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"Zinc-nickel Plating, misc. Q & A's"



Current question:

September 20, 2021

Q. Hi all I'm new here and new to electroplating. I'm in the process of setting up my first electroplating setup and have been given a load of new nuts and bolts to be plated but they are already zinc plated in a silver finish and need to be yellow.
I have purchased a hobby plating zinc nickel kit and my question it this, can I plate straight over the existing zinc plate or will it have to be stripped off completely and started again?

Any help greatly appreciated.
Thanks
C

C B Evans
- Swansea, Wales
^


September 2021

A. Hi Cee. If you were a production plater, the answer would be yes you can proceed directly to plating over what you've got AND yes you have to strip them ... because sending the parts through an electroclean tank will strip the chromate anyway, and sending them on to the HCl acid dip will strip the zinc anyway.

I don't know exactly what you intend to do for pretreatment, but the chromate must be removed, and the existing zinc plating must be at least acid activated.

Luck & Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
Striving to live Aloha
finishing.com - Pine Beach, New Jersey
^


October 11, 2021

Q. Hi Ted thanks for the reply I'm just doing the plating for restoration projects. I have purchased [name of hobby plating supplier deleted by editor] zinc nickel kit so I'm using the chemicals supplied within that kit it has an acid pickle for before the electrolyte. You're saying I need to be stripping the chromate -- how is this done please?

I have had some success but somehow I keep getting what look like burn marks on the bottoms of some of my pieces any ideas how this is happening and what I can do to prevent it?
Thanks again hope to hear from you again.

C B Evans [returning]
- Swansea, Wales
^


October 2021

A. Hi again, Cee. The basic issue is that you can only successfully electroplate onto a waterbreak-free clean metal surface, and a chromate conversion coating is not metal.

The problem that arises for a hobby plater is that the simple way to remove a chromate conversion coating is to make it anodic in a strong caustic solution (similar to an electrocleaner) but this definitely generates hexavalent chromium -- the toxic, carcinogenic thing that made Erin Brockovich famous. A plating shop with a wastewater treatment system and employees with haz-mat training can easily deal with this -- a hobbyist not so well.

I guess what I would so is, while wearing a good dust mask, sand off as much of the thick chromate as practical, then immerse the part in an inhibited acid pickle, and assume that undercutting will occur, so as the zinc plating is removed, with it will go the chromate.

This site has approximately a quarter million questions posted, the majority having to do with plating defects, so please understand that it is rarely the case that anyone can get a quick answer to "this is what I see, what caused it?"   :-)

Usually we'll need good well-focused, representative, photos of the defect (attached in e-mail to mooney@finishing.com for posting here) together with some detailed data about what you are doing (concentration, temperature, time, surface area, volts & amps, sketches or photos of the arrangement) to move the guessing game along productively. 'Burning', if that's what it actually is, is caused by excessive current density for the situation, and is usually most pronounced at corners & edges because those are the areas which often receive the most current. 'Electricity follows the path of least resistance' is usually a helpful truism. But if your kit doesn't include a cleaning step, or at least cleaning instructions, you need to start there. You need exceptional cleanliness of the surface for successful plating.

Luck & Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
Striving to live Aloha
finishing.com - Pine Beach, New Jersey
^



October 8, 2021

Q. What is the best approach to remove zinc plating from fasteners and subsequently apply nickel plating?

The nickel coat is more durable than that of zinc, I presume?
Or the whole exercise is considered futile and I should retain the zinc coated fasteners?

I am currently restoring an old motorcycle and would like to nickel plate the zinc coated fasteners I purchased.

Many thanks in advance for your time.

Reuben

Reuben Bajada
- New Jersey, USA
^


October 2021

A. Hi Reuben. Although your question involves nickel plating, which is a very different thing than zinc-nickel plating, we added it to this thread because C B Evans just went through the same question as you about stripping the existing zinc plating, so that discussion should be applicable for you.

