I contacted the maker of this wetting agent and indeed he admitted that he took 2 gallons of the concentrated wetting agent and then added 50 gallons of water to it and sold it by the barrel at about $2,000/barrel. I chose NOT to deal with this guy who liked to dilute a good material and sell it for a huge profit. Later I found a concentrated material that works extremely well at 1 to 3 parts/10,000 parts of tank volume. (e.g. 0.01% to 0.03%). Thus from this posting you should note and understand that if an inhibitor company recommends much higher concentrations it is likely the inhibitor is not very effective or watered down. Also realize that the more inhibitor an inhibitor company sells the more money the inhibitor company makes. Also some inhibitor makers do not disclose on MSDS sheets what is in their products which should make you question why not? In the USA disclosure on MSDS sheets is a requirement of law. An acid inhibitor MUST nearly prevent additional attack of the bare steel after the mil scale is removed, and it MUST NOT slow down pickling (removal of mil scale). Thus two types of testing are required: 1)acid attack on steel in a stressed condition and 2)pickling speed tests on steel with a mill scale coating. Less fumes in the plant come automatically with a good inhibitor. There are fume control agents (which are NOT inhibitors) as well but I rarely use them except in special cases.

My article in the magazine METAL FINISHING about inhibitors is titled something like: "Testing and Use of Acid Inhibitors." From this article you can test and evaluate inhibitors to find the one or two (from many) that suits your needs.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

November 15, 2012 -- this entry appended to this thread by editor in lieu of spawning a duplicative thread

Q. I am an employee at one of the construction companies that manufacture scaffolding and formwork.
Most of our products are galvanized, therefore we set up a galvanizing process. It's been running 75%, but I am still confused as to the determination of the proper usage of fluxing solution because I'm new in this issue. Whether mono salt, salt double, triple or quad salt?
I need help to determine which fluxing solution I will use in my company now.

Defi Afriyanti
- Cikupa, Tangerang, Indonesia

November 17, 2012 -- this entry appended to this thread by editor in lieu of spawning a duplicative thread

Q. How do you purify triple salt flux which is contaminated by hydrochloric acid? Test procedure to determine the iron content in a flux solution?

Psalm Velarde
production - Dubai, UEA

February 3, 2013 -- this entry appended to this thread by editor in lieu of spawning a duplicative thread

Q. Dear Sir,

Please give me details of flux (% ammonium chloride, zinc chloride, & other )

Thanks & regards

- Pune, India

February 17, 2013

Q. Hi sir

I am responsible of qc in galvanizing factory. I have an article about flux. Please guide me what should I do?

Best regards

meysam karimi
responsible of qc - iran-khorasan-mashhad

February 20, 2013

Q. Dear sirs,

I've just started working in a company that galvanizes steels for power transmission towers. The problem is, it doesn't have any knowledge about the chemical of the process and I'm in this field only for 5 months. We're making some tests to prove what is good for us and what is not, but we're still facing some difficulties

One of the problems we have is about the preflux additives, we've just prepared a new preflux bath because the old one had 50 g/L of iron contamination. Some suppliers told us about some additives and I'd like to know if they really work or are just people trying to sell their products. The additives are:

-Additive for complexing of iron: a product that maintains the iron concentration low by complexing the iron contamination;
-Additive containing nickel: some said that nickel in the preflux bath help the homogeneity of the zinc layer, but others say that this nickel only oxidizes in the heating before the zinc kettle, forming ashes;
-Additive to make the steel more wettable.

These additives really work? Is there another kind of additives I can use in the preflux bath?


Daniel Athayde
Chemical Engineer - Belo Horizonte, Brazil

simultaneous February 23, 2013

A. See some people even add acid to the flux but they tend to miss it that this would go to the GI tank.Better way is to change the water after pickling on a regular basis and check the iron content of it.If the water after pickling is clean you wont see iron content in your flux increasing.Changing of Flux is an Expensive part but changing of water after pickling is relatively cheaper;)

nitesh agarwal
- mumbai, India

February 23, 2013

A. Daniel,

Regarding additives for flux:

There is no additive to complex iron in flux.

