Summary for sulfuric acid measurement Discussion
Sulfuric acid measurement in this thread is answered with simple acid-base titration methods. John Martin recommends pipetting a 1 ml sample into a flask, diluting it with 100 ml water, adding methyl orange, and titrating with 1.0N NaOH to a yellow endpoint; he says to calculate % acid as ml of 1N NaOH × 2.5. Teody Delgado offers a second approach: weigh 1 gram of sample, add 100 ml deionized water, use phenolphthalein, and titrate with 1.0N NaOH, then calculate with volume of titrant × 4.904 / weight. The original question from Fredy Lie asks how to measure the composition of sulfuric acid for an aluminium extrusion factory. The thread presents practical lab titration formulas rather than instrumental analysis, and the two answers differ mainly in sample handling and indicator choice.
Q. Hi I’m Freddy from Indonesia, I’m running an aluminium extrusion factory here in Jakarta. What I would like to ask you is how do I measure the composition of a sulfuric acid. I hope you could give me an answer soon, thank you.
Fredy Lie
PT Alumex Perkasajaya – Jakarta, Indonesia
2005
“Analysis of Electroplating & Related Solutions”
by Langford & Parker

on Amazon
or
<!–
(UTL on eBay)
eBay
or
–>
(affil link)
“The Chemical Analysis of Electroplating Solutions”
by Terrance H Irvine

on Amazon
or
or
(affil link)
A. Pipette
[pipettes on
eBay or
Amazon [affil link]
a 1 ml sample into a flask and dilute with 100 ml water.
Add 4-6 drops methyl orange
⇦ on
eBay or
Amazon [affil link]
indicator solution.
Titrate with 1.0N NaOH [1N NaOH on
<!–UTL 3/17/24
eBay &
–>
Amazon [affil link]
until yellow end point.
Calculation:
ml of 1N NaOH x 2.5 = %acid
John Martin
– Wales
2005
A. Weigh 1 gm sample in erlenmeyer flask ⇦ on
eBay or
Amazon [affil link]
add 100 ml D.I. water
with 3 drops phenolphthalein
⇦ on
eBay &
Amazon [affil link]
indicator
titrate with 1.0N NaOH
calculations:vol.of titrant*4.904/weight
Teody Delgado
– Manila, Philippines
2006