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What is Liver of sulfur?

I am a Maker of Pewter figurines I read in a jewelry book that you can oxidize (blacken) pewter with Liver of sulfur. No one in South Africa seems to know what this chemical is. Can you please tell me another name for it or what it is made of. I have been blackening my pewter with Nitric Acid in the past but it gives a finish that is too dark (i.e., hard to polish the black off sufficiently) and sometimes inconsistent.

Thank you,

Andrew Postus
private - Durban, KZN, South Africa
2003

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sulfurated Potash.

Neil Bell
Albuquerque, New Mexico
2003

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See question 20448 - all will be revealed.

Trevor Crichton
R&D practical scientist
Chesham, Bucks, UK
2003

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2005

Liver of sulfur is not a chemical compound but is a mixture, prepared as a brown mass by fusing sulfur and potassium carbonate.(P. J. Durant 1954, General and Inorganic Chemistry page 491)

6S + 3K₂CO₃ = 2K₂S₂ + K₂S₂O₃ + 3CO₂

When I last prepared this I melted sulfur and slowly added a measured quantity of potassium carbonate as per the above formulae.

The mixture was stirred until bubbling ceased and was then allowed to cool. It was then broken up and bottled. The mixture was stable.

A dilute solution can be used to tarnish copper and other metals.

Note that hydrogen sulfides are also evolved which smell bad in low concentration but are poisonous in higher concentrations. Thus a fume cupboard is mandatory.

Claudio Ferrero
- Sydney, NSW, Australia

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Hello, Liver of Sulfur is widely available in the states. "Rio Grande" is a jewelry supply firm and they will ship it to you. It will loose potency with moisture or air so store carefully. It is easy to control and will give a variety of colors from light brown to black. Easily mixed in warm water to make solution.

Luanne Meader
- Georgetown Massachusetts
March 31, 2009

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