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letter 42425

Color plating of chrome vanadium sockets - what's the process?



A discussion started in 2006 & continuing through 2017 -- add your Q to bring it back to the Hot Topics page.

(2006)

Q. My apologies to the "Made in America" folks out there.... Harbor Freight is selling chrome vanadium sockets that are color coded but the finish is definitely some kind of plating. The part number is 93265-1VGA. Beautiful finish on the set I just bought. Any idea what process is being used to apply the finish. I have a few applications in mind if it truly is a durable finish suitable for steel hardware.

(Auto Zone is also carrying lug nuts made by Dorman (subsidy of R&B Inc.) that have the same sort of coloring.)

What process should I specify to a plating shop to get that finish?

colored sockets

Thanks,

John Andrew Winkler
- Tucson, Arizona, USA


(2006)

A. This could be either interference coloring or PVD coatings, e.g., gold-colored TiN. See 'Special Finishes for Stainless Steel' available from the SSINA: http://www.ssina.com/publications/spe_fin.html

Interference coloring on stainless, also called INCO coloring, can be produced by anodizing in a hot sulfuric-chromic acid mixture. Colors arise from the interference between the light reflected off the metal and the light reflected from the transparent oxide surface; different thicknesses in the range 70-400 nanometers give different colors.
Interference coloring is not as available as PVD coating. B&M Finishers Inc. in NJ advertises both 'Prismatic' and 'Ti-Gold' Stainless Steel.'
Russamer Lab interference color anodizes Ti, Ta and Zr, so probably can handle stainless, too (commercial accounts, only).

If interested in the process, find the Internet article: 'Chemical and electrochemical coloration of stainless steel...'
This same Brazilian group has a follow-up paper using only 5M sulfuric acid electrolyte (no chromic) at 50 °C:
'An Environmentally Friendly and Practical Method for Obtaining Color on Stainless Steel by Interference,'
J. Electrochem. Soc., Vol. 152, Issue 11, pp. B491-B494 (2005).

Ken Vlach
- Goleta, California



(2007)

Q. Being a metal artist, this Question has been making the rounds about colored galvanizing. Like on the sockets and wrenches that Harbor Tool store has started selling. People say there is such a thing as the colored galvanizing either hot or cold dip. Can anybody give a answer about that, and what is the coating or finish on the tools in colors from yellow to blacks, purples, greens, red and blue. On the Chrome Vanadium Steel the tools are made out of.
Second part, are these coatings something that a small shop can set up on a small scale to do like for art work, metal work on gates, and metal work in homes.

Glen Perye
metal artist, jeweler, smithy - Mount Clemens, Michigan USA


(2007)

A. Ken's replies are always well researched and usually right. But in following the link from Glen, I see a claim from Harbor Freight that these are chrome-vanadium tool steel with "durable electroplate".

Someone would have to examine them close up to know for sure, but from this claim I think they are nickel plated followed by electrophoretic lacquers of various tints. Another reason for this being my guess is that it would be significantly less expensive than PVD processes. Each color would take a separate tank, but yes, I think a small shop could set up one color to apply to nickel plated items.

P.S. to John. Without a picture of the lug nuts it's only a guess, but usually these are zinc plated with a blue or gold colored chromate.

Ted Mooney, finishing.com
Teds signature
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey


(2007)

A. If something can be proved, it need not be argued! Or so goes a saying.

John, please take those colorful sockets and subject them to solvent test. Dip them in MIBK overnight and then rub them aggressively with a cloth kept wet with MIBK. If the colors begin to wear off, you will know that the process is electrophoretic lacquer with a dye.

In case the colors are not affected, then it could be PVD / CVD.

I personally do not have much knowledge about Anodizing / Electrocoloring but I have seen that being done only on Aluminum.

Keep your fingers crossed that the color does wears off when you do the MIBK / solvent rub test.

Gurvin Singh
Coatec India
supporting advertiser
Mohali, Punjab, India



(2007)

Q. Thank you for your, fast response to my question. Here are some pictures I took after doing a couple of experiments on them. They seem to be coated with a clear lacquer top coat as the two that were sitting in the thinner for 50 minutes. had a little bit of orange peel looking clear sheet stuff just above the thinner line.

