Copper Tarnishing: Smart Fixes for a Persistent Problem

Summary for copper tarnishing Discussion

Copper tarnishing on plated parts was the core problem in this thread: Kannan Boopathi said he was barrel plating 1.2 mm sheet with cyanide copper undercoat, acid copper topcoat, and an anti-tarnish top coat, yet still seeing tarnish despite careful packing. Mark Baker advised checking several likely causes, especially metallic impurities in the copper bath, the quality of the final rinse, and whether a hot DI rinse is being used, since water quality is often the culprit. Later, Madhukar Nandakumar asked about using tollytriazole or benzotriazole and how to detect poor anti-tarnish treatment quickly. The reply said benzotriazole is a good answer, but recommended going to the plating chemical supplier for a copper tarnish preventer, likely triazole-based, so the supplier can provide instructions and ongoing support. The discussion points to bath cleanliness, rinse quality, and supplier-backed anti-tarnish chemistry as the main practical checks.

Q. In 1.2 mm thick sheet I am doing the copper (Barrel) plating of 5 to 10 microns (I am doing cyanide copper plating as an undercoat and acid copper for top for better look after that I am using some top coat as an anti tarnishing solution (packing is 100% perfect with all safety precautions for tarnishing). Still I am facing tarnish. What is the best suggestion?

Kannan Boopathi
Development – India
October 14, 2008

A. There are various causes of tarnishing. Check copper bath for metallic impurities, use a hot DI final rinse (water quality is often the culprit) and make sure the anti-tarnish solution is up to par. Good Luck!

Mark Baker
Process Engineer – Syracuse, New York
October 16, 2008


Q. 1. I have found in the web that TOLYTRIAZOLE & BENZOTRIAZOLE

⇦ on

eBay

or

Amazon [affil link]
are chemicals that can be used for anti tarnishing are there any recommended chemical or manufactures ?

2. Tarnishing usually appears after 48 hrs is there any method to know poor anti-tarnishing treatment within hours of few hours of plating?

Madhukar Nandakumar
– Bangalore, India
December 11, 2008

“The Chemistry of Benzotriazole Derivatives”

benzotriazole

on Amazon

or

eBay

or

AbeBooks


(affil link)

A. Hi Madhukar

Yes, benotriazole is a good answer. However, it is probably better to just go to your plating chemical supplier and ask for a copper tarnish preventer (which no doubt will be triazole-based). That way you will get instructions for use and keep your supplier in the loop so they can help you properly with plating issues as they periodically develop.

We don’t suggest particular brands or sources in this forum ( huh? why?).
Luck & Regards,

Ted Mooney, finishing.com
Ted Mooney, P.E.
Striving to live Aloha

finishing.com – Pine Beach, New Jersey



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