Although you're perfectly welcome to attempt zinc plating, zinc-nickel plating, or nickel plating there is one very big difference between them which refutes your "nickel coat is more durable than that of zinc, I presume?. That difference is that zinc and zinc-nickel are sacrificial coatings offering cathodic protection to steel, whereas nickel plating is at best a barrier-layer plating, but at worst it's anodic to steel and promotes the rapid rusting of steel. You are probably aware that steel boats and ships are often equipped with zinc anodes, the purpose of which is to sacrificially corrode to protect the iron/steel; ship anodes cannot be made of nickel because nickel is more noble that iron and the system would work exactly oppositely: the iron would corrode to protect the nickel.

Thus, imperfect zinc or zinc-nickel plating with a pinhole or porosity still offers substantial protection to the fasteners. Nickel plating must be perfect, completely free of pinholes & porosity, to function as a barrier coating; if a pinhole exists, the presence of the nickel will cause the fastener to sacrificially corrode. Thus it's usually not the right coating for a beginning hobbyist to apply if he is looking to add corrosion protection. If you want nickel plating, either buy nickel plated fasteners, or get very good at nickel plating :-)

Luck & Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
Striving to live Aloha
finishing.com - Pine Beach, New Jersey
^




Closely related Q&A's, oldest first:

2002

Q. Hi

I need the process for Zinc-nickel plating of metal parts (9SMn28K, SAE 1215)

I have the standard - DIN EN ISO 4042 [affil. link to spec at Techstreet]-P3R

Many Thanks

Shalom Barr
- Ashkelon,Israel
^



2003

Q. I have a challenge. I hope someone can help me up.

1. Is Zinc-nickel plating solderable?
2. Can Zinc-nickel be applied on aluminum?

We used to silver plate our aluminum microwave electronic equipment parts. This part is soldered on another also silver plated part for best contact between two parts. Keeping that contact is critical for our product. Right now, our product will be exposed to the harsh environment. In this situation the silver plating is going to change the color to black (corrosion). It looks terrible. We need some kind finish which is much more stable than silver plating, but solderable on substrates of aluminum.

Thanks,

Xiaoling
- Montreal, Quebec, Canada
^


2003

A. I have heard of Zinc/Nickel being tack welded, but not soldered. Also, you can apply the alloy to Aluminum if needed. Please remember that the purpose of Zinc/Nickel originally was to serve as an alternative to Cadmium plating on steel. Both are sacrificial, but the Cadmium is both toxic and a carcinogen. On Aluminum use good preparation including a good Double Zincate.

You may wish to investigate Tin/Zinc plating. It can be applied to aluminum, is solderable, and can be plated from either a neutral or alkaline solution. You can check your vendors for names of products.

ed budman eb sig
Ed Budman [dec]
- Pennsylvania
With deep sadness we advise that our friend Ed passed away Nov. 24, 2018

^



Zinc-Nickel plating of nails for pressure treated wood?

2003

Q. Part of our business is the zinc plating of 2.1/3.1 dia. nails for our customer who exports some to the US. We are told that because wood preservatives are no longer allowed to contain Arsenic there is a move towards a zinc/nickel requirement. For us this would be a major investment in new plant and any feedback as to this possible change would be greatly appreciated.

Many thanks,

Russell Waite
Presswork /Stampings and zinc plating - Ulverston, Cumbria, England
^


October 20, 2009

A. Hi, Russell. Indeed the older grades of pressure treated wood have been banned and the newer grades are very heavy in copper, which causes rapid corrosion of zinc plated nails. I don't know for a fact that zinc-nickel plated nails are any better. The most common satisfactory nails are hot dip galvanized. Good luck.

Regards,

Ted Mooney, finishing.com
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey
^



Zinc Nickel Plating in Military applications

2003

Q. What Types of Chemicals is Zinc Nickel resistant to? i.e., JP4, JP5, Coolants, etc.

Thanks

Pat Hale
harsh environment connectors - Naugatuck, Connecticut, USA
^


2003

A. Pat, zinc nickel electroplated steel is currently being used for fuel tanks on automobiles. The zinc nickel coated steel typically has an epoxy coating applied prior to the parts being formed. It is the combination of the pretreatment, epoxy coating and zinc nickel substrate which provide the resistance to the fuel and the corrosive environment, not just the zinc nickel.

