Oxide Removal on Alloys: Powerful Acid Option for Ti

Summary for oxide removal on alloys Discussion

Removal of oxide on alloys comes up in the context of a 3-D printing finishing question. The only answer in the thread is from an unnamed contributor who says that, for a titanium finishing job years ago, they used a 1:1 mix of nitric acid (HNO3) and hydrofluoric acid (HF) to remove oxide, while warning that it is "scary stuff." The same answerer adds that ammonium bifluoride might work as a substitute for HF. Because the thread excerpt is brief, no broader process details, safety steps, or confirmation from other participants are provided. The practical takeaway is that oxide removal on titanium/alloys was reported using a very aggressive acid mix, with a possible alternative suggested, but the advice is clearly hazardous and should be treated cautiously.

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Q. Hi,
I have a titanium alloy (TI-6Al-4v) which was 3-D printed from SLM printer, which is heated to 450 °C in vacuum. Now I can’t read the surface of the alloy for micro hardness through the tester because of the oxides formed on the alloy. How can I remove the oxides formed on the alloy to have a clear view of the surface?

kali pogula
project – australia
April 18, 2017

simultaneous replies

A. When I had a Ti finishing job some years back, I used a 1:1 mix of HNO3 and HF. Scary stuff!

Ammonium bifluoride might work instead of HF.

dave wichern
Dave Wichern
Consultant – The Bronx, New York


? Are you saying that you can’t properly see and measure the diamond indentation because of the oxide?

Ken Kirby
– Kenosha, Wisconsin, USA

A. We electropolish 3-D printed titanium parts, but only small ones – the surface is very developed and consumes lots of AMPS.

60434

anna_berkovich
Anna Berkovich
Russamer Lab – Pittsburgh, Pennsylvania
(ed. update July, 2025: sorry, Anna has retired)