finishing.com -- The Home Page of the Finishing Industry

HomeFAQsSuggested
Books
Help
Wanteds
Advertise
on this site
FORUM
current topics
Live! From beautiful Pine Beach New Jersey: Welcome to the world's most popular metal finishing website

topic 18965

Alkaline Zinc Electroplating Bath Efficiency




An ongoing discussion from 2003 through 2015 . . .

2003

Q. We have non-cyanide alkaline zinc electroplating bath,we are using caustic potash , brightener, Carrier & zinc metal. I need to know what is the bath efficiency suppose to be?

popat patel
Popat Patel
    Beacon Park Finishing LLC - Roseville, Michigan


2003

A. Efficiency varies widely as a function of several parameters. The most efficiency varying parameter is the current density, the higher the cd the lower the efficiency.

Also Caustic/Zinc ratio is a big variable, the higher the ratio the better the "throw" the lower the efficiency.

Metal Content, temperature, agitation all influence efficiency.

No vendor will state his process efficiency because it varies from tank to tank. You must derive your own efficiency test for the conditions under which you plate.

robert probert
Robert H Probert
Robert H Probert Technical Services
supporting advertiser
Garner, North Carolina
Editor's note: Mr. Probert is the author of Aluminum How-To / Aluminio El Como
and co-author of The Sulfamate Nickel How-To Guide


2003

A. Robert is absolutely right. There are a lot of parameters that influence the efficiency. Anyhow, 40-60% is the right answer.

sara michaeli
sara michaeli signature 
Sara Michaeli
chemical process supplier
Tel-Aviv, Israel



2003

A. Both of the above answers are correct. In general, with the latest generation of alkaline non cyanide zinc the efficiency can approach 60% although one or two vendors are claiming higher numbers. The "caustic potash" (potassium hydroxide) baths are generally higher in efficiency than the sodium hydroxide baths.

Gene Packman
process supplier - Great Neck, New York


2003

A. I don't claim to be an expert by any means, however, I listened well when we finally bit the bullet and installed an alkaline non-cyanide zinc about 6 years ago. I was highly impressed by the baths ability to plate in narrow slots that cyanide barely covered and acid zinc left bare. There's a point here....just read on!

Alk non-CN zinc is formulated to have different efficiencies on the same part depending on the relative current density at that area. High CD edges have lower efficiency and lower CD areas have higher efficiency thus resulting in a more uniform deposit. Sounds weird but explains why alkaline, non-cyanide zinc plates far more uniformly than cyanide or acid zinc.

One thing for certain is that the efficiencies overall are on the order of roughly 40-60% and nowhere near 80-100%.

milt stevenson jr.
Milt Stevenson, Jr.
Anoplate Corporation
supporting advertiser 
Syracuse, New York

Anoplate banner


2003

A. Milt is right, the efficiency is higher at the LCD and lower at the HCD. As a result, the thickness is almost evenly spread like in electroless plating.

Sara Michaeli
Sara Michaeli signature 
Sara Michaeli
chemical process supplier
Tel-Aviv, Israel



August 22, 2015

A. Not all Caustic non-cyanide zinc processes are low efficiency. Running a high-volume continuous line, we have a normal efficiency range of 82% to 92%.

If your product is a batch process, it's most definitely more difficult to reach higher efficiency ranges.

keith_bowers
Keith Bowers
Continuous High-Volume Zinc Plating - Louisville, Kentucky, USA



If you have a question in mind which seems off topic, please Search the Site

ADD a Q, A, or Comment on THIS topic START an UNRELATED topicView CURRENT HOT TOPICS

Disclaimer: It's not possible to diagnose a finishing problem or the hazards of an operation via these pages. All information presented is for general reference and does not represent a professional opinion nor the policy of an author's employer. The internet is largely anonymous & unvetted; some names may be fictitious and some recommendations may be deliberately harmful.

  If you need a product/service, please check these Directories:

JobshopsCapital Equip. & Install'nChemicals & Consumables Consult'g, Train'g, SoftwareEnvironmental ComplianceTesting Svcs. & Devices


©1995-2019 finishing.com, Inc., Pine Beach, NJ   -   About finishing.com   -  Privacy Policy
How Google uses data when you visit this site.