Electrolytic Cleaning of Aluminium: Simple Powerful Setup

Summary for electrolytic cleaning of aluminium Discussion

Electrolytic cleaning of aluminium is discussed as a simple shop process for motorcycle magneto bodies, with Goran Budija giving a specific bath formula: potassium carbonate 100 g plus water glass (sodium silicate) 8 g per liter of water, using the aluminium as the cathode, stainless steel as the anode, and 12 V at 1–5 A/dm² for 10–30 seconds. The original poster had heard that the aluminium was first blackened by oxidation and then the effect was reversed, but the thread’s practical answer focuses on the cleaning electrolyte and setup rather than that theory. In a later question, Daniel Oliveira asked what “water glass” meant, and it was clarified as sodium silicate. Paul Sperbeck then asked why potassium carbonate was preferred over calcium carbonate; Geoff Smith explained that potassium is generally much more soluble than sodium, which is much more soluble than calcium, implying solubility is the key reason.

Q. I am setting-up a small business repairing motorcycle magnetos and would like to use electrolytic cleaning for the aluminium bodies (I knew a guy who used the process years ago, but he wouldn’t tell me about it). Can anyone point me in the right direction, please? I believe the process he used turned the aluminium black by oxidising the surface and this blacking was then removed by some sort of reversal of the process? Trouble is I don’t know what solutions are required.

Dave Fisher
– Northampton, England
2003

A. Electrolytic cleaning solution for aluminum:

potassium carbonate 100 gm
‘water glass’

⇦ on

eBay or

Amazon [affil link]
8 gm
1 lit. water, object=cathode (-),stainless steel anode (+),12 V,1-5 A/dm2, 10 – 30 sec.

Goran Budija
– Cerovski vrh Croatia
2003

Q. Hi,

what do you mean by “Water glass 8 gm” ?

Daniel Oliveira
– Algarve, Portugal
April 19, 2011


Q. The answer specified a Potassium Carbonate and Sodium Silicate electrolyte. I have used Calcium Carbonate for electrolytic de-rusting of iron and steel.

Is there a chemical reason to use Potassium Carbonate instead of Calcium Carbonate?

Paul Sperbeck
– Waukesha Wisconsin USA
August 4, 2016


August 2016

A. Hi Paul.
In general, potassium is much more soluble than sodium which is much more soluble than calcium.

Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com – Pine Beach, New Jersey



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A. Hi Paul
Calcium carbonate is a naturally occurring mineral. It is found as limestone, chalk, marble, etc.
Entire mountain ranges are made of this and they have withstood many thousand years of rain.
It is very close to being completely insoluble so it is not a very promising basis for an electrolytic cleaner.

geoff smith
Geoff Smith
Hampshire, England
August 7, 2016