Aloha, fun & authoritative answers -- no cost, no registration, no passwords, no popups
(as an eBay Partner & Amazon Affiliate we earn from qualifying purchases)

Home /
T.O.C.
Fun
FAQs
Good
Books
Ref.
Libr.
Adver-
tise
Help
Wanted
Current
Q&A's
Site 🔍
Search
pub  Where the
world gathers for metal finishing
Q&As since 1989



-----

Electroplating Copper Chromium Alloy Deposit

TUTORIAL:
(to provide context, hopefully helping readers more quickly understand the Q&A's)

It is far more often the case that you can't electrodeposit a given alloy than that you can :-(

Why? Consider for example a student's lemon battery where a copper penny and a zinc coated nail are inserted into the conductive lemon juice and connected. A voltage of about 1.0 volts is generated as the copper pulls electrons from the zinc, causing the zinc to lose electrons and turn from metal to positively charged ions that dissolve into the acidic juice.

Now imagine trying to electrodeposit brass (copper-zinc) in this electrolyte. No sooner would an atom of zinc plate out as metal, than a copper ion next to it would steal its electrons, turning the zinc atom into a positively charged ion which dissolves again ... so your electrodeposit will be almost pure copper instead of brass.

There are some complexing tricks that can make plating of certain alloys (including brass) possible, but in general it's tough and usually it's impossible.

Q. As a mechanical engineer, I am looking to electroform or produce a heavy deposit of Copper 0.5-1% Chromium alloy (AMS C81500). The result will be heat treated to improve its strength and annealing resistance. I know that both copper and chromium can be electroplated from H2SO4 electrolytes. Can they be plated simultaneously to produce an alloy? Or will an attempt work like a tank house and produce electrolytically refined copper?

I would prefer to produce AMS C18000 but I suspect that electroplating the Si will be impossible.

John Pennucci
- Colchester, Vermont
May 12, 2022



"Electrodeposition of alloys: principles & Practice"
by Abner Brenner

on AbeBooks

or eBay or

Amazon

(affil links)

May 2022

A. Hi John. I strongly suspect that this is impossible. A quick scan of Brenner's 2-volume 1350-page tome on Electrodeposition of Alloys didn't seem to show anything promising, but if you can get to a library that has it, and if you have the time & inclination, it covers absolutely everything about electrodeposition of alloys :-)

Luck & Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
Striving to live Aloha
finishing.com - Pine Beach, New Jersey




(No "dead threads" here! If this page isn't currently on the Hotline your Q, A, or Comment will restore it)

Q, A, or Comment on THIS thread -or- Start a NEW Thread

Disclaimer: It's not possible to fully diagnose a finishing problem or the hazards of an operation via these pages. All information presented is for general reference and does not represent a professional opinion nor the policy of an author's employer. The internet is largely anonymous & unvetted; some names may be fictitious and some recommendations might be harmful.

If you are seeking a product or service related to metal finishing, please check these Directories:

 
Jobshops
Capital
Equipment
Chemicals &
Consumables
Consult'g, Train'g
& Software


About/Contact  -  Privacy Policy  -  ©1995-2024 finishing.com, Pine Beach, New Jersey, USA  -  about "affil links"