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topic 59342

RoHS Zinc Plating ASTM B633 Type III - are trivalent chromates ready for prime-time



A discussion started in 2013 but continuing through 2018

July 15, 2013

Q. We are converting zinc-plated part specs to RoHS (to ensure no hexavalent chromium).
I would like to maintain equivalent salt-spray corrosion resistance.
Looking through the forum I see people claiming that the trivalent chromates are:
much worse than..
almost as good as..
equivalent to...
better than...
hexavalent chromate. Since these answers span several years, it wasn't clear whether there was a consensus developing or even whether the answer had changed as the processes and formulations have evolved.
So - can I get a RoHS compliant ASTM B633 [affil. link to spec at Techstreet] Type III finish that is [corrosion] equivalent to the non-compliant hex-chrome version and if so, how do I clearly state that on a spec?

Paul Maier
Design Engineer - Lowell, Massachusetts, USA


July 17, 2013

A. Hello Paul,

The equivalent is ASTM B633 [affil. link to spec at Techstreet] Type V. You have the same thickness, you can have the same corrosion resistance. For clear blue chromates, trivalent are (in my opinion) far better than hexavalent ones. Take a try with a few in "lab scale" (2-3 gallons, a few parts) and have they tested for corrosion resistance.

For yellow chromates (B633 Type II), the equivalent is Type VI. But yellow hexavalent chromates are far better than yellow-colored trivalents, in my experience.

Well, I hope you can change to trivalent and improve your results (process cost, quality, and water treatment costs). Good luck!

Daniel Montanes
- Canuelas, Buenos Aires, Argentina


July 22, 2013

thumbs up signThanks for your response, Daniel. I talked to a local plater who also suggested the type V (and said that it was rated better than the old (non-RoHS) process. Your explanation about the yellow trivalents (type VI) not being as good as the yellow hex was also helpful. I think that may have explained why some folks on the forum were indicating that the trivalent wasn't up to par. In any case, I am going to move forward with a clear/blue type V and will run some tests. Once again - thanks for your input.

Paul Maier [returning]
- Lowell, Massachusetts, USA


November 20, 2013

A. The equivalent for yellow hexavalent chromate is a thick trivalent chromate, and the equivalent for clear hexavalent chromate is a thin trivalent chromate.

You can improve the corrosion resistance by applying a sealer on top of the trivalent chromate.

sara michaeli
Sara Michaeli sara michaeli signature
chemical process supplier
Tel-Aviv, Israel



November 20, 2013

A. Perhaps my experience is dated. But I believe that a trivalent "chromate" is merely a decorative finish. Somebody show me a part with that on it, with no sealer, that will stand up to a salt spray, and I'll become a believer.

I question the environmental benefit of using some "eco/green" finish when corrosion resistance, and hence the useful life of the part is lowered.

dave wichern
Dave Wichern
Consultant - The Bronx, New York


November 21, 2013

A. Hi David. You are extremely knowledgable in metal finishing, but in this specific area I do think recent progress in trivalent chromates may be substantial. Although today's trivalent chromates are not the equal of hexavalent in ALL ways, they are not the trivalents of the old days, and I believe they are the equal of hexavalents in salt spray resistance. My understanding, subject to correction by someone more knowledgable, is that the thin film trivalents generally require a sealer but the thick film chromates do not.

Regards,

Ted Mooney, finishing.com Teds signature
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey


January 3, 2014

A. Hello Ted,
I fully agree with your view.I have been connected with this finish for auto parts for multi national companies for the last 6 years ever since the arrival of trivalent chromate.They have been so remarkable in Salt-spray testing,one customer company has revised the hours for white corrosion from 96 to 140 hours now.

Subramanian Ramajayam
Subramanian Ramajayam
consultant - Bangalore, India



August 31, 2018 -- this entry appended to this thread by editor in lieu of spawning a duplicative thread

Q. We have a print that calls out for zinc ASTM B633 [affil. link to spec at Techstreet] fe/zn 5 sci type V. Our plating sources are unclear of what the V is:

Cathy Delbridge
- Sterling Heights, Michigan usa


August 2018

A. Hi Cathy. You and/or your plating shops need to spring for a recent edition of ASTM B633 [affil. link to spec at Techstreet] , rather than outdated versions. Type V is clear trivalent chromate ... but no one can certify to it, nor inspect compliance with it, based on just that one fact.

Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
Aloha -- an idea worth spreading
finishing.com - Pine Beach, New Jersey

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