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How to achieve Brown Zinc Chromate finish?

Quickstart:
     Zinc plated finishes would quickly exhibit 'white rust' corrosion unless they receive a chromate conversion coating, so they nearly universally do.
     A certain amount of chromate color variation may be selected; traditional hexavalent chromate may be clear/blue, iridescent gold/yellow, olive drab, or black. The modern trivalent chromates may have a more limited range but are dyeable.
     Some readers -- usually classic car enthusiasts -- periodically inquire about brown chromate. Although this has been a topic of discussion for several years now, most plating professionals seem unfamiliar with it and seem to feel that there never was a brown chromate, but that a yellow chromate or olive drab chromate might have aged to a brown color over the decades. Not everyone agrees.
     Read on, join in ...





Q. If I had a hexavalent chromate and I wanted the browns instead of blacks generally how much would I reduce the silver by?

Tommy Erwin
- Houston TX
February 2, 2026


"Zinc Electroplating"
by Muralidhara & Venkatesh
zincPlatingMuralidhara2016
on Amazon
or eBay
or AbeBooks
(affil link)

A. Hi Tommy,

Please offer context for me. What kind of parts, a handful or a major production run, and why do you want brown?

As you apparently realize, brown coatings are not what is usually expected from a black chromate solution -- brown coatings, brown areas, brown splotches are defects. Unfortunately, trying to produce aesthetic, consistent, robust defects is nearly an oxymoron, so I'm concerned that you could put a lot of effort into trying to get brown, without ever being able to produce a 'good' brown coating ... but more detail about what you're trying to do please.

Luck & Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com - Pine Beach, New Jersey

Need quick confidential answers? $25
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Q. This would be small batch as in a couple dozen for watch dials. Back in the day there were brass dials that were plated with zinc and then a silver based hexavalent black chromate was applied. Over time some of these black dials turned brown.

I know it's considered a failure but I am trying to mimic a patina. I'm totally okay with an organic look that isn't 100% uniform in a brown color. 
It seems like potentially exposing the black chromate to high dosage of UVC might work. Any chance heat and humidity would have any effect or even adjusting the pH of the bath itself? ⇦ Answer?

Tommy Erwin [returning]
Hobbyist - Houston, TX




⇩ Similar, related, Q&As -- oldest first ⇩



Q. Hello Again. Here is another item looking for help. How to achieve or purchase dichromate crystals of a brown color, not a reddish brown more like a root beer color. If need be, who does this?

This color is also a highly desirable finish used on Chrysler muscle car parts form 65 to 73. No one can seem to produce this finish.

Bill Meerholz
- Pompton Plains, New Jersey
August 14, 2012


A. Hi, Bill. Readers might not understand a verbal description of the color. Please try to <send pics for posting> if you can. Thanks!

Ted Mooney, finishing.com
Ted Mooney, P.E.
Striving to live Aloha

finishing.com - Pine Beach, New Jersey

Need quick confidential answers? $25
Need project assistance? $100/hr.


Q. Attached are some pictures of 2 different Chrysler original new never used or subjected to sun or bright lighting.

58797-1a brown chromate  58797-1b brown chromate  58797-1c brown chromate 

Base is definitely zinc or cad. Probably zinc. On the backside of the bigger catch you will see a spot where I applied few drops of 50% Muriatic acid & water. Took approx. 10-15 seconds to get to bare metal. The brown chromate does not scratch easily, as blacks do.

Can anyone shed any light on this question? ⇦ Answer?

Bill Meerholz [returning]
- Pompton Plains, New Jersey


What is brown zinc that was used on Chrysler parts late 60's-early 70's.

Q. What is brown zinc that was used on Chrysler parts late 60's early 70's. Hood latches, etc. ⇦ Answer?

Bill Meerholz [returning]
Restore many original Chrysler parts including hood latches that are the brown zinc finish. - Pompton Plains, New Jersey
October 23, 2016


Q. Can someone please advise something about this what is believed to be brown chromate or what it is or how to achieve it? What is the finish on latches pictured? ⇦ Answer?

