Aloha, fun & authoritative answers -- no cost, no registration, no passwords, no popups
(as an eBay Partner & Amazon Affiliate we earn from qualifying purchases)

Home /
T.O.C.
Fun
FAQs
Good
Books
Ref.
Libr.
Adver-
tise
Help
Wanted
Current
Q&A's
Site 🔍
Search
pub  Where the
world gathers for metal finishing
Q&As since 1989



-----

Remove sodium metabisulfite from Nickel Plating bath




Q. Sodium metabisulphite was added by mistake to Nickel plating path. How can I get rid of it?

asghar norouzi
- tehran, Iran
December 2, 2021


A. You don't say how much SMBS you added but you can render it innocuous by oxidizing it with Hydrogen Peroxide.

Geoffrey Whitelaw
Geoffrey Whitelaw
- Port Melbourne, Australia



January 18, 2022

A. First question is why was sodium metabisulphite added to a nickel bath? It is used as a passivating agent on nickel and in the separation of an electroform from a reusable mandrel. Assuming the nickel bath is used for electroforming, removal of the metabisulphite by adding hydrogen peroxide, as suggested by Geoffrey. This will convert it to sulphate, but then bath may become out of balance and if it is being used for electroforming, this could create issues with brightness and throwing power. It could also have secondary effects of hardness and stress if the extra sulphate throws the bath out of balance. Excess sulphate can be removed by the addition of barium salts and the precipitation of barium sulphate. Either way, I recommend re-analysing theh bath before any further work is sent through it.

trevor crichton
Trevor Crichton
R&D practical scientist
Chesham, Bucks, UK
January 14, 2022


thumbs up sign My guess is that someone mistook a bag of sodium bisulfite for a bag of boric acid due to language difficulties :-)

I'd probably mistake a bag of "$%^#B00!@$" for a bag of "@$!%^$#B00+#!" myself   :-)

Luck & Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
Striving to live Aloha
finishing.com - Pine Beach, New Jersey
January 2022




(No "dead threads" here! If this page isn't currently on the Hotline your Q, A, or Comment will restore it)

Q, A, or Comment on THIS thread -or- Start a NEW Thread

Disclaimer: It's not possible to fully diagnose a finishing problem or the hazards of an operation via these pages. All information presented is for general reference and does not represent a professional opinion nor the policy of an author's employer. The internet is largely anonymous & unvetted; some names may be fictitious and some recommendations might be harmful.

If you are seeking a product or service related to metal finishing, please check these Directories:

 
Jobshops
Capital
Equipment
Chemicals &
Consumables
Consult'g, Train'g
& Software


About/Contact  -  Privacy Policy  -  ©1995-2024 finishing.com, Pine Beach, New Jersey, USA  -  about "affil links"