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topic 34839

Want good salt spray hours from phosphating without oil

Current question and answers:

January 13, 2021

Q. Hi,

We are following below process in out Mn/Zn Phosphating:

Degreasing-->Water Rinsing-->Activation-->Phosphating-->Water Rinsing-->Passivation-->Dewatering-->RP Oiling

Now as we know phosphating layer should provide corrosion resistance itself, so can we eliminate RP Oiling operation??

We have taken trial of the same and found rust in approx. 12 Hours in Mn phosphating part without RP oil.

Please help how we can improve rust life without RP oil.

Thanks,

Keyur Solani
- Ahmedabad, Gujarat
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January 2021

A. Hi Keyur. Hexavalent chromating will help, and you can apply a clear wax instead of oil, and our friend VG advises us below that a small grain size will help because it's less porous.

But can you tell us what you are trying to accomplish -- i.e., why you want/need to operate in that fashion, and what you want the salt spray test to tell you? Will the parts eventually be painted, or are they internal machine parts which will eventually be bathed in oil?

The twin issues here are that phosphate is not designed or intended to be a final finish, and salt spray testing is not intended to predict corrosion resistance in the real world -- with the result that even after all your efforts the salt spray hours your un-oiled phosphate survives may remain little more than just a random number :-(

I worked with a firearms manufacturer who sometimes stripped the oil off of parts and then re-oiled them. Parts that were stripped of oil could sometimes flash rust in 20-30 minutes; but sometimes something would come up and they didn't get re-oiled that day but they did not rust even in nearly 24 hours. They didn't concentrate on trying to figure out all the tiny variations that might account for the 24-hour survival ... they focused on getting them re-oiled immediately. I'm afraid that you may find randomness rearing its head; and just when you think you've got a big improvement going, a part will only survive 3 salt spray hours :-(

Luck & Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
Aloha -- an idea worth spreading
finishing.com - Pine Beach, New Jersey


March 2, 2021

A. Manganese phosphate is rather thin and will provide little protection by itself. Zinc phosphate is much thicker and will be better, but both are better with a thin organic coating of water soluble wax.

jeffrey holmes
Jeffrey Holmes, CEF
Spartanburg, South Carolina




Previous closely related Q&A's starting in:

2005

Q. We have a customer requirement for a component with Zinc phosphating thickness of 7 to 10 Micron and salt spray test to cross 72 Hours.

We have tried with various chemicals and we are able to meet only 30 Hours with 7 to 10 Microns.

Is it possible to meet 72 Hours with 7 to 10 Microns thickness.

If it is possible please send me process sequence and chemical details.

Thanks and Regards

M.Mohanan
PLATING SHOP - Chennai, TamilNadu and India
^- Reply to this post -^


2005

A. Salt Spray life is mostly dependent on the rust preventive which is applied over the phosphate. Any of the major suppliers can give you a heavy wax or oil which will meet 72 hours.

jeffrey holmes
Jeffrey Holmes, CEF
Spartanburg, South Carolina


sidebar 2005

A. Mr Mohanan
It is possible to examine this approach.

Plate 7 microns Alkaline Cyanide free zinc. Chromate.
Paint .

SST will exceed your needs -- 120 hours.
Regards

asif_nurie
Asif Nurie [dec.]
- New Delhi, India
With deep regret we sadly advise that Asif passed away on Jan 24, 2016



2005

A. Hello Mohann;

You need to use a water soluble topcoat, the kind they use over zinc plating, over your phosphating, it may work.

Khozem Vahaanwala
Khozem Vahaanwala
Saify Ind
supporting advertiser
Bengaluru, Karnataka, India
saify logo


affil. link
"Phosphating of Metals"
by Werner Rausch
from Abe Books
or
info on Amazon

2005

A. The phosphate coatings are basically a conversion coating. Your chemical supplier can give a chemical to get a coarse crystal conversion or a fine crystal conversion coating. If you go for a coarse crystal formation, the coating is porous, which will corrode fast. This type of coating is generally preferred for preparation before painting, so that the paint can adhere well with the pores.

