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Soldering Brass -- Discoloration Problem

Quickstart:
     Brass is an alloy of copper and zinc. But various actions can cause a degree of "de-zincification" such that some of the zinc is dissolved, leaving a copper-rich surface. This is sometimes manifested as a copper-colored or pink discoloration.
     Read on, join in ...

Q. WHEN SOLDERING .032 BRASS TO .032 BRASS USING A 60/40 FLUX CORE SOLDER ALONG WITH STAY CLEAN SOLDERING FLUX THE BRIGHT BRASS FINISH WILL DISCOLOR TO A PATCHY REDDISH COPPER COLOR IS IT POSSIBLE TO GET THE BRASS TO SOLDER WITHOUT THE DISCOLORATION? WE USE A HIGH WATTAGE SOLDERING IRON.

THANK YOU,

ROBERT HERMAN
- PORT ORANGE, FLORIDA
2003


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A. Sounds like you are burning or etching away the zinc in the alloy.

Check with a brass supplier regarding the proper solder and temperature to solder this material as it sounds like it is possibly getting too hot.

A protective coating over the brass around the joint may help, as may heat sinking the metal nearest the joint. Kool Jool
(a jeweler's compound for protecting stones and fittings near solder joints) is one possibility.

December 27, 2008
Charles M. Barnard
- Menomonie, Wisconsin




Q. Is there a way to remove the copper that has come to the surface after soldering brass?

Jann Greenland
- Little Rock, Arkansas
July 31, 2009


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A. Hi. In response to brass turning pink, on thread 351/45 Goran B. suggested trying ammonium citrate; Liz G. followed his advice and said her components turned back yellow. It's certainly worth a try  🙂

I'm not sure if it's practical, but it it possible to bright dip the brass, which may get it back to a nice color. Many types of bright dip are available, but the most popular is probably the proprietary sulfuric acid + hydrogen peroxide formulations. I'd suggest asking a plating shop to do a sample, as that way you won't have to learn everything all at the same time  🙂

I haven't done such soldering and experienced such a problem, but from book knowledge it seems more likely to me that the flux is the culprit rather than the soldering temperature; for one thing, brazing can produce a nice brass color despite its higher temperature.

Good Luck & Regards,

Ted Mooney, finishing.com
Ted Mooney, P.E.
Striving to live Aloha

finishing.com - Pine Beach, New Jersey

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