Nickel in the flux is toxic, according to the USA CDC, nickel in any form causes lung cancer. Also nickel in the zinc at 0.05% only works for silicon semi-killed steel (e.g. 0.05% silicon to about 0.15% silicon). In the USA nearly all steels are fully-killed steels, silicon above 0.15% or aluminum above 0.03% aluminum. For these steels nickel is of little or no value.

There is an excellent surfactant in the market which at 0.03% reduces the surface tension from about 80 dynes/cm down to about 30 dynes/cm. It also is an excellent corrosion protector for steel and by having a 1 inch layer of suds on the flux solution reduces the heating cost for the flux tank by 50%. This wetting agent is made in the USA and Germany.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

Best ACN for my case

July 8, 2013

Q. Dear sirs,

My company sent the flux samples of different suppliers to a lab. The two samples had different ACNs and I still don't know which one is the best for my case.

We galvanize about 80% angle steel and the other 20% are sheets. We are not able to heat the preflux more than 40 °C, but we have an oven.

What is the best for me? An ACN of about 0.4 (MONOSALT) or is there another good composition for my case? I've read that the best for sheet is the monosalt, why is this? Is it because of the low ammonium concentration?


Daniel Athayde
Chemical Engineer - Belo Horizonte, Brazil

July 29, 2013

Q. Dear.Dr.Cook,
I run plating business in South Korea.
I read your posting on and I would like to ask some questions, if you don't mind.

1. In your posting, there's a direction that 'Add some wetting agent during fluxing process'. So I added made-in-Korea wetting agent over 2%, but only resulting 40 dyne/cm of surface tension.

2. Is it ok to get less zinc consumption, less ash and less bottom dross effect with surface tension 40 or so?

3. I would like to know correlation between zinc consumption and surface tension.

4. And, is there any negative effect in flux cistern, pouring some addition agent of 2% - 4% of total amount?

Kwak Dong Bin
- Ulsan, Daun-Dong, South Korea

July 30, 2013

A. Sir:

There is no way I can answer your questions because I have no idea what your wetting agent is. I do not know if it would be beneficial or bad.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

At what point does recirculating waste water ruin the flux?

December 27, 2013

Q. Dear Dr Cook and other readers,

I am working as a chemist in an HDG plant.
My question considers the effect of washing water on flux. We are using HCl for pickling. As we don't have canalization, waste water for rinsing has to be sent to authorized companies and thus we were forced to deal with this problem in a way that our waste water is circulating. It goes from washing tub in to neutralizer (NaCl is added) and it is neutralized at 8,1 pH; some coagulants and flocculants are added for precipitation and after that water goes to precipitation tank where the sludge is pulled out. "Clean" water goes back in the wash tub and it is used again.
The only problem now is that the water currently contains 83% of NaCl (100% corresponds to 36 g/l), total dissolved solids are 19 g/l, conductivity is 36mS at the temperature of 13,2 °C.

I am aware that at some point we will contaminate flux with Na+ ions. Do you know what other problems I can expect? What can I expect in the dipping process, more smoke, ungalvanized areas?
We are using our type of flux for 8 years now where the ratio of ZnCl2:NH4Cl is 2:1, flux is 21 baumé, temperature 25-35 °C, content of Fe2+ lower than 1 g/l, and we don't have any problems in production -- black spots are really rare.

Does anyone else have the same experience with rinsing of goods in salted water? At what level/concentration of NaCl /conductivity do you send it out? At what concentration of salt can I expect that the material after rinsing and before fluxing, although it takes few seconds, will start to corrode? Is it possible that material goods will corrode after fluxing? Do you have any suggestions for me?

Really looking forward to your answer.

Vedrana Bukal
- Zagreb, Croatia

December 27, 2013

Q. Dear Sir,

Currently we are buying flux from a local supplier. It's giving us a lot of problems. When i ask the supplier whether it's:

2)Triple salt

He is unable to answer. According to him, this type flux is specially designed for my plant.

