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Chemical removal of heat treating scale and oxides -- steel parts



A discussion started in 2002 and continuing through 2017 . . .

(2002)

Q. Looking for suggestions on removing heat treating scale from carbon steel parts prior to tempering and subsequent grinding. Would be interested in any experience with commercial products, or "home-brewed" pickling solutions. Thank you.

Fred Pickard
- York, Pennsylvania


(2002)

A. I would like to suggest electrocleaning the workpiece. It is the reverse from the electroplating process, causing the dirt on the surface of the workpiece to fall off.

Hartarto Ciputra
- Surabaya, Indonesia


(2002)

A. There are dozens of approaches and formulas. Some based on galvanic phenomena, some based on chemical attack (either highly acidic or heavily chelated), some based on the reducing potential of melt or fused salts. It depends very much on budget, type and volume of work and established facilities. Get a good book on the subject. A web search, no matter how thorough, will never be a substitute for a good specialized book. May I suggest to you the ASM Metals Handbook.

Guillermo Marrufo
Monterrey, NL, Mexico


(2002)

A. I will suggest a 3 in 1 degreasing solution before tempering; this will remove scales and oil.

Harish Chitkara
- Madras, India



H-13 got scale during heat treatment despite stainless foil wrap

(2004)

Q. I heat treated H-13 with stainless foil wrap. When I finished heat treatment, there was scale and it's hard to remove with sandpaper. Is there a chemical solution for this?

Thank you,

Dongok,Kim
student - Fayetteville, Arkansas, United states


(2004)

A. We've used hot alkaline cleaners for removing that kind of scale, and sometimes it even works. Pickling in hot, dangerous hydrochloric acid can also work, but I don't recommend it: you might remove the scale, and cause the part to crack from hydrogen embrittlement. Since you noted you're a student, I'd start with Naval Jelly or other rust remover that you get from a local hardware store. Those are usually alkaline based, so it should be safer than other formulations I can imagine.

Yet we've found the best thing is to keep it from happening in the first place. Something we've had really good success with is filling the foil pouch with a slow stream of nitrogen or argon, which displaces the air and keeps the parts bright and shiny. It's surprising how little you need, and bottled gas, especially nitrogen, is not expensive. Compare it to chemical cleaning, and prevention is cheaper than cure. By far.

Good luck!

lee gearhart
Lee Gearhart
metallurgist



(2004)

A. Naval Jelly [linked by editor to product info at Amazon] is basically phosphoric acid in a jellied alcohol media. I did many types of tool steels with the SS wraps with very very little staining. The secret is to eliminate as much air as possible by folding or collapsing the wrap so there is very little air and then sealing it with a triple fold pressed as flat as convenient. Lee's nitrogen suggestion is very workable if you seal the baggie well.

James Watts
- Navarre, Florida


June 21, 2011

A. For eliminating or substantially reducing scaling, anti scale compound may be used.

27963

Removal of anti scale compound after heat treatment is easy, and surface finish of component is good. Unproductive work of scale removal is either eliminated or substantially reduced.

srikar_shenoy
Srikar Shenoy
- Mumbai, India


To minimize searching and offer multiple viewpoints, we combined multiple threads into the dialog you're viewing. Please forgive any resultant repetition.



Removing heat treat scale from 4140 steel parts

(2004)

Q. I need help in removing heat treat scale from steel gears made of 4140. These parts are induction heat treated and are hard on outside and soft on the inside. Currently we have been vibe deburring them. With this process we are seeing damage that we cannot live with, mainly from parts banging into one another. I am looking for a process that will remove the heat treat scale with little to no damage to the part.

Thanks in advance.

