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Removing Silver from old silverplate, holloware, etc.

Quickstart:
     Some flatware and silver service items are sterling silver, in which case they are usually marked "995" or "Sterling" (99.5% pure). Sterling silver items are somewhat in demand as well as having intrinsic metal value if melted down.
     But most silver flatware, trays, tea sets, and similar items are just silver plated. For several decades up to and including the 1960s such stuff was a very popular wedding gift ... but it has fallen out of fashion with the result that basements & attics are drowning with it and the resale value is pretty much negligible.
     It's also generally considered non-economic to recover the silver value because the plating is so thin that the cost of the recovery equals or exceeds the value of the silver recovered -- not to mention that hazardous chemicals are required.
     One contributor notes though that as the cost of silver increases it may be possible to economically recover the silver by abrasive blasting. The other alternative is to just keep it in the attic; perhaps by the time your grandchildren are adults it will back in fashion and better appreciated.
     Read on, join in ...





Q. I have a small collection of decorative silver plated items that I would like to sell if possible, or donate if not. Sadly, I've come to realize that they have virtually no resale value as is, since they are not rare or valuable antiques. Some are plated on copper. Considering the current commodity prices of both silver and copper, is there any technically and economically feasible way to separate the silver from the base metal for recycling of either material? At the very least, I would like to keep these items out of the landfill. Thanks so much for sharing your time and expertise, I really appreciate it.

Apollo Silver Co. tea sets on eBay (affil link)
Rogers Silver Co. tea sets on eBay (affil link)

Paula K. Rasmussen
Retired IT Professional - Shoreline, Washington, USA
2006


A. Paula,

Nope.

The chemicals used to strip the plating off and reclaim them are corrosive or toxic or just not real friendly. It takes a bit of work to set up everything needed to do the job right. There is not enough silver or copper plated on your parts to make it worth it.

Trent Kaufman
Trent Kaufman
electroplater - Galva, Illinois


A. Hi Paula,
The amount of silver you could recover from silver plate would not be worth chemically stripping. You would have to buy the stripper, and dispose of the silver bearing stripper in the right manner. The collection may have copper value, depending on the total weight. Metal recyclers may be interested. Another option is to put a fair market value on the collection and like you say, donate it to charity for a possible tax deduction. Good Luck!

Mark Baker
Process Engineer - Syracuse, New York




Q. I have a much larger quantity of scrap plate I wish to recover. I have about 30 pounds military scrap silver plated ethernet connectors and the plating appears to be heavy. Silver spot is currently $17.34. I have Nitric and HCl acids and adjustable d.c. power supplies. I also have two years worth of college chemistry but that was 30 years ago. If needed I can make a fume hood I designed and I have a local company that can sell me an activated charcoal filter for it. What I would like to do is remove the plate without dissolving the underlying brass. ⇦ Answer?

John Cooper
- Houston, Texas , USA
July 26, 2008

A. Hi John,

This is hard to do electrolytically in simple salt or dilute acid solutions because silver is more noble than brass, meaning that the brass will go into solution preferentially. You would need cyanide based strippers (no go for home use) or hopefully some less toxic alternatives. Thread 225/07 is "Stripping Silver from Brass" and describes those alternatives.

Still, many of these solutions are too toxic for home use or for use without hazmat training.

Luck & Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com - Pine Beach, New Jersey

Need quick confidential answers? $25
Need project assistance? $100/hr.




Q. I am trying to decide if a commercial silverplate recycling operation could be financially profitable. I realize that the price of silver is low now and that the references to this idea in the past have been negative. Any ideas on this subject would be appreciated.

Greg Harding
Recycler-startup - Shingle Springs, California
November 15, 2008


A. One way to go about removing silver from silver plate is the abrasive method, as silver becomes ever more expensive (today spot price is $32.64/oz ) the cost of recovering silver will be more economical. I recommend rigging an abrasive wire or grinder to wind or solar power, fit the item on a lathe and rig it to go back and forth and turn every so often, time is your enemy if you want it done fast because fast will cost you money, if you're willing to wait you can recover plenty of dust that can be collected (if contained properly) and then melted down with a home-built foundry. If you do not have any of these things or are not planning on building them anyway then this method is more costly than just selling it to a scrap recycling company.