Specific gravity of neat solution of fresh flux is: 1.15
Temperature of flux is: 51 °C.
I am suspicious of the supplier because the quality of flux he is supplying us is causing us a lot of problems.

After dipping the product into flux solution, we will have corrosion line on the surface of the product and it creates a lot of ash during dipping in the zinc pot.


Jeet singh
galvanizing - Selangor ,Malaysia

January 12, 2014

A. Sirs:

In hot dip galvanizing fluxes certain non-volatile chemical compounds may be present (even in brand new fluxes). These may include calcium chloride (CaCl2), magnesium chloride (MgCl2), manganese chloride (MnCl2), sodium chloride (NaCl), and potassium chloride (KCl).

About 30 years ago I found 13% sodium chloride in a flux from Iceland and the galvanizer had 13% rejects. A reject being product that had to go through the kettle twice. When the flux was replaced with a flux having no sodium chloride the rejects went away. Same thing happened in Madrid except it was 20% sodium chloride in a pipes galvanizing plant with 20% rejects and again rejects disappeared when flux with no sodium chloride was put in the flux tank.

I now know that if the solid flux contains about 3% total non-volatiles (or about 8 grams/liter in the working flux), then the rejects will be about 5%.

I recommend that you have your working fluxes tested by icp/ms and post the results. The results should be in mg/liter of the chlorides of the various metals.

Vedrana-- You cannot neutralize with sodium chloride (NaCl), you must mean sodium hydroxide (NaOH). The proper pH of rinse before flux is 5 or lower, otherwise the product will corrode before you can get to the zinc kettle. Your current procedure is bad and you will contaminate the flux.

Jeet-- Have your incoming (new) flux tested and post the results.

Regards, Dr. Thomas H. Cook, Hot Springs, South Dakota, USA

Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

May 12, 2014

Q. Dear Dr. Thomas.
Which flux salt (mono, double, triple, quadra) you recommend me to use in my batch galvanizing plant since my dryer is not really effective. Also what can I add to my flux tank to stop the zinc spattering or scattering from my kettle since my dryer is not effective as I told before.

rashad ahmed
hot dip galvanizing - borjal arab , Alexandria , egypt

May 13, 2014

A. If you would like to try a flux extremely low in non volatile salts I suggest you try PREACT. We manufacture our flux at our plant in Freeport, TX USA from virgin raw materials to insure the lowest possible level of non-volatile salts.

Thorn Baccich, President
Mineral Research and Development - Harrisburg, North Carolina USA

May 2014

thumbs up signThanks for your participation Thorn! We don't recommend one proprietary product over another in this forum, nor can we ask our supporting advertisers who make the forum possible to bear the costs of postings that steer the potential customers to non-advertisers, so we had to abbreviate your posting a bit.

But you are implying that low-volatiles in flux is an important issue, and it sounds to me like a valid technical point. Thanks!


Ted Mooney,
Teds signature
Ted Mooney, P.E. RET
Pine Beach, New Jersey

May 15, 2014

A. Ted, I can appreciate your comments. The best expert to ask regarding the problems of high levels of non-volatile salts in a galvanizing flux can cause is Dr. Thomas Cook. He has done a great deal of work testing fluxes. He is by far the best expert I know on this topic.


Thorn Baccich, , President [returning]
Mineral Research and Development - Harrisburg, North Carolina USA

May 2014

Hi again. No question about Dr. Cook's expertise, which has been demonstrated countless times on this site, let alone many other venues. However, unless there are several suppliers of fluxes with low non-volatiles, the topic would become a public discussion of a single proprietary product -- which is always a disaster for a dozen reasons :-) Thanks.


Ted Mooney,
Teds signature
Ted Mooney, P.E. RET
Pine Beach, New Jersey

May 15, 2014

A. Dear Mr. Rashad Ahmed;

Generally double salt flux is used among batch galvanizers. However you can use higher ammonium chloride content but it will cause excessive fume.

If you don't have a dryer you can:

1- Heat up your flux to 60 °C with a simple boiler and heat exchanger coils
2- Use flux surfactants (will be cheap and easy to use)
3- Soprin has an flux additive for exactly that purpose

But please keep in mind that nothing will be as advantageous as a good drying system.

