Stainless Steel Passivation Process: Helpful, but Limited

Summary for stainless steel passivation process Discussion

stainless steel passivation process is discussed as a preventive step for 304 and 316 stainless, especially when corrosion is already a concern. Janire Pagai asks when passivation is recommended for stainless items in a metallurgical research setting. Rosina Gómez replies that passivation is always recommended for stainless steel to preserve integrity and should be done periodically to avoid corrosion, with extra importance in corrosive atmospheres such as salt areas and high humidity because it removes free iron that promotes rusting. Guillermo Marrufo adds an important caution: 304 and 316 are still relatively low-alloy, lower-corrosion-resistant grades and can be attacked by chlorides, stray galvanic currents, or strong oxidizing environments even if properly passivated. He suggests that, for severe service, a high-nickel alloy may be more appropriate. The thread therefore frames passivation as helpful maintenance, but not a cure for unsuitable alloy selection or aggressive exposure.

Q. Hello,

I work as a Chemical Engineer in a metallurgical research center. We have a customer who has a quite important problem with corrosion in some stainless steel items and in order to provide him a solution for his problem we are really interested in knowing in which cases is recommended to use or can be used the passivation process, specially in 304 and 316 SS.

Thanks in advance.

Janire Pagai
Chemical Engineer – Durango, Bizkaia, Spain
2004

A. Hello Janire Pagai,

The passivation process is always recommended for Stainless Steel in order to preserve the integrity of it. The passivation process should be done periodically to avoid corrosion problems. When the atmosphere is really corrosive like salt areas and high humid it is really important to passivate, eliminating the free iron that promotes the corrosion. Do you speak Spanish, Janire? adv. We have a lot of experience in passivation of stainless steel and we can help you.

Regards,

Rosina Gómez
Stellar Solutions, Inc.
supporting advertiser
McHenry, Illinois
stellar solutions banner
2004

A. Just to add that the grades of stainless steel you mention are considered low alloy, low corrosion resistant. They will be attacked in presence of chlorides, stray galvanic currents or strong oxidizing environments even if properly passivated. In order to avoid this a high nickel alloy would be appropriate.

Guillermo Marrufo
Monterrey, NL, Mexico
2004