For a plain phosphating you should go for a fine crystal formation. You need to convert these phosphate coatings with an additional chromating conversion, which is very simple dip in a chromate solution. This fine crystals will have very low porosity, and can have about 12 to 24 hours salt spray resistance without oiling.

An additional good quality of rust preventive oil in combination with zinc phosphate and chromate can give up to 96 hours salt spray resistance.

v g rajendran
V. G. Rajendran
- Trichy, Tamilnadu, India


2007

Q. We are doing zinc phosphating process. Our product is corroding only in later stages. What are all the reasons for corrosion of products on later stages.

K.Dharmaraj
- Coimbatore, Tamil Nadu, India
^- Reply to this post -^


A. Hi Dharmaraj. Unfortunately there is simply no way to approach the problem from that direction because failure can come from numerous problems with the substrate, the pretreatment, the phosphate process per se, the post-treatment, handling & packaging, shipping, exposure conditions, or mis-specification. Instead you must describe what you are doing and exactly what you mean by "corroding only later stages". Thanks, and sorry.

Regards,

Ted Mooney, finishing.com Teds signature
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey



To minimize search efforts and to offer multiple viewpoints, we combined previously separate threads onto this page. Please forgive any resultant repetition, failures of chronological order, or what may look like readers disrespecting previous responses -- those other responses may not have been on the page at the time :-)



Salt spray test hours for zinc phosphated panels?

affil. link
"Phosphating & Metal Pretreatment"
by Freeman
from Abe Books
or
info on Amazon

May 26, 2010

Q. I want to know that what is the SST Range of Phosphated panels. I use Tri-cation Zinc Phosphate and Stages are as follows:
Cleaning
W/R
Derusting
W/R
Phosphating
W/R
Chrome free Passivation

S. Singh
Paint Shop - Faridabad, Haryana, India
^- Reply to this post -^


May 28, 2010

A. A phosphated panel that has not been painted or does not have a protective coating applied will corrode very quickly in a salt spray chamber, probably less than three hours.

George Gorecki
- Naperville, Illinois


June 4, 2010

A. Phosphating is a pre-treatment and not a finish. Hence, it cannot offer much resistance to corrosion in salt spray test.

One of the important attributes of phosphate conversion coating is its ability to prevent underfilm corrosion.

Measurement of the extent of spreading of corrosion from the scribed region of the phosphated and painted panel compared to its non-phosphated counterpart will give an idea about the quality of the phosphate coating.

T.S.N. Sankara Narayanan
T.S.N. Sankara Narayanan
- Chennai, Tamilnadu, India
(ed.note Nov. 2017: The good doctor has a fascinating blog at https://advancementinscience.wordpress.com)


June 19, 2010

A I have done the salt spray test on a tri cationic cold zinc phosphating, and have the certificate from a testing body that my panel lasted 23 hours under salt spray chamber.

Shankar Khandelwal
- Coimbatore, Tamilnadu, INDIA


! Hi, Shankar. Thanks!

This then begs the question of what wax or oil was applied to the phosphate, either deliberately or inadvertently, which may account for the salt spray survival time? I think if you degrease the panel after phosphatization to remove those greases and oils you may find that you won't even get 23 hours in normal atmosphere, let alone in a salt spray chamber :-)

Regards,

Ted Mooney, finishing.com Teds signature
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey


July 7, 2011

Q. I would like to know how many hours salt spray test will pass for Phosphated parts (ED coating - semi finished part)?

Sathis Kumar
Product designer - Tamilnadu, India
^- Reply to this post -^


July 2011

A. Hi, Sathis.

I'm not sure if I understand the question in light of the previous responses, where you heard estimates from 3 hours for zinc phosphate to 23 hours for tricationic. If you can phrase your question in terms of the previous responses, with what type of phosphating you are applying, and additional details, maybe an estimate can be offered -- but I personally think that Mr. Sankara offered a very insightful answer, i.e., that testing a scribe mark in a phosphated and painted panel is the proper way to judge the quality of the zinc phosphate pretreatment, and salt spray testing at an intermediate stage in the process is not particularly useful. Good luck.

