Plating onto Tin Substrate: Smart Nickel Barrier Choice

Summary for plating onto tin substrate Discussion

Plating onto tin substrate is the main concern in this thread, where Mallory Nichols asks whether medallions cast from lead-free solder (mostly tin, sometimes with bismuth) can be plated with copper or gold, and whether an intermediate layer such as nickel or zinc is needed. The response says the process should be possible, but warns that tin and copper or tin and gold may diffuse into each other too readily. The recommended approach is to use nickel plating first as a diffusion barrier, then apply copper or gold on top. The answer also notes that while adhesion problems have been reported when plating onto tin, they are likely less important for medallions that will not be soldered or exposed to high temperatures or significant stress.

Q. I have started casting small medallions using lead-free solder (over 99.6% Sn). Sometimes I also mix in 20% bismuth to get a better cast. Now I’m interested in plating them with copper, and possibly gold.

Will copper take to tin? Or should I start with nickel or zinc or something, then copper as the final layer? And the same question for gold really.

Mallory Nichols
– Burnley, England
July 6, 2020

A. Hi Mallory. I think you would be able to do such a process, or have it done, but that the tin & copper or tin & gold, will diffuse into each other too readily. I think you’d probably be better off doing nickel plating as a diffusion barrier first before the copper or the gold. Although I’ve heard of some adhesion issues when plating onto tin, I would expect that medallions would not be soldered, or exposed to high temperatures or stresses, such that in your case adhesion issues will probably not be a significant problem.

Luck & Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com – Pine Beach, New Jersey



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July 2020