finishing.com -- The Home Page of the Finishing Industry

HomeFAQsSuggested
Books
Help
Wanteds
Advertise
on this site
FORUM
current topics
Live! From beautiful Pine Beach New Jersey: Welcome to the world's most popular metal finishing website

topic 32350

Removing ammonium ion in effluent


2004

Ammonia in effluent I have seen reference to the use of sodium hypochlorite in removing Ammonium from effluent. Is this effective, how much is needed or is there any alternative?

Geoffrey Whitelaw
Geoffrey Whitelaw
- Port Melbourne, Australia


2004

Geoff,

Don't try it! Google "dangers of ammonia and bleach" or go to http://www.bbc.co.uk/dna/h2g2/classic/A795611 for more information. It will remove ammonia from effluent but the byproducts are worse than the ammonia. I'd dig a little deeper before trying this one.

Trent Kaufman
Trent Kaufman
   electroplater
Galva, Illinois



2004

Actually, the use of super chlorination is an effective, but expensive, method to treat ammonium ions in water. Trent is correct - the mixture of ammonia and bleach can be downright deadly, but we are looking at water borne concentrations that will not typically gas, and you have to use pH control to keep the ammonium ion as NH3, not NH4.

I think that you will find there are much better ways to treat this, depending on the amount of ammonia present, any applicable air discharge regulations (for one technology), and also alternate technologies. We had a client that we put an advanced oxidation technology into for ammonia removal a few years back coming off his CN treatment system after the POTW applied a most stringent free ammonia limit to his effluent. A combination of ozone/UV at the proper pH worked quite well, and was also highly cost effective compared to the super chlorination approach.

tom baker
Tom Baker
   wastewater treatment specialist
Warminster, Pennsylvania



2004

One way to remove ammonia from water is to us zeolites as an ion exchange media. Clinoptilolite, a naturally mined clay material is particularly effective and is available in granular form. Ammonia can also be regenerated back off of the zeolite in a concentrated form using brine or mild caustic.

If the quantity of ammonia is small enough, then one time use of the zeolite may be practical,since it is fairly inexpensive. Typical capacities are over 0.25 lbs of ammonia per cubic foot of media, and removal to < 1 mg/L is possible.

If you want to test this, you could try using Cat Litter (non clumping) [linked by editor to product info at Amazon], since it is primarily a similar type of zeolite.

For optimum results, the ammonia needs to be in the NH4+ form,which requires a pH of 7 or a little lower.

Lyle Kirman
consultant - Cleveland, Ohio



If you have a question in mind which seems off topic, please Search the Site

ADD a Q, A, or Comment on THIS topic START an UNRELATED topicView CURRENT HOT TOPICS

Disclaimer: It's not possible to diagnose a finishing problem or the hazards of an operation via these pages. All information presented is for general reference and does not represent a professional opinion nor the policy of an author's employer. The internet is largely anonymous & unvetted; some names may be fictitious and some recommendations may be deliberately harmful.

  If you need a product/service, please check these Directories:

JobshopsCapital Equip. & Install'nChemicals & Consumables Consult'g, Train'g, SoftwareEnvironmental ComplianceTesting Svcs. & Devices


©1995-2019 finishing.com, Inc., Pine Beach, NJ   -   About finishing.com   -  Privacy Policy
How Google uses data when you visit this site.