Regards,

Ted Mooney, finishing.com Teds signature
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey



August 12, 2011

Q. We would like to know the life of zinc phosphated components in neutral salt spray test and normal atmosphere.

VIJAY GUNJAL
phosphating optr - Aurangabad, India
^- Reply to this post -^


August 17, 2011

A. Hi, Vijay.

George Goreki estimated 3 hours in salt spray. If all of the oil has been stripped, I'll estimate a day in normal atmosphere; I've seen flash rusting much sooner than that.

As noted, phosphatization is not a final finish; because of that, arbitrary and inconsistent factors may have more influence on the corrosion resistance than the quality of the phosphatization. This frames the question as whether there is any value at all in such testing or you are just throwing away money and resources by conducting such a test. :-(

Please try to tell us your situation, and please very slowly re-read Mr. Sankara's response and try to profit from what I feel is its wisdom. Thanks and good luck!

Regards,

Ted Mooney, finishing.com Teds signature
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey



May 7, 2013 -- this entry appended to this thread by editor in lieu of spawning a duplicative thread

Q. Hello All,

I am a Master of Science Student in Chemical Engineering Department. I am researching corrosion protection on steel to which Zn Phosphating was applied.

These materials stay for 5 hours in salt spray test, and test is passed. But when I transport these materials, corrosion seems on material.

Do you have any idea to solve these problems ?

Best Regards

Duygu

Duygu Adgzl
- Bursa, Turkey
^- Reply to this post -^


May 15, 2013

A. Hello Duygu,

The panels were put in a salt spray chamber AND transported or the panels you put in the salt spray chamber are a sample of the ones that you transport?

I agree with Ted, phosphating is a pretreatment, a finish could be if you treat it with some anti-corrosive product (water-displacement oil, for example), or paint it (epoxy, KTL).

If your panels last 5 hours in salt spray chamber, I suppose they can last several hours in normal (dry) atmosphere.

Please tell us some more details :)

Regards,

Daniel Montanes
- Canuelas, Buenos Aires, Argentina



May 26, 2016 -- this entry appended to this thread by editor in lieu of spawning a duplicative thread

Q. What oils are recommended to apply after zinc phosphate coating to withstand 72 hours of salt spray test.

Alok Gaur
- Mumbai, Maharashtra, India
^- Reply to this post -^


June 15, 2016

A. Hello Alok,

You can use some heavy water displacement oil, there are many vendors capable of help you out of this requirement. Only, as I recall in my process, you must have more than 10 g/m2 of phosphate in the surface you want to protect. If you can use hexavalent chromium, I recommend a phosphate sealer before you apply the oil. You can't lose!

Hope I could clarify something! Best of lucks,

Daniel

Daniel Montanes
N Ferraris S.A. - Canuelas, Buenos Aires, Argentina



July 2, 2019

Q. Hi I want to know how many hours of salt spray life of zinc phosphate coated material. We are phosphate coating mild steel rod and dipping time is 45 minutes.
Thanks

harish singh
- rudrapur udham singh nagar, india,
^- Reply to this post -^


July 2019

A. Hi Harish. The way I read the helpful answers offered, 72 hours is a good target if you are doing the phosphating correctly with quality materials and are applying a proper rust-preventative. How many hours are you actually getting? Remember that the purpose of a salt spray test is to learn whether you are currently doing it right, not to extrapolate anything.

Regards,

pic of Ted Mooney
Ted Mooney, P.E. RET
Aloha -- an idea worth spreading
finishing.com - Pine Beach, New Jersey

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