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Anodizing Hardness vs. temperature, current, and other parameters




2004

Q. My name is HC Lee and I am working as an QA Executive in a anodizing services company.

I urgently seek consultancies on the problem of the anodizing material hardness.

Specification require = hardness 400 Hv minimum

Operating temp    = 13 °C
voltage = 23V time    = 20 minutes
sulfuric acid = 200 g/l Al content = 5 g/l
Sealing    = 15 min/98 °C

Any of the above factors that contribute most to the failure of the hardness? It seems hardness went down from 430 to 375 hv by using the same operating parameters. Can any one advise me?

Thanks

Hwa Chang Lee
Anodizing Industry - Kuala Lumpur, Malaysia



simultaneous replies

A. Suspect one is that your agitation , air and / or liquid, has dropped. Two is the temperature control throughout the run is not consistent-possibly larger loads. Three is your temperature control has lost calibration. Four is your power supply has lost its calibration. five, someone changed some parameter of the tanks chemistry or times. Finally, your anodize tank has too much copper or aluminum in it.

James Watts
- Navarre, Florida
2004


A. If you used the exact same operating parameters, and the same aluminum, the hardness would not change, so you will have to look at your operating parameters and see which have changed. Let's take temperature for example. You say 13C, but there must be some operating range, an upper and lower control limit. If you were to anodize today at, say,11C and tomorrow at, say 15 C, the work you do tomorrow would likely be softer. Find out exactly what your parameters were when you did good work, duplicate them, and you'll do good work again.

jeffrey holmes
Jeffrey Holmes, CEF
Spartanburg, South Carolina
2004



A. Sounds like you are trying to coat type 3, should coat @ 30 amps per sq/ft not by volts.

Chris Snyder
plater - Charlotte, North Carolina
2004



simultaneous replies

"The Surface
Treatment &
Finishing of
Aluminium and
Its Alloys"

by Wernick, Pinner
& Sheasby

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A. Amen to what Chris said.

By Faraday's Law, anodization is done by current, not voltage. The voltage will be whatever is required to establish the anodizing current, governed exactly by Ohm's Law. 23 volts is completely meaningless without knowing the total electrical resistance of the anodizing setup in question. Decent ammeters are now commonplace on anodizing rectifiers, there is no excuse for archaic (and grossly inaccurate) "voltage" anodizing.

If the intent here was a Type III coating; 13 °C = 55.4 °F, seems too warm, even with additives. A 200 g/l electrolyte also seems too strong, both will contribute to a softer coating.

Paul Yursis [deceased]
- Columbia, Maryland, USA

Ed. note: it is our sad duty to advise of the passing of Paul Yursis in August 2005.
Here is a brief obituary by Mike Caswell.


A. Drop the sulfuric acid from 200 g/L to 165.3 g/L and the pore gets smaller and the surface gets harder.

robert probert
Robert H Probert
Robert H Probert Technical Services
supporting advertiser
Garner, North Carolina
probertbanner
2004




November 12, 2012

Q. I am a new supervisor in an automotive industry>
We have a new project involving "hardcoat anodising on aluminum alloy"
Our customer requests the specification as
1. max roughness 2,4 Rz
2. minimum hardness 310 Hv (microvickers)
3. minimum thickness 4 microns

We conduct the trial with
1. Anodizing material Al alloy AC2B
2. 20% W/W sulfuric acid
3. Temperature 5 °C
4. 21 V with Constant Voltage

We can get a fine result for Roughness and thickness, but when we test the hardness, it failed.
Sometime we can get at about 300-310 Hv.
But most likely the average hardness is 190-270 Hv.
For your information, we conduct anodizing in 2,5 hour and the thickness is 10-15 micron and we use cold resin to make sample moulding.
Please anyone can give us some advice to increase the Hardness?

thank you very much for your help

Franky Agustinus
anodising line supervisor - Jakarta, Indonesia



simultaneous replies November 14, 2012

A. Hi,
Before offering suggestions, will you confirm that you are anodizing for 2.5 hours and getting 10 - 15 microns. If not, what are the correct values.

harry_parkes
Harry Parkes
- Birmingham, UK


A. "Normal" hardcoating parameters are 0 °C with constant current density of 3.5 to 4.0 A/dm2. The final voltage should be higher than 21 VDC. I would expect to achieve 10-15µm in about 20-30 minutes with a terminal voltage of 30-40 VDC.

Chris Jurey, Past-President IHAA
Luke Engineering & Mfg. Co. Inc.
supporting advertiser
Wadsworth, Ohio
luke banner
November 15, 2012




Temperature, Hardness and Coat

September 19, 2016

Q. Specifically I would like to know how to set the parameter between coat and hardness according to several specifications (COAT: 10 to 30 µm Hardness: 330 to 430HV).
I have some idea that the temperature is totally involved in the process as more hot less hardness and more cold more hardness, is it correct?
We can consider a table of parameter for this?

33213-1a
33213-1b

Eliel Guedes Pinheiro
- Leon, Guanajuato, Mexico




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