Rocheltex Analysis Method: Practical Advice for Plating

Summary for rocheltex analysis method Discussion

Rocheltex analysis method is the focus of this thread, with Barkin Ugurer asking how to measure Macdermid Enthone METEX Rocheltex in a cyanide-based copper plating bath. Leon Gusak replies that, from the name, the product likely contains Rochelle salt, but because it is a proprietary chemical mix, the best source for an analysis method is the supplier/manufacturer. When Barkin says the local supplier had no method and Macdermid had not replied, the discussion shifts to practical contact issues: the response notes that email can be missed and suggests using Macdermid’s website question-submittal form instead. No one provides a direct lab method or a way to calculate Rocheltex from %KOH, so the thread’s practical takeaway is to seek the manufacturer’s guidance rather than infer composition from bath chemistry.

Current question and answers:

March 30, 2021

Q. We are using Electroplated copper from cyanide-based plating bath on our firm. I am looking for a Rocheltex analysis method but I could not find any method.

Product Name:
Macdermid Enthone
METEX Rocheltex

I will be appreciative if anybody can help.

Thanks a lot,

Barkin UGURER
– Ankara Turkey

A. Hello Barkin
From the name – most likely this component includes Rochelle salt

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. As this is a proprietary chemical mix, I would go to the supplier/manufacturer to get their recommendation for analysis.
Good luck

Leon Gusak
– Winnipeg, Canada
April 8, 2021


Q. We tried to reach our local supplier for analysis but they don’t have too. I sent an e-mail to Macdermid but I didn’t get any answer.

If I know the %KOH in bath, can I find %by vol. Rocheltex in bath?

Barkin UGURER [returning]
– Ankara Turkey
April 9, 2021

A. Hi Barkin. Spam e-mail is a curse, so they may not have got your mail. I get 700-800 a day to my current e-mail address, while hundreds more directed to my outdated e-mail addresses go direct to the trash unseen. And Macdermid probably gets more than that. I suggest you go to their site and use their question submittal form instead.

Luck & Regards,

ted_yosem
Ted Mooney, P.E. RET
Striving to live Aloha

finishing.com – Pine Beach, New Jersey



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April 2021

A. Hi Barkin
Rochelle salt is Sodium-Potassium Tartrate.
If your bath is based on Potassium salts only – by using some advanced method for Sodium determination (ICP-MS? ICP-OES?) – you can calculate the amount of Rochelle salt.
Or opposite, if your bath is based on Sodium salts only – by determining Potassium you can calculate the Rochelle salt.
However, as it is proprietary mix, you may not know all the additives. I would put an effort to get a help from the manufacturer of the chemical…
Good luck.

Leon Gusak
– Winnipeg, Canada
April 21, 2021


⇩ Similar, related, Q&As — oldest first ⇩


Q. We are reviewing U.S. Army technical manuals and some require the use of Rocheltex in plating solutions. It apparently is a discontinued product but we are needing to determine its availability for certain and if there is a replacement.

Thank you,

George Hanna
Titan Corp. – Huntsville, Alabama
2002

A. I was unaware that Macdermid had discontinued the product. It is an anode corroder for cyanide copper plating used as a replacement for Rochelle Salts (a generic material. Manufacturers of cyanide copper plating additives make similar products that are generally interchangeable.

Gene Packman
process supplier – Great Neck, New York
2002