Summary for cadmium anode baskets Discussion
Anode basket material for cadmium plating is the central question in this thread. Steven Smithers of Kansas City says his cyanide cadmium shop is using titanium baskets but is seeing possible breakdown at very high pH, and he found conflicting guidance: plating books mention steel cages for cadmium anode balls, while a metal specialist recommended steel but said stainless steel would not carry the current. He also noted that regular steel may not be approved, while stainless steel was listed as approved in a spec. The reply says titanium is common, but steel was the traditional anode cage material for cyanide cadmium plating for decades and should work fine if that is indeed the bath chemistry. However, the answerer warns that steel baskets can create hard-to-destroy ferrocyanides, which may cause wastewater treatment problems. The answer also notes uncertainty about which approving body the questioner is referring to.
Q. I am a chemist for a cadmium plating shop and am trying to determine what type of metal to use for our anode baskets
⇦ huh? in a cyanide bath. We are currently using titanium but are experiencing some breakdown of this titanium metal, possibly due to the pH being above 13. I have looked in several of the popular plating books/manuals and they indicate the use of steel cages for use in containing the cadmium anode balls. I contacted a metal specialist and he recommended the use of steel but said that stainless steel couldn’t conduct the current requirements of our bath. To my knowledge, regular steel isn’t approved for use in this bath, but stainless steel was listed as an approved material for the spec. Any suggestions or recommendations would be helpful.
Steven Smithers
– Kansas City, Missouri
A. Although titanium is a common anode basket material, steel was the traditional anode cage material for cadmium plating for decades and it should work fine (assuming you are speaking of cyanide cadmium). Steel anode baskets can lead to the formation of difficult-to-destroy ferro cyanides, which might present a wastewater treatment problem though. I don’t know who you are referring to as the approving or disapproving body.
Good luck and regards.

Ted Mooney, P.E.
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