The color also was removed with out any power tools with the described tools on the pictures. I'm of the opinion that it probably is the thinnest plating the world has ever seen or just transparent lacquer under the clear also. Since it came off on the rag when they were being dried off

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They only other thing that wasn't clear to me is is there a colored galvanizing process other than the silver/grey color. As this question or statements by a number of artists/sculptors keeps surfacing on a forum that I am on. If it is possible what is the proper name to call it when contacting a plating/finish shop

Thank you very much.

Glen Perye
metal artist, jeweler, smithy - Mount Clemens, Michigan USA


(2007)

A. Now I am more confident that they are nickel electroplated followed by a tinted lacquer. I believe it's electrophoretic lacquer, that is, deposited via electricity. I don't think there's enough evidence in the picture for us to say whether there is an additional clear coat on top of the tinted layer, but if you saw it, you saw it -- and polyurethane coatings on tops of e-coating are common. Despite the scratching, it seems like a pretty good product idea.

No, there is no galvanizing or electroplating process that would offer colors like this. To obtain this coating, apparently you should specify nickel plating followed by electrophoretic lacquering in whatever color you want. Good luck.

 

Ted Mooney, finishing.com
Teds signature
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey



Need a Durable COLORED finish for steel motorcycle sprockets

September 10, 2014 -- this entry appended to this thread by editor in lieu of spawning a duplicative thread

Q. Looking for a Wear resistant COLORED coating. i.e., blue, green, orange, yellow, black etc, for steel motorcycle sprockets

Al Mitchell
new business development manager - Reno, Nevada


September 2014

A. Hi Al. Metals are silvery or brass/gold in color, of course, not the colors of the rainbow. As far as I know, there are only three ways to get colors like that then: an organic coating process like electrocoating, or anodized aluminum which can absorb dyes into its porous honeycomb structure, or a clear oxide coating which yields diffraction coloration.

We appended your inquiry to a thread about colorful electrocoatings, which may help give you a feel for that approach. We have numerous threads about anodizing if you feel that anodized aluminum sprockets have applicability. The third approach, transparent/translucent oxide coatings for diffraction coloration could apply if the sprockets were made of stainless steel or titanium; I don't think they can be done directly on steel, but they might be possible on sputtered titanium coatings on steel. Good luck.

Regards,

Ted Mooney, finishing.com
Teds signature
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey


December 4, 2014

A. Electroless nickel plating over Steel baked in a conventional oven to 400 °C for an hour will oxidize superficially and take rainbow colors. Perhaps not what you are looking for but very appealing in a way.

Guillermo (Bill) Marrufo
- Monterrey, Nuevo Leon, Mexico


March 24, 2015

A. Well... An interesting take on this would be to make the sprockets out of Titanium and "Anodize" them. You can get most colors in the rainbow and they vary with the voltage applied.

Richard Dubey
- Torrington, Connecticut, USA



June 16, 2017

Q. We are trying to produce our components with different color with plating or coating. At present we are doing ED coating, blackening, Zinc for our components, but it is not up to the mark in aesthetics. Kindly suggest some attractive color plating or coating with good wear cum corrosion resistance.

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Dinesh Ravi
TIDC India - Chennai


June 2017

A. Hi Dinesh. Your photo is small and low resolution, so I'm not sure what your components are or what they are made of. Hose couplings, socket wrenches?

Nickel plating followed by ED coating would be corrosion resistant, although it looks like some suppliers have had trouble keeping their colored sockets good looking.

Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey
Striving to live "Aloha"


June 20, 2017

Q. Thanks for the response sir, Looking for a Wear resistant cum Rust prevention COLORED coating. i.e., blue, green, orange, yellow, black, etc, for steel motorcycle sprockets

Dinesh Ravi [returning]
TIDC India - Chennai Tamilnadu India


June 2017

A. Hi. You can probably go ahead with the process up through the nickel plating for rust prevention and wear resistance. But no organic coating that you can apply for color sounds very promising against the wear of a chain. I think you'll need some type of PVD coating -- perhaps titanium, subsequently anodized.

Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey
Striving to live "Aloha"



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