Blue Zinc is turning yellow over time
A discussion started in 2008 but continuing through 2018December 13, 2008
Q. Dear sir,
We are facing a problem in Zinc plating Blue passivation, After 10 to 12 Weeks, passivation is converting to yellow passivation; we are not able to find out the problem.
plating division - Bangalore, Karnataka, India
December 18, 2008
Could you please provide us with some more information? For example is this a hex or tri clear? What types of parts are these? What conditions are the parts subjected to during these 10-12 weeks? Is the corrosion performance still up to par after the yellowing? What are the chemical properties of the bath? Etc.
The more information that you can give us the better.
David J. Wolf|
December 26, 2008
Q. Dear Sir,
We are fasteners platers from chennai, India and we are facing the problem of discoloration of trivalent blue passivation on storage. The silver-tone color changes to pinkish yellow on storage of 3-5 weeks. The Salt spray like is unaffected. The discoloration takes place even in new passivation bath which means zinc and iron contamination cannot be the reasons. Hexavalent passivation from the same plating baths are good and meets the salt spray expectations.
Can any one help. Thanks in advance.
process incharge - Chennai, Tamilnadu, India
June 26, 2012
I am seeing a yellowish tinge in blue passivated parts, mainly on the edges. How could that happen -- is it because of a cyanide bath? Normally RoHS compliant passivations use non cyanide bath ... is it that reason?
- Kochi, Kerala, India
A. Dear Arun,
When there are yellowish tinges on the edges, mainly is a iron content problem of the zinc bath, or the blue chromate concentration is too high.
We see that problem in barrel pieces and solve it with diluted (5%) hydrogen peroxide. Do you test the zinc bath with Hull cell? If you do, you could test it in Hull cell (2 A, 5 minutes, with agitation) and chromate the plates with and without peroxide added. Then you could make a conclusion!
Hope you could solve your issue. Best regards,
Self-Drilling Fasteners Manufacturer - Cańuelas, Buenos Aires, Argentina
Two acid zinc tanks give perfect blue but two give yellowish tintFebruary 8, 2014
Q. We have 4 Rack acid zinc plating tanks. Material from two tanks gives perfect blue tint after blue passivation. While the material from other two tanks have yellowish tint after blue passivation.
Can you suggest a remedy?
- Lahore, Punjab, Pakistan
A. Hi Shazer. You are fortunate to have a rather consistent issue rather than an off and on problem. I think Step 1 is to do Hull Cell testing of the four baths. Because of the consistent nature of the problem this testing ought to quickly reveal whether the problem is in the chemistry of the bath vs. elsewhere. Good luck and please get back to us.
Ted Mooney, P.E.
Pine Beach, New Jersey
February 22, 2014
A. When I used to have this problem it was mostly due to iron contamination of the bath. But maybe there could be another reasons for that problem.Daniel Hernandez Guerra
- Bucaramanga Santander Colombia
February 24, 2014
A. The yellow chromate of a blue chromate formation coming out of a chloride solution is most likely high iron contamination.
Robert H Probert
Robert H Probert Technical Services
Garner, North Carolina
March 10, 2018
Q. I have a problem, after blue zinc and pack with plastic bag the next day it become yellowishJames kt
electroplating Malaysia - johor Malaysia
A. Hi James. I think the first step is to leave a part unwrapped, wrap a part in paper, & wrap a part in different plastic and see whether the problem is related to the wrapping material/method or whether the yellowing always appears irrespective of the wrapping. Good luck.
Ted Mooney, P.E. RET
Pine Beach, New Jersey
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