Aloha, fun & authoritative answers -- no cost, no registration, no passwords, no popups
(as an eBay Partner & Amazon Affiliate we earn from qualifying purchases)

Home /
T.O.C.
Fun
FAQs
Good
Books
Ref.
Libr.
Adver-
tise
Help
Wanted
Current
Q&A's
Site 🔍
Search
pub  Where the
world gathers for metal finishing
Q&As since 1989



-----

Removing chrome oxide passivation layer from stainless nano particles




Q. I want to etch off the Cr oxide passivation on stainless steel nano particles using HCl. Is this a clean and controlled process? After the etch, I want to keep the particles from repassivation. Any suggestions?

Sudarsan U
- Portland, Oregon, USA
August 12, 2012



A. Sudarsan,
I've never had any experience in nano-scale applications, but I suspect that an HCl etch, especially on that scale, would not be considered clean or controlled. You might want to search this forum for previous questions and the responses concerning treatments to activate the surface of stainless for electroplating.

Preventing repassivation should be as simple as not exposing your particles to citric acid, nitric acid, or air.

ray kremer
Ray Kremer
Stellar Solutions, Inc.
supporting advertiser
McHenry, Illinois
stellar solutions banner
August 13, 2012


A. We agree with Ray. Etching in HCl is a harsh process for nano-particles. If passive layer is removed, the particle will immediately dissolved in the acid. In order to replace the initial passive film by the new one, it is necessary to apply the process of slow passive dissolution. During such process the initial passive film will slowly dissolve in the solution, and the new passive film of required thickness and composition will grow.

anna_berkovich
Anna Berkovich
Russamer Lab
supporting advertiser
Pittsburgh, Pennsylvania
russamer labs banner
September 11, 2012




(No "dead threads" here! If this page isn't currently on the Hotline your Q, A, or Comment will restore it)

Q, A, or Comment on THIS thread -or- Start a NEW Thread

Disclaimer: It's not possible to fully diagnose a finishing problem or the hazards of an operation via these pages. All information presented is for general reference and does not represent a professional opinion nor the policy of an author's employer. The internet is largely anonymous & unvetted; some names may be fictitious and some recommendations might be harmful.

If you are seeking a product or service related to metal finishing, please check these Directories:

 
Jobshops
Capital
Equipment
Chemicals &
Consumables
Consult'g, Train'g
& Software


About/Contact  -  Privacy Policy  -  ©1995-2024 finishing.com, Pine Beach, New Jersey, USA  -  about "affil links"