plating, anodizing, & finishing Q&As since 1989
Zinc Barrel Plating Current Density
Q. I have a question regarding zinc barrel plating --
The barrel can hold 15,000 pieces of an object, which surface area of each object is 0.16 dm^2
The barrel are designed to pass through current of max 300A
I wish to plate 0.8 µm of zinc
What is the current density and plating time required?
A. Alan, per Faraday's Law, at 100% efficiency it would take 96,485 Amp-seconds (a Faraday) to deposit one gram molecular weight of zinc (that is the atomic weight of zinc divided by its oxidation number), which is 65.38/2 or 37.69 grams of zinc.
Since the density of zinc is about 7.14 g/mL, one Faraday will deposit 5.28 mL of zinc. If you have a surface area of 15,000 x 0.16 = 2400 dm^2, that's 240,000 cm^2. So one Faraday will deposit a thickness of 5.28/240000 or cm, that is 0.000022 cm or .22 micron. So for 0.8 micron thickness you would need 0.8/0.22 or 3.64 Faradays or 350,850 Amp-seconds. At 300 A, this would take 1170 seconds or 19.5 minutes. But efficiency is not 100 percent; it might be 50 percent for cyanide and 75 percent for acid zinc. So the plating time would be maybe 30 to 40 minutes :-)
But you might want to double check some of your units because they don't sound realistic to me. Perhaps your 0.8 µm thickness should be 10X thicker, or 8 µm -- which would be a very common thickness specification. And I have a hard time believing the barrel holds 240,000 cm^2 (258.3 ft^2) of work; 24000 cm^2 sounds more like it. But if your thickness is low by a factor of ten, and your area is high by the same factor, the answer is the same -- a reasonable 30 to 40 minutes of plating time :-)
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey
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