I recommend the home built solution because in the end you will learn a new skill and become more self sufficient which will pay off more than any silver recovery process you may do.

Drew Manupupule
- Honolulu, Hawaii
December 3, 2011




Recovering silver from hotel items

Q. I am looking for 2 things --

First will be antique hotel silver
Next I need to find the best indices and skill to fix small dents and then go on to replate the item.

I would love to get as many answers as possible. ⇦ Answer?

Antique Hotel Silverplate on eBay (affil link)

Courtney Arnot
- New York, New York
September 1, 2013


Q. Dear all,

I embarked on a project recently, renovation of hotel items namely wine buckets, wine bucket stands, trays, cloches etc. The assignment is to polish only and all the above mentioned items are silver plated Stainless Steel objects.

I started by stripping the silver off in a mixture of:
950 ml sulfuric acid and 50 ml nitric acid per litre and it works wonders.

Then we polish the objects and work is done.
However, I would like to know if there is a simple lab procedure or any, to extract the silver from the solution. ⇦ Answer?
Thank you.

Rhiaz Muhammad Subdurally
Plating shop Manager - Port-Louis, Mauritius
August 14, 2019




Multiple threads merged: please forgive chronology errors and repetition  🙂



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"Recovery And Refining Of Precious Metals" by C.W. Ammen (1984)
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"Refining Precious Metal Wastes" by C. M. Hoke (1982)
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"Gold Refining" by George Gajda (1977)
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Q. I have silver plated scrap materials. But how can I strip the silver metal from scrap materials and how to recover the silver metal from silver scrap solution? Please suggest any suitable method for me.

R MUNIRAJU
- Bangalore, Karnataka, India
August 14, 2019


A. Hi Muniraju. The question is pretty broad. Most silver plating is not economically feasible to recover, and for the rest it depends on the thickness. But different stripping methods are required depending on the base metal.

But I think the important thing is to not buy scrap unless you know what it is, and to acquire some experience on a small scale before getting involved with large quantities. Another issue of course is that this can be dangerous, depending on the knowledge and facilities you can bring to bear. Good luck.

Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com - Pine Beach, New Jersey

Need quick confidential answers? $25
Need project assistance? $100/hr.


Q. Any silver stripper solutions is there to remove the Silver content in plated parts or scrap materials.

R MUNIRAJU [returning]
- Bangalore, India
September 14, 2019


A. Hi again cousin . You can search this site for "silver refining" and "silver stripping" to find dozens of threads and specific answers. But there is no universal stripper where you just throw your parts into a vat and out pop stripped parts plus pure silver. The stripping method will depend on whether the silver has a clearcoat/lacquer on it, and whether the substrate is nickel silver, a copper alloy, steel, aluminum, or something else. It depends on whether it's practical to use electricity on the particular items, whether you are allowed to use cyanide-based strippers in your area, and whether you are trying to preserve the substrate (such as silver plated brass musical instruments) or it's okay to treat everything strictly as scrap. My understanding is that most silver refining starts with melting the scrap rather than stripping it; still, it does seems that if you can segregate it based on the factors listed above, it may be possible to strip the silver off, abrasively, chemically, or electrochemically -- although not necessarily at a profit.

You need to invest more time though, cousin. You've submitted requests for help 16 times but not followed up when readers took the time to help you on other threads. We've requested repeatedly that you please describe your situation so readers can try to answer you as a consumer if you are a consumer, as an OEM customer if that's what you are, as a plating operator, or whatever. Please describe who you are, the source of the parts (and its volume), with your general thoughts on what you are trying to achieve (preserve the parts, or scrap them) -- and I'm confident readers can help!  🙂

Good Luck and Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com - Pine Beach, New Jersey

Need quick confidential answers? $25
Need project assistance? $100/hr.


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