Roy Nuss
Trevose, Pennsylvania, USA
^



A. Hi,

While Roy answered Pat's question well, and I learned from it, it should not be interpreted that zinc-nickel plating is never used "stand alone". To the contrary, almost anything that is zinc plated can probably benefit from the additional corrosion resistance of zinc nickel plating (or zinc cobalt plating) instead.

Regards,

Ted Mooney, finishing.com
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey
^



ZINC-NICKEL PLATING CHEMICALS REQUIRED

2004

RFQ: WE NEED CHEMICALS FOR DOING ZINC-NICKEL PLATING. IN INDIA. WHO IS THE SUPPLIER? IS THERE ANY POSSIBILITY TO GET THE CHEMICALS IN INDIA?

R.Ramarao Yalamanchi
plating shop - Hyderabad, Andhra Pradesh, India
^

^- Sorry, this RFQ is outdated
     View Current RFQs




Zinc-nickel plating on aluminum

2007

Q. Hi. I'm currently seeking to realize a zinc-nickel plating on aluminum parts.
For that, I have to make a double zincate.
In order to not dissolve my zincate in the zinc-nickel bath (which is very alkaline), I have been told to make a chemical nickel on my zincate.
But the cost of that kind of treatment is too expensive, so I would like to find an other way to realize my deposit.
I have also heard about a zinc plating realized with a cyanide zinc bath (less alkaline than zinc-nickel baths) before the achievement of the zinc-nickel plating.
Could you give me any advice to realize this treatment and, as far as possible, others ways to make my zinc-nickel plating.
Thanks for your help.

Simon Hallais
Student - France
^


January 16, 2013

Q. I would like to know the standard which is used for evaluating the Zinc nickel parts with base metal as aluminium.

RAMESH CN
- BANGALORE, KARNATAKA,INDIA
^


January 16, 2013

A. Hi Ramesh. There are no proper standards except those which were written into the purchase order. If you are in QA, that's what you'll need to find. If you are writing a purchase order and spec'ing parts, standards are available from ISO, ANSI, military, etc., but a starting point might be ASTM B253 [affil. link to spec at Techstreet] "Standard Guide for Preparation of Aluminum Alloys for Electroplating " and ASTM B841 [affil. link to spec at Techstreet] "Standard Specification for Electrodeposited Coatings for Zinc Nickel Alloy Deposits".

Good luck.

Regards,

Ted Mooney, finishing.com
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey
^



Color of Zinc-Nickel plated bushing

2007

Q. WHAT IS THE APPEARANCE (COLOR) OF A ZINC-NICKEL PLATED BUSHING?

Gersain Vejar
Sheet metal shop employee - Gardena, California, USA
^


2007

A. Alkaline Zn-Ni is a semi-bright coating. Take a look at aftermarket parts made for VW, Mercedes, or some other European automotive manufacturer, they commonly use this coating on fuel filters, etc.

Don't expect the "jewelry" bright look you get from zinc plating/clear chromate, particularly acid zinc. (I'm not familiar with the acid Zn-Ni process; it seems to me that the alkaline bath is more common and easier to run) But, as an old plating foreman I used to commiserate with, when his OC inspectors rejected parts for dull appearance, "the protection is there." Alkaline Zn-Ni is not the easiest process to run, nor is it much cosmetically, but it is a great finish when it comes to preventing rust.

That's the whole idea, at least it ought to be.

dave wichern
Dave Wichern
Consultant - The Bronx, New York
^


Is this part suitable for Zinc-Nickel plating?

17234-1
August 6, 2019

Q. Is the steel bracket suitable for Zinc-Nickel plating process?
The proposed process is Zinc-Nickel 0.0003" min thickness, 12-17% Ni Alloy, with Black Chromate and Organic Topcoat.
The steel stamping is made using a progressive die.
Dimensions of bracket are roughly 100 x 53 x 60 mm, material is 20 ga 1018 steel.

Luigi Cervantes
Quality Engineer - Burbank, California, USA
^

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