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Phase structure of galvanized zinc on sheet steel




Q. Dear Sir,

I am really want to know the structure of Zinc sheet (tole). If can, you advise me where I can get this information! And also you can tell me the basics of tole (formula, the thickness of each level!)

Thanks a lot and warm regards!

Jackie Thu
Student - Dong Nai, Viet Nam
2003


A. Do you mean zinc-coated sheet steel? Formulas and thicknesses of layers make sense for galvanized steel produced by hot-dipping in molten zinc. The liquid zinc alloys with the steel (iron) to form the phases of the Fe-Zn phase diagram: Fe (containing up to 6.3 wt% Zn at its surface), Gamma (20.5-28 wt% Fe), delta (7-10% Fe), zeta-FeZn13 (6-6.2% Fe) and Zn.

The Gamma layer comprises about 1% of the coating thickness, delta about 5%, zeta about 40%, and the Zn surface layer being the remainder. There is some intermixing of the zeta and zinc phases.

A common galvanized coating specification (U. S. and EN ISO 1461) is 2 oz/square foot (600 g/sq.meter) by weight, or 0.0033 inch (85 microns) by thickness.

The American Galvanizers Association publication "Zinc Coatings" shows cross-sectional microstructures of zinc coatings: https://www.galvanizeit.org/resources/files/AGA%20PDFs/T_ZC_00.pdf

Updated URL, June 2013:
https://www.galvanizeit.org/about-hot-dip-galvanizing/what-is-hot-dip-galvanizing/the-hdg-coating/zinc-coating/

The European Galvanizers has a product fact file showing a similar Fe-Zn galvanize microstructure, with text available in 5 languages, e.g., the Spanish version at http://www.egga.com/fact/spanish/02/industry.htm

Ken Vlach [deceased]
- Goleta, California
contributor of the year Finishing.com honored Ken for his countless carefully researched responses. He passed away May 14, 2015.
Rest in peace, Ken. Thank you for your hard work which the finishing world, and we at finishing.com, continue to benefit from.





Fe-Zn intermetallic compounds during galvanization

Q. When will Delta, Zeta, Gamma phases form during Galvanization?
Does Aluminum in zinc bath affect the Fe-Zn phases?

Abhilash Kotha
- Hyderabad, Andhra Pradesh, India
June 24, 2013




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