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Problem of discoloration/tarnish of brass components


Q. We are component manufacturers for Automobiles, Defence and agricultural industries. Recently we started having problems with one of our brass tubular sleeves(25 mm OD x 35 mm length). They were being returned due to discoloration/tarnish. Is there a cost/time effective way to solve this problem. Currently our final operation is to ball burnish these parts after a quick acid dip (dil H2SO4). Please advise.

Thanks

Praj Amin
Component Manufacturer - Bombay, Maharashtra, India
2004


"The Chemistry of Benzotriazole Derivatives"
benzotriazole
on Amazon
or eBay
or AbeBooks
(affil link)

A. Dear Praj,

If you can think of having chemical dip as a final treatment, tarnishing may be avoided, by using an additive 1,2,3 Benzotriazole(BTZ) on eBay or Amazon [affil link] in your chemical dip, the concentration may be 1%.

Just try out, Good Luck.

Keshava Prasad M
- Bangalore


A. Ref. a book -- technica przeciwkorozyina-warszawa-1973 (russian trans)-page105 -- brass may have what they call seasonal cracking, that may be seen if the metal is stessed or if there is ammonium (NH3) in the air. A high percentage of chlorides, sulfur, or ammonium in soil would increase rate of corrosion.

Cair Shishani
Khair Shishani
aircraft maintenance - Al Ain, UAE


A. Dear Mr. Praj Amin

The problem seems to be due to dezincification. Use of 1, 2, 3-benzotriazole (as suggested by Mr. Keshava) as corrosion inhibitor (CI) is generally recommended. However there are several new and effective CI available. The usage condition (i.e. temperature, duration and concentration of CI etc.) is more important in all cases.

D. JAMAL
- Pune, India


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