Ozge Saracoglu
- Doha, Qatar

May 16, 2014

Q. Hi friends,
Mr. Ozge. Thanks for your existing reply and I appreciate your help a lot. Regarding fumes, no problem; we have our effective fume suction unit.
So what is the best flux to give us best quality and consumption?
As well do you an idea about pickling accelerator?
By the way what do you do in Doha?

rashad ahmed [returning]
- egypt , cairo

May 22, 2014

A. Dear Mr. Rashad Ahmed;

For quality issue, actually I have never noticed any difference between double salt and triple salt. Moreover if you can eliminate fume, and I am assuming that your pickling is not perfect (as you want to accelerate your pickling) triple salt can give you a better solution. Although the consumptions are nearly the same, triple salt is cheaper than double.

I have seen a chemical supplier is offering pickling accelerators, but I have never used it or seen any plant using it. I am not sure chemical approach to accelerate pickling can efficiently work. Maybe Dr. Cook can explain that subject to us.

But, kinetic approach for accelerating works perfectly. You can heat up your acids to 30 °C, and give some agitation by a mixer or blowing air in. By applying both, you can double your pickling efficiency. But be careful not to exceed 30 °C much. It will cause excessive acidic gas extraction, and also it makes Dr. Cook so much angry :-)

I am currently installing a galvanizing plant (14.5 x 1.8 x 3 m kettle dimensions) and a fabrication unit (fully automated pole production line and road barrier line). Actually main equipment installation is finished; we are doing the auxiliary fabrications and waiting for governmental approvals.

Ozge Saracoglu
- Doha, Qatar

May 27, 2014

Q. To reduce the Fe from flux bath I put in H2O2 . how can I remove the foam that appears on the bath surface? Because in this foam is very much Fe and I want to get it away from the flux bath .
Best regards,

George Condurat,
- Bucharest , Romania

June 1, 2014

A. Dear George,

Didn't you filter your flux after adjusting pH and adding peroxide?

- Doha Qatar

June 18, 2014

A. Dear Sir...
Better you do continuous flux filtering system which helps to remove Iron content from Flux bath.

Ilesh G Vyas
Gunatit Builders
supporting advertiser
Manjalpur, Vadodara, Gujarat
gunatit builders

July 4, 2014

A. George,

The reason you got so much foam when you added H2O2 to the flux was that your pH is too low. You must also FIRST add aqua ammonia (ammonium hydroxide) to provide OH- groups for the Fe+3 that is formed to make Fe(OH)3. Without the ammonia, peroxide self destructs to oxygen (the foam) and water.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

June 18, 2014

Q. Dear sir

I need the method to analyse flux solution (Hot dip galvanizing) for iron content. The method which I have is by using KMnO4 with pink end point.

My problem is the pink end point never comes while analysing flux. It's found the the solution turns greenish black which cannot assure the end point.

Please help and guide which method to be used for analysing iron in flux which can show clear endpoint.

Awaiting response soon.

Dharampal Singh Salooja
- Jeddah, KSA

July 3, 2014

A. Sir,
Best titrant for Fe+2 is potassium dichromate with sulfuric acid/phosphoric acid buffer and sodium diphenylamine sulfonate. End point is from light green to deep blue.

Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

July 5, 2014

Q. Dear Dr. Thomas
Thanks for response regarding Fe+2 analysis.
Can you describe a complete method to analyse hot dip galvanizing flux for iron content using potassium dichromate?