Kirk Edwards
Automotive - Portland, Oregon, USA


(2004)

A. Have you considered chemical methods such as acid cleaning/pickling?

Toby Padfield
Automotive module supplier - Michigan


(2004)

A. Lots of possibilities:

1. Fixture them in your vibe so they don't bang each other.

2. Pickle in inhibited HCl, but be certain to bake after.

3. Alkaline Derust hot.

4. Glass bead blast.

jeffrey holmes
Jeffrey Holmes, CEF
Spartanburg,
      South Carolina




Heat treatment scale removal before plating

(2005)

Q. Part material SAE 1070, heat-treated at 600 degree for 3 hours nitrogen furnace. Trying to remove heat-treated scales using 50% HCl for 20 minutes. Result: still can see scale on surface. For further process like Electroless Nickel, fail bend test.
Is there any other ways of improving the pre-treatment etching? Or is there a problem when only using soak clean as only cleaning process?

Lian Guik
employee - Malaysia


(2005)

A. Even though it is a high carbon steel, you should not be seeing scale if your furnace were working properly. Just flowing nitrogen in a furnace does not remove all of the oxygen, and certainly not at once. It is better to prevent the scale than to try to remove it afterwards. I would try to find a good consultant. The MFG of your furnace might be able to help you with a better operation cycle or help to reduce leaks.

James Watts
- Navarre, Florida



Removal of scale and soot before phosphating without using acid

(2006)

Q. We phosphate a part after heat treatment. We would like to remove the soot and scale on the parts prior to phosphating. Since the volume of parts is huge we need a fast method of removing them without affecting the dimensions of the part.(HCl changes the dimension).

These parts have close tolerances and we need to phosphate close to 2500 parts per day. Approximate part weight is 75 g.

Ganesh.J
- Chennai, India


(2006)

A. You should look at a Phosphoric Acid based pickling process which will not attack the steel. Or try shotblasting.

khozema
Khozem Vahaanwala
Saify Ind supporting advertiser
Bangalore, Karnataka, India

saify logo


(2007)

A. Are you sure the acid is the problem? It appears to me that your problem is the heat treat scale is too thick. Any method to remove it will affect your close tolerances. Consider a controlled atmosphere furnace. Another option would be a vacuum furnace (absolutely the best but more expensive).

Guillermo Marrufo
Monterrey, NL, Mexico



How to best improve our pretreatment cleaning process?

(2006)

Q. We are a small plating shop located in the Midwest. We are currently having problems w/ the pretreatment cleaning of our steel parts. We don't have trouble w/ the oiled steel parts coming in to plate. We do struggle periodically w/ the mill scale and heat treated steel parts in our pretreatment cleaning. We are a non-cyanide alkaline zinc only plating shop. We offer a trivalent blue chromate and a hexavalent yellow chromate conversion following plating. Our process for the rack line is as follows:

-Heated soak cleaner 170 °F for 10-15 minutes
-1 Rinse
-Electrocleaner (ambient temp) 70 °F 5-10 minutes
-1 Rinse
-Heated Sulfuric acid w/ agitation 100 °F (30% concentration) 10-30 minutes
-1 Rinse
-Plating tank non-cyanide alkaline zinc , maintain chemistry as follows, zinc 2.0 oz/gal and KOH level 19-20 oz/gal 12-20 minutes, pending parts and customer specs, usually 5-15 microns for thickness
-1 Rinse
-Blue/ Yellow Chromate conversion pending customer preference and spec.
45 sec -1min30sec
1 Rinse

Other relevant info
No agitation other than the acid tank
No filtration other than the plating bath
No heat on any tanks except soak cleaner, acid, and final rinse
No heat for drying/curing off line

My question is, on a limited budget, which aspect of improving the pretreatment cleaning process would give us the best value for the money? Obviously we have several areas that are already identified as problems in the cleaning process. Is one solution better than the other?

Chris Johannsen
Plating Shop Employee - Cedar Falls, Iowa, USA


(2006)

A. Hi Chris,
Sulfuric acid is very common for removing mill scale. For heat treated and weld steel you may want to set up a small pilot tank with the following mixture:
18% by volume of 70% nitric acid
6% by weight of ammonium bifluoride
2% by volume hydrochloric acid

Temp. ambient
Time 15-20 minutes
If your parts are small enough try it in the lab, or in a 5 gal. bucket. As far as reactions the solution will only produce a mild exothermic reaction. Another option would be using HCl with an inhibitor to avoid attack of the steel. good luck!

