Silver Gold Alloy Plating: Safe, Practical Options

Summary for silver gold alloy plating Discussion

Plating with an alloy of silver and gold is possible, but Goran Budija says it is complicated and usually requires careful experimentation. In response to Daniel Fronefield’s question about reproducing traditional Japanese alloys such as Shibuichi and Shakudo, he notes that both cyanide-based and cyanide-free processes can be used. He specifically points to ferrocyanide solutions as the simplest and probably oldest cyanide-free option, and mentions that thiosulphate- and pyrophosphate-based baths may also work. Budija warns that cyanide solutions are very dangerous and recommends only cyanide-free methods for DIY work. He suggests one practical route is to start with a gold or silver bath and add a water-soluble copper salt, or use a copper bath and add water-soluble gold or silver salts. The overall message is that the process is feasible, but not straightforward.

Q. Is there a way to electroplate alloys of silver and gold? Usually these would be 25-60% silver in copper, or 3-10% gold in copper (maybe with some small lead additive). These are traditional Japanese alloys (Shibuishi and Shakudo).

Daniel Fronefield
hobbyist – Peyton, Colorado, USA
October 5, 2012


A. Yes it can be done, but it is complicated. You can use cyanide based solutions or even cyanide-free. Ferrocyanide solutions are simplest and probably oldest cyanide free solutions (1841-Elsners ferrocyanide based gold plating solution!) Probably thiosulphate based or pyrophosphate based solutions can be used too (try uspto.gov webpage -USA patents database, there you can find at least 1 patent devoted to thiosulphate based gold, copper and silver baths). Probably you know that cyanide based solutions are very dangerous stuff, so for DIY work I must recommend you only use cyanide-free solutions. You can use gold or silver bath + add some water soluble copper salt, or copper bath + add gold or silver water soluble salts. Complicated, and need lots of experiment, but as I said before it can be done. Hope it helps and good luck!

Goran Budija
– Zagreb,Croatia
October 10, 2012