Thanks awaiting reply

Dharampal Salooja [returning]
- Jeddah, saudi arabia

September 19, 2014

Dear Sirs,
for flux treatment (Fe reduction) we made lots of experiments and one of the results is that the amount of chemicals (both H2O2 and NH4OH) is reduced when first adjusting the pH value by adding NH4OH and the oxidate the Fe(II) to Fe(III) and with this, Fe(III)hydroxide precipitates. But it is highly advised to "stop" oxidation and precipitation when the pH value decreases <3. For lower pH values the floc becomes bad and the separation of Fe(III) hydroxide with chamber filter press is much more difficult. There is a De-Iron-Unit on the market which considers all these items and treats the flux in parallel to the HDG process

Dr. Frank Schmelz
- Recklinghausen, NRW, Germany

November 21, 2016

Q. We are using nickel base Flux chemical and the baumé is 14 only. I need to increase the baumé. How can I increase it?

Elango Edison
- Tamil nadu, India

November 22, 2016

A. Sir:

Nickel in the zinc is effective ONLY with silicon semikilled steels (e.g. silicon between about 0.04% and 0.14% Si). There is very little steel like this in the USA and nickel in the zinc at 0.05% nickel is not so popular as it was some years ago.

I am not aware of any proof that nickel chloride in the flux is effective in controlling silicon semikilled steels.

I did some experiments with auto catalytic nickel plating (a few microns before a regular flux) and it did work on silicon semikilled steels. There were problems in controlling the nickel content in the auto plating solution depending on temperature, pH, and some other variables. A flux company in Germany said they did not make nickel containing flux because after it was contaminated there was no way to get rid of it.

Because nickel causes lung cancer, I NEVER recommend the use of nickel in galvanizing because it is quite likely to become airborne.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

December 17, 2016

Q. Good day for all,

My chemical analysis on flux solution is:

Zinc(zn) total = 8.5
Chloride (Cl) = 17.8
Total Iron (Fe) = 1.67
Ammonium Ion (NH4) = 0.32


- Ammonium as Ammonium Chloride (NH4Cl) =0.95
- Zinc as Zinc Chloride (ZnCl2) = 17.71

What do you think of this Analysis,
And what is the advice to get the best results?


aly elsokkary
- Saudi arabia

December 17, 2016

A. Sir:

I presume your numbers are percent?
How was the Zinc determined? ICP or AA
How was the ammonium ion determined? Kjdahl or Specific Ion Electrode
How was the iron determined?

IF!! your numbers are correct?? There is not nearly enough ammonium chloride for good galvanizing. The iron is a bit high.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

December 20, 2016

Q. Dr.Cook,
Thanks for your kind reply.
This is the result from the report; we use double salt flux.
What is your opinion in this analysis, and what precautions should I take?

Zinc(zn) total = wt% 8.5
chloride (Cl) = wt% 17.8
total iron (Fe) = wt% 1.67
Ammonium ion (NH4) = wt% 0.32


- Ammonium as Ammonium Chloride ( NH4Cl) = Vol% 0.95
- Zinc as Zinc Chloride (ZnCl2) = Vol% 17.71

Your guidance is always appreciated.

aly elsokkary [returning]
- Saudi arabia

March 17, 2017

Q. Dear sir,

My flux gravity is 1.18 and its temperature is 40 °C, and I'm also doing online flux filtration. Iron content in flux is 4.5 gm/lit.

Now I am struggling from more ash formation in zinc bath and also heavy ash marks on material.

I am using platinum flux.

Please advise me how can I solve the problem?


kiran gaikwad
- davangere, karnataka, india

June 13, 2017

Q. Hi,
I prepared the flux solution from the reaction of zinc chloride with ammonium chloride. When analyzing the solution, the ratio of zinc chloride was 21.66% while ammonium chloride was 15%. When the solution was left for a period of time, a precipitate was formed. I do not know what is the reason? It also gives little adhesion. I hope you will help me to give the exact proportions of the reactive materials.

ali amal
- baghdad, Iraq

June 15, 2017

Q. Dear Sir
I want to use only NH4CL for new fluxing tank. What will happen? Please answer me? We galvanize all kinds of structures and towers.

Thaw Kaung Maw
Myanmar Economic Corporation - Yangon, Myanmar

June 16, 2017

A. You will certainly get a lot of fume.
It might work, but it could also be that you don't get full wetting and fluxing and that results in bare patches.

You could try it in a small batch on some sample plates and see what happens, that way you don't waste a whole flux tank of materials.

