Summary for ammonium ion removal Discussion
Removing ammonium ion in effluent was discussed as a treatment problem with two very different approaches. The original question asked whether sodium hypochlorite is effective for removing ammonium from effluent, how much would be needed, and whether alternatives exist. Tom Baker warned that while bleach can remove ammonia from effluent, the byproducts are worse than the ammonia itself, so he advised digging deeper before using that route. Lyle Kirman предложed zeolite ion exchange as a practical alternative, specifically clinoptilolite, a naturally mined clay material available in granular form. He noted that ammonia can be regenerated off the zeolite with brine or mild caustic, or the media can be used once if the ammonia load is small. He cited typical capacities above 0.25 lb ammonia per cubic foot and removal to below 1 mg/L, and said optimum performance requires the ammonia to be in NH4+ form at about pH 7 or slightly lower.
Q. Ammonia in effluent I have seen reference to the use of sodium hypochlorite in removing Ammonium from effluent. Is this effective, how much is needed or is there any alternative?
Geoffrey Whitelaw
– Port Melbourne, Australia
2004
A. Geoff,
Don’t try it! Google “dangers of ammonia
⇦ on
eBay or
Amazon [affil link] and bleach” or go to https://www.bbc.co.uk/dna/h2g2/classic/A795611 for more information. It will remove ammonia from effluent but the byproducts are worse than the ammonia. I’d dig a little deeper before trying this one.
Trent Kaufman
electroplater – Galva, Illinois
A. Actually, the use of super chlorination is an effective, but expensive, method to treat ammonium ions in water. Trent is correct – the mixture of ammonia and bleach can be downright deadly, but we are looking at water borne concentrations that will not typically gas, and you have to use pH control to keep the ammonium ion as NH3, not NH4.
I think that you will find there are much better ways to treat this, depending on the amount of ammonia present, any applicable air discharge regulations (for one technology), and also alternate technologies. We had a client that we put an advanced oxidation technology into for ammonia removal a few years back coming off his CN treatment system after the POTW applied a most stringent free ammonia limit to his effluent. A combination of ozone/UV at the proper pH worked quite well, and was also highly cost effective compared to the super chlorination approach.
Tom Baker
wastewater treatment specialist – Warminster, Pennsylvania
A. One way to remove ammonia from water is to us zeolites as an ion exchange media. Clinoptilolite, a naturally mined clay material is particularly effective and is available in granular form. ammonia can also be regenerated back off of the zeolite in a concentrated form using brine or mild caustic.
If the quantity of ammonia is small enough, then one time use of the zeolite may be practical, since it is fairly inexpensive. Typical capacities are over 0.25 lbs of ammonia per cubic foot of media, and removal to < 1 mg/L is possible.
If you want to test this, you could try using cat litter ⇦[this on
eBay or
Amazon affil links]
, since it is primarily a similar type of zeolite.
For optimum results, the ammonia needs to be in the NH4+ form, which requires a pH of 7 or a little lower.
Lyle Kirman
consultant – Cleveland Heights, Ohio