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topic 15480

Phosphate coating & part temperature limits


A discussion started in 1998 and continuing through 2013.
Add your Q. or A. to restore it to the "Current Topics" discussions.

(1998)

Q. Greetings from Denmark

I would be very grateful if you could supply information about the temperatures phosphate coatings on steel (iron-, zinc, zinc/calcium- and manganese-phosphate) can be heated to in air without getting damaged. The phosphate coatings shall be used as pre-treatment prior to heating in oven and polyethylene-coating in a fluidized bed process.

Looking in the literature is a bit confusing, as the maximum temperatures referred range from 150 °C to 500 °C. However most of the references give a limit of 250-300 °C.

Can you help me out of my confusion. Literature references to new results would be very much appreciated.

Best Regards

Torben Jense, Mc.S, Ph.D
- Brøndby, Denmark



(2001)

Phosphating & Metal Pretreatment
by Freeman
from Abe Books

or

Q. Dear Reader:

We are having a dispute in our company as to the maximum temperature (and time) we can have in our dry-off oven without dewatering our lightweight iron phosphate coatings produced in our 6 stage spray washer. We also have another line that uses zinc phosphate for automotive parts, and have disagreed as to the maximum temperature (and time) for that dry-off oven as well - before dewatering of the coating occurs.

Does anyone have a technical article that they can refer me to so I can read it for myself, or, if not, let me know by response to this inquiry in the usual written fashion.

Many Thanks,

Tom Meyer
- Milwaukee, Wisconsin, USA


(2001)

A. Hi,

Stoving times are very flexible. At temps above 150 deg C for 20+ mins 2 molecules of water will be driven off from zinc phos. This is NOT detrimental in any way. Above 250 deg C complete dehydration will occur and this will most definitely adversely affect performance. Lightweight iron will be less affected. In short you could use powder cure temps for drying and not suffer!

Roger Bridger
- Croydon, UK



To minimize searching and offer multiple viewpoints, we've combined multiple threads into the dialog you're viewing. Please forgive any resultant repetition or failures of chronological order.



(2002)

Q. I recently saw in an Air Force Technical Order that zinc phosphated coating is not to be used on parts exposed to temperatures above 200 °F. Why would this be since zinc phosphate is recommended as a pretreatment by powder coating manufacturers whose coatings are cured at temperatures in excess of this?

Joe Yochum
- Warner Robins, Georgia, USA


simultaneous (2002)

A. Hi,

At 150 °C phosphate will lose 2 molecules of water, which is not harmful and can indeed improve performance. Above 250 °C total dehydration occurs which causes partial destruction of the structure. These figures refer to exposure when uncoated. Curing of the paint film at < 220 °C does not affect coating integrity.

Roger Bridger
- Croydon, UK


(2002)

A. Zinc phosphate heated above 200 °C gives off water of crystalisation after ~30 minutes at that temperature, which turns the crystal coating into an amorphous layer that reduces corrosion resistance and adhesion. Paint or powder stoving for the recommended time seals the coating and prevent this loss so the crystals stay complete.

Robert D Lilley
- Singapore



(2005)

Q. What is the decomposition temperature of zinc phosphate coating on steel parts? What is the recommended operating temperature for such parts? Can you please support your data with the resource?

Aida Ratner
- Cleveland, Ohio



To minimize searching and offer multiple viewpoints, we've combined multiple threads into the dialog you're viewing. Please forgive any resultant repetition or failures of chronological order.



(2005)

Q. We have a cylinder application using 4130 steel with zinc phosphate internal finish to store high pressure oxygen. Our customer (US Military) has heard that at above a certain interior or surface temperature, the coating will start to off-gas with possible toxic results. We have reviewed Fed TT-C-490 [link by ed. to spec at TechStreet] but cannot find anything specific to this situation.

Can anyone provide information on what maximum temperature is allowable for zinc phosphate coating before it will start to off-gas? The maximum fill temperature is 125 °F, but we expect the internal temperature may exceed this.

Thanks,

David Snyder
cryogenics - St. Louis, Missouri


(2005)

A. Hopefully, some company that manufactures it would have that research. If not, try finding the right office at the Rock Island Arsenal. They are or were the OPR for that mil spec and years ago had one of the best knowledge basis of anyplace.

James Watts
- Navarre, Florida



March 27, 2013

Q. What is the behavior of a zinc phosphate film at high temperatures, i.e. above 700 °F - 900 °F? Possibly higher?

Carlos Alvarado
- Houston, Texas, USA


April 2, 2013

Phosphating of Metals
by Rausch
from Abe Books

or

A. Hello Carlos!

Over 300 °F you have phosphate dehydration, so the layer itself tends to decompose, and any sealer you can put on it will not have any effect, the anticorrosive properties are lost and the surface tends to corrode.

It is different if you have a topcoat over the zinc phosphate, then you must read the topcoat technical sheet and look for its maximum operative temperature. We use some topcoats that will behave normally up to 400 ° F, but I don't know if there is any topcoat that can handle 700-900 ° F...

Hope this can answer your question! Regards,

Daniel Montanes
- Canuelas, Buenos Aires, Argentina


July 10, 2013

A. Not all of the zinc phosphate will be lost. I have done testing on panels that had zinc phosphate pretreatment; cat-epoxy e-coat; and polyester powder. I burned off the coating at 800 °F. Then ran the panels through pretreatment, e-coat and powder again.
The burn off panels outperform control panels in salt spray and in cyclic testing.

Dan Mack
- Horicon, Wisconsin



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