Summary for nickel chromium alloy electrodeposition Discussion
Nickel-chromium alloy electrodeposition is presented as a difficult problem, especially for a coating with less than 8 wt% chromium. In response to Mohamad Saqib Ayub’s question, Ted Mooney says the classic reference by Brenner does not really acknowledge nickel-chromium alloys and notes that only sketchy reports existed, with even well-known researchers unable to reproduce them. He adds that Safranek’s book points to a 1985 AES conference presentation by Lashmore, Wisehauss, and Pratt, which reported success using pulse plating. However, Mooney also recalls David Lashmore later suggesting the result may not have been a true alloy at all, but a multilayer “sandwich” of alternating nickel and chromium microlayers. The thread therefore suggests that practical nickel-chromium deposition is uncertain and that the reported success may depend on pulse plating or layered deposition rather than a straightforward alloy bath.
“Electrodeposition of Alloys: Principles & Practice”
by Abner Brenner

on Amazon
or
or
(affil link)
“The Properties of Electrodeposited Metals and Alloys”
by William Safranek

on Amazon
or
or
(affil link)
Q. HI
I WANTED TO FIGURE OUT THE SALTS AND OTHER AGENTS THAT CAN BE USED TO MAKE A SOLUTION FOR ELECTRODEPOSITION OF NICKEL CHROMIUM COATINGS WITH CHROMIUM CONTENT OF LESS THAN 8 WEIGHT PERCENT. HAS ANYONE WORKED ON SUCH COATINGS? KINDLY HELP ME OUT.
MOHAMAD SAQIB AYUB
student – MILANO
November 2, 2021
A. Hi MOHAMAD SAQIB.
That is not an easy one :-)
• “Electrodeposition of Alloys” by Brenner (dated 1963) does not seem to acknowledge any nickel-chromium alloys, and mentions that only very sketchy reports of chromium-nickel alloys are available, and notes that well known researchers were unsuccessful in trying to duplicate the reported results.
• “The Properties of Electrodeposited Metals and Alloys by Safranek (dated 1986) has one page on the subject, relating a technical conference presentation by Lashmore, Wisehauss, & Pratt, “Electrodeposition of Nickel-Chromium Alloys” (AES Research Project 58) as Session P of the Proceedings of Technical Conference, American Electroplaters Society, 1985, where success was reported with pulse plating.
I attended a presentation by David Lashmore some time later where he seemed to say that this was not actually an electrodeposited alloy, but more of a many layer sandwich where a microlayer of nickel was deposited, then a microlayer of chrome, then a microlayer of nickel, etc.
Luck & Regards,

Ted Mooney, P.E. RET
Striving to live Aloha
finishing.com – Pine Beach, New Jersey
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November 2021