Bill Meerholz [returning]
- Pompton Plains, New Jersey


58797
"Electrolytic and Chemical Conversion Coatings"
by Biestek & Weber

( Rarely avail. for purchase, but see library holdings on Worldcat.org)
biestek
on Amazon

or eBay
or AbeBooks
(affil link)

A. Hi Bill. Nobody has related their experience with this finish in over 4 years now. Here are two ways to get varied colors in chromating: dyeing the chromate or changing the operating conditions. The attached page
from Biestek & Weber
implies that brown chromating can be accomplished, without dyeing, by adjusting the sulphate ratio. I'm not sure how much practical help that will provide though :-(

Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com - Pine Beach, New Jersey

Need quick confidential answers? $25
Need project assistance? $100/hr.


A. The dark chromate conversion coating described and seen in the photos is one of two possibilities: (1) an olive drab chromate, or (2) a dark yellow chromate. In the more common yellow (or gold) chromates, if an article is
(a) left in the chromate for a longer period of time, or
(b) the chromate is too concentrated, or
(c) the pH is low, then the chromate will be dark, running towards brown. If the chromate is too dark, the chromate conversion coating will be friable and powdery, so these processing conditions are wisely avoided.

tom_rochester
Tom Rochester
CTO - Jackson, Michigan, USA
Plating Systems & Technologies, Inc.
supporting advertiser
plating systems & technologies banner ad




Trying to identify a 1950s anti-corrosion automotive metal finish

Volkswagon Type 2 Vans
volkswagon_type2
on eBay

(affil link)

Q. Hi

I own a 1956 VW Type 2 that, having lived most of its life in a dry climate, is mostly rust free and retains its original anti-corrosion coating in areas that were not directly exposed to abrasion and road spray. I'm trying to identify what coating that might be. My ultimate hope is that whatever coating was used, I might be able to reproduce it on repair patches.

The coating is a bronze colour and has a slight satin sheen. It does not appear to be a paint-type coating. It is very thin, does not flake and scratching it reveals bright steel with no primer coat.

58797-2

Other owners of VW Type 2s of that era have reported finding the coating on the inside of box sections etc, suggesting that the coating was applied by dipping and I have seen period production line photos showing VW dipping Type 2s. A period VW technical document mentions 'phosphatierung' (phosphating), but the coating is not grey and I believe that phosphate coatings are intended to be temporary protection and would have needed additional protection to have survived this long?

Can anyone suggest what the finish might be and whether it could be (safely) applied to modern steel repair patches by spraying or another means?

Andrew Cousins
- Horsham, West Sussex, UK
May 17, 2017


A. Hi Andrew. This component looks like a frame stiffener. If it's just part of the welded frame, it probably has the same coating the rest of the frame once had.

My guess is it's an early electrocoat priming but it's probably not really possible to figure it out just from the look of it. Hopefully someone will wander in who actually knows what VW did in those days.

Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com - Pine Beach, New Jersey

Need quick confidential answers? $25
Need project assistance? $100/hr.


A. Maybe that is some sort of combined phosphate and chromate finish. Hope it helps and good luck!

Goran Budija
- Zagreb,Croatia


Q. Thank you for the responses.

Am I correct to assume that, if the finish is a brown zinc chromate, it cannot be re-applied or applied to patch areas of repair on my vehicle?

On that assumption, I'll look to try to get a reasonable paint match and paint repaired areas to a suitable dividing point, so it's not so obvious. ⇦ Answer?

Andrew Cousins
- Horsham, West Sussex, UK


11694_autosteel

A. Hi again. Chromate only works on zinc plating (and a few other metals), not on steel. Further it is toxic and carcinogenic -- but I really don't think that's what it is anyway. So I think that rust converter on eBay or Amazon [affil link] followed by your paint idea may be the best approach. In the meantime, though, I stumbled upon this really informative paper which you might want to review

Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com - Pine Beach, New Jersey

Need quick confidential answers? $25
Need project assistance? $100/hr.


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