Summary for alternative to sulfuric acid Discussion
Alternative to sulfuric acid for anodizing aluminum is the central question, but the provided thread excerpt does not include the actual discussion or any technical answers. The only visible material is the thread title, a reference to related Topic 42228 about anodizing aluminum with formic or citric acid, and site navigation text. Because no answer text is present, there is no documented recommendation to summarize beyond noting that the thread appears to point readers to a related discussion on non-sulfuric anodizing chemistries. No conflicting views or named technical advice are available in the excerpt.
Aluminum How-To
“Chromating – Anodizing – Hardcoating”
by Robert Probert
You’ll love this book. Finishing.com has sold a thousand copies without a return request 🙂
“The Surface
Treatment &
Finishing of
Aluminium and
Its Alloys”
by Wernick, Pinner
& Sheasby

on Amazon
or
or
(affil link)
Q. Hi.
I have several questions re anodizing aluminum, specifically 6061 alloy.
I have read that borax
⇦ on
eBay or
Amazon [affil link]
or TSP [trisodium phosphate
⇦ on
or
Amazon [affil link]
] can be used as an electrolyte. Is this true?
Is there any advantage to using sulfuric acid? I can always use the TSP, and/or borax
⇦ on
or
Amazon [affil link]
to clean other things.
Wouldn’t the TSP serve as an adequate cleaner?
What about plain old salt water?
What is desmut, and is it necessary?
Regarding the power supply, isn’t it simply a power vs time thing? With this in mind is longer pickling better or worse for the metal? i.e., is the finish harder, softer, or the same?
Does 3 lb. sheet lead make a good cathode? What would be a good hanger? (Anode)
Jim Agans
roof consulting – Eldersburg, Maryland
2006
A. No, James. You might be confusing the anodizing of aluminum with anodizing of titanium jewelry. Although anodic current is used in both cases, neither the required procedures nor the resultant anodized surface have much in common.
For aluminum you need the acid, not just a carrier of ions. The acid continuously attacks and dissolves the anodized film, and that is what creates the honeycomb pore structure that absorbs the dye.
Please send the aluminum to an anodizing shop if you need it anodized. If you anodize this material for installation on a customer’s roof, you’ve suddenly become an anodizing business, not just a roofing business — and you will be shocked at the number of permits and licenses you require, the time it takes to comply, and the costs of non-compliance because you will be in a business that generates regulated hazardous waste.
Good luck.

Ted Mooney, P.E.
Striving to live Aloha
finishing.com – Pine Beach, New Jersey
Need quick confidential answers? $25
Need project assistance? $100/hr.
Readers may wish to also see:
• Topic 42228 “Anodizing aluminum with formic or citric acid ”
