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topic 22905

DI water is attacking PVC and Polyethylene Piping


A discussion started in 2013 but continuing through 2018

2003

Q. I have 12-17 meg-ohm DI water running through PVC piping to a humidity chamber. For some reason, after about a week or so, the polyethylene parts in the chamber show signs of a chemical attack. Does anyone have any idea of why this would happen with my PVC piping but not my stainless piping?

Darnell Albearto
- Odessa, Texas


2003

A. Why are you running such high quality water in a humidity cabinet. Electronics testing? You mention polyethylene and PVC. Both should be unaffected to any significant degree by 18 M water. Bet you a nickel cup of coffee that you are talking about a fitting and I bet that it is nylon, even tho it looks like PE. Replace it with a polypropylene, or if you are rich, teflon, fitting and your problem should go away.

James Watts
- Navarre, Florida


2003

Q. I am also showing attack on polycarbonate parts. My theory is that the DI water is taking something out of the piping that is detrimental to the parts in the chamber. There is also a bit of polyethylene running to the chambers.

Darnell Albearto
- Odessa, Texas


2003

A. Darnell,

What James Watts said sure sounds l00% correct.

Both PVC and PE are NOT affected by the D.I. water ... but in all my experience, we never, EVER used or even considered using Polycarbonate for chemical plant work ... You went on to say that PE parts show signs of chemical attack but then go on to say "why is this happening to my PVC piping" ... and that sure DOESN'T make sense, does it?

Please indicate the attack mode. PVC's drawback is temperature and many solvents. PE's drawbacks (apart from temperature) lies with certain oils, surfactants, some solvents and very strong acids. Then you say that you have a piece of PE running to the chambers. Ah. Um. What! Are you sure that it is PE? Does it burn? Does it drip? Does it smell of candle wax? All are proven tests for PE.

I am a great disbeliever! Often Chief Chemists or Engineers have passed on false information hence, if you don't mind, I'm taking what you said with the proverbial grain of salt, a large grain!

Please get back with more info, if you don't mind. Thanks.

freeman newton portrait
Freeman Newton
White Rock, British Columbia, Canada

(It is our sad duty to
advise that Freeman passed away
April 21, 2012. R.I.P. old friend).



2005

A. Our business is purified water systems. Your contractor should know that 10-18 megaohm xcm water is the most aggressive solution that exists.
PVC piping is not recommended for ultra-pure water and you should know it.
PVC piping is fabricated with multiple chemical additives and most are carcinogenic leachants. These chemical additives leach out in ultra-pure water and create your problems as well as other types of problems.
Get rid of the PVC piping and replace with natural virgin polypropylene (PP) or polyvinyldene fluoride (PVDF) piping.
As for the SS piping: if grade 316, it will deteriorate at a very slow rate of maybe 0.02%/year and is hard to notice with the eye. SS 316 grade that has been passivated is even slower to deteriorate.
PP piping is best for such applications.

DENIS GAULIN
- ST-BRUNO, Quebec, Canada



August 12, 2012

Q. We are an assembler of ultrapure water systems for electronics.
Usually we have problems with PVDF distribution lines, due to very slow fusion and installation.
Some people claim that PVC Schedule 80 pipe is suitable, and installation is easier with cement.
Please enlighten me.

Hasan Peksen
- Ankara, Turkey


August 14, 2012

A. For my nickel, I would only use teflon tube or pipe for ultra pure DI. Mandatory at 18 megohm and advisable at 12 Megohm water.

James Watts
- Navarre, Florida


August 16, 2012

A. PVC piping is fine for O.5 - 5 Meg-ohm DI water as long as you are not concerned with the Total Organic Carbon (TOC) concentration. There will be some leaching of plasticizer from new PVC and some other plastic piping, and the solvent cement will elevate the TOC for days after a piping modification.

Fusion welded PP or PVDF is preferred for > 10 meg-ohm, low TOC DI water.

Lyle Kirman

Lyle Kirman
consultant - Cleveland, Ohio


August 29, 2012

A. Hi there,

we use C-PVC in all our piping with DI water <5 microSiemens without having any issues.

Regards

Dominik Michalek
- Melbourne, VIC


January 29, 2018

A. When you run high purity water through PVC piping, you have to consider that you have removed some minerals from RO/DI filters and then when you run the RO/DI water through high purity resins you have incompletely removed all minerals from the water, then it starts to degrade the PVC piping which removes the plastisizers in the PVC piping. (In plain English the pure water starts to remove the flexibility from the pipe and the pipe becomes rigid and slowly over a period of time the water is attacking the pipe trying to absorb all the minerals back into the pure water. If you consume or drink too much of the 10 to 18 meg-ohm water your body's organs will start to shut down because the high purity water starts to attack your organs of the minerals and cause you to get very sick or even die from complications from your organs shutting down.

Gregory L Smith
- Hagerstown, Maryland



July 12, 2018

Q. I HAVE USED PVC PIPES FOR DI WATER. WE USED A PVC SOLUTION TO JOIN THESE PIPES. WE CAME TO KNOW THAT DUE TO USE OF PVC SOLUTIONS THE TOC OF THE WATER RISES. IF ANYBODY HAS THIS SORT OF EXPERIENCE PLEASE SHARE

MUHAMMAD ALI
Business - Pakistan, Islamabad


August 19, 2018

Q. TOC will rise sharply whenever new piping revisions with new primer and solvent are used, but will decline to normal after a few days.

Lyle Kirman
Consultant - Cleveland Heights, Ohio USA



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