Geoff Crowley
Geoff Crowley
galvanizing & powder coating shop
Glasgow, Scotland

June 23, 2017

Q. Thanks sir
I also want to know the ratio. How much NH4Cl to use in 1 liter?
Please advise me.

thaw kaung maw [returning]
myanmar economic corporation - yangon, myanmar

June 2017

thumbs up sign Hi cousin Thaw. I am not a galvanizer, but I try to listen and learn -- and I think in your eagerness to get started you have not slowed down to listen closely enough :-)

I think the answer was essentially: "I think it's a bad idea and not liable to work well for several reasons; but if you insist on trying it, do some experiments on a few small parts". Asking people for the exact details on how to do what they've repeatedly suggested that you not do can be problematical badgering, but good luck :-)


pic of Ted Mooney
Ted Mooney, P.E. RET
Pine Beach, New Jersey
Striving to live "Aloha"

June 23, 2017

A. Sir:

45 years ago I did experiments using NH4Cl alone and ZnCl2 alone for hot dip galvanizing fluxes. NH4Cl dried very quickly on the steel but corroded the steel very badly. ZnCl2 never dried and the steel did not corrode. The NH4Cl flux gave much skimmings (ash) and smoke. The ZnCl2 spattered badly when going into the molten zinc. In the end both steel samples galvanized fairly well with about 3 mils of zinc (75 microns). Do not expect good results from ammonium chloride alone or zinc chloride alone.

Experiments with hot 160 °F (71 °C) triple or quadraflux dried quickly and did not corrode and gave an excellent result. The steel must be in the hot triple salt solution long enough to heat the steel completely so the heat of the steel dries the flux from the inside.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota

December 11, 2017

Q. I'm a process engineer at a hot dip galvanizing plant in Morocco. We are facing a problem with the flux solution: the ACN is going up and we can't explain the ZnCl2 consumption.
We use a double salt flux with temperature 45 °C. Our ACN went from 0,8 to 1 in about 4 months.
I would be very thankful to you if you can help us out on this issue.

Soufiane esslaoui
- rabat, rabat, morocco

December 21, 2017

A. Sir:

If you are using ammonium hydroxide (aqua ammonia) to raise the pH of your flux then this is the same as adding ammonium chloride. Each U.S. gallon of ammonium hydroxide is the same as adding 11 pounds of ammonium chloride.

If this is not the "problem", then perhaps whoever is dong the testing may be doing it incorrectly.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs, South Dakota USA

December 22, 2017

Q. Thank you sir for your quick reply.
Actually we are using ammonium hydroxide 25%, and for each 1000 l of ammonium hydroxide we're adding 275 kg of zinc chloride to correct the ACN.

Soufiane esslaoui [returning]
- Rabat, Morocco

December 24, 2017

A. Sir:

By adding 1,000 liters of 25% aqua ammonia (expressed as percent NH3), and 275 Kg of zinc chloride, you are indeed increasing your ACN.

The Kg of ammonium chloride in 1,000 liters of 25% NH3 is:
0.25 * 1,000 L * 0.91 * (53.45/17) = 715 Kg ammonium chloride.

The resulting ACN of your additions are:

ACN = (715Kg/275Kg) ACN = 2.60

In the above calculation: 0.25 is the % NH3.
The 0.91 g/ml is the density of the NN3 solution.
The 53.45 is the molecular weight of ammonium chloride.
The 17 is the molecular weight of ammonia

The real question here is WHY would you need to add 1,000 liters of NH4OH to neutralize excess acid in your flux? This is enough ammonia to neutralize about 2,000 liters of 17% HCl. You must not have a rinse tank between your HCl tanks and your flux OR you have an old rinse solution that is stagnant for many years? Perhaps clean water is costly in your country.

I do not normally give any advise without knowing more about a plant, however skimmings or ash possibly could be added to your flux to both neutralize acid carry-over and to keep your ACN down.

What is the density (in Be' units or g/ml) of your flux.
Your operation is not in control.

And by the way I do not like double salt.


Dr. Thomas H. Cook
Galvanizing Consultant - Hot Springs South Dakota USA

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