Mark Baker
process engineer - Malone, New York


(2006)

A. Hi Chris,

The question of which process improvement will give you the most value is one that only you and your company can answer. Here are some suggestions.

1. Make sure that your alkaline cleaners are properly formulated to handle the types of soils that you encounter. Your chemical supplier should be able to help you.

2. Add agitation to the soak cleaner and electrocleaner.

3. Add heat to the electrocleaner. Higher temperatures will allow this product to do its job better.

4. Ask your chemical supplier about a formulated product in the pickling stage. This may help with the removal of the scale that you mentioned.

George Gorecki
- Naperville, Illinois


(2006)

A. Try using a pickle tank after cleaning. This is the best way I found to remove heat and mill scale.
35% muriatic acid / 65% water
room temp

You may still have to do a little wire brushing or scotch brite rubbing.
Keep this tank covered when not using. It will rust and corrode everything around it.
You will have to re-clean parts after this process before continuing into plating.

Frank DeGuire
- St. Louis, Missouri, USA


(2006)

A. Also we have found a really good substitute for acids. It is an acid salts from Enthone Actane 340 is the name it is used a lot in place of the HCl. The ratio we use is 1 pound per gallon @ room temp. It can be heated. Also no fumes. This may be something to try.

William Sklavenitis
- Canton, Ohio, USA



(2010) -- this entry appended to this thread by editor in lieu of spawning a duplicative thread

Q. We are faced with a problem of smut on heat treated fasteners after pickling. Is there any way of removing this smut?

A Prabhu
Plating shop employee - Chennai, Tamil Nadu, India



August 8, 2014 -- this entry appended to this thread by editor in lieu of spawning a duplicative thread

Q. Hello,
1. We are doing Phosphating on clutch plates.
2. The plates undergo heat treatment followed by oil quenching which forms a thick black crust on the parts.
3. Is there some way of removing this crust prior to plating using purely chemical means?
4. We use a Phosphoric-citric dip followed by glass bead blasting, but that is not feasible due to the high volume and propensity of the clutch plates to bend under the pressure.

Any insights are welcome.

Sincerely

Ravi Patel
- Anand, India


May 16, 2016

A. Try sand blasting or shot blasting.

Mohan Vishshwakarma
- Jabalpur MP India



August 30, 2016

Q. Sirs,
We are doing descaling process after heat treatment for removing carbon scale on the child parts. In the process we are using saw dust and mesh powder. Is any new concept process available with low cost? Kindly share.

sundara moorthi
- Coimbatore, tamilnadu, India


August 2016

A. Hi Sundara. I think this page introduced a whole bunch of excellent ideas for your consideration. I think at this point the ball is probably in your court for you to ask detailed questions about the many ideas that were suggested. Good luck.

Regards,

pic of Ted Mooney
Teds signature
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey
Striving to live "Aloha"



February 12, 2017

Q. Will a warm citric acid pickle clean the surface of parts made from SAE 52100 steel heat treated to 58-62 Rc in order to remove the residual oxides left over from the oil quench. The production parts are small -- approximately 1/2 inch in diameter and no longer than 5/8 long. Our surface cleaning task is in preparation for a PVD coating process (400 °F) to not contaminate the PVD vessel. I have a plating vendor that can do normal acidic pickling which I assume will require a post pickle bake to prevent hydrogen embrittlement. If needed I have glass bead shot blast available. The purpose of a single step of a citric acid pickle is based on economics.

Mike Gordon
tools - Fraser, Michigan, USA


February 20, 2017

A. Mike,
I would say "probably", but you should be able to prove it one way or the other rather easily.

Ray Kremer
Stellar Solutions, Inc.

McHenry, Illinois


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