Summary for copper black oxidation Discussion
Copper has oxidized to black color is a short Q&A about a copper substrate for electronic use that showed different oxidation levels and a black surface. Valeriano Cardi asked what the black oxidation was and how to remove or reduce it. The reply says there were not enough details to identify the exact cause, but the black color may be a sulfide reaction rather than simple oxidation. The answer also notes that copper oxidation can be slowed with benzotriazole or chromates. Because the thread is brief and lacks process details, the advice is general rather than a specific cleaning or restoration method. The practical takeaway is to identify the contaminant or environment first, then consider protective inhibitors if the goal is to slow further tarnishing.
Q. Hello,
I’m working with copper substrate for electronic application, I found different level and color of oxidation. Could you help me to understand the oxidation with black color and how I can remove, reduce, this oxidation ?
Thanks
Valeriano
Valeriano Cardi
research – Rome, Italy
January 21, 2009
A. Hi, Valeriano. You haven’t given us any details to work with, but black oxidation may be a reaction with sulfides, and copper oxidation can be slowed with benzotriazole
⇦ on
or
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or chromates. Good luck.
Regards,

Ted Mooney, P.E.
Striving to live Aloha
finishing.com – Pine Beach, New Jersey
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