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Letter 6021
Recycling Chromating
Wastewater
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Dear Sir/Madame,
We do clear & yellow Iridite. We are looking for an
inexpensive way to recycle the waste water back into the system. For
the time being we neutralize the nitric acid and reduce the
hexa-chromium.
thank you.
Adel

- nepeab, ont Canada
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At today's cost structures, there may be no "inexpensive" way.
I have seen systems that employ ion-exchange to get the chromates
out of the rinse water so that rinse water can be returned; they are
fine but they only increase the overall chemical use compared to
end-of-pipe neutralization.
Unfortunately, chromates--unlike most plating solutions--are not
equilibrium processes wherein you can just add anodes and brighteners
and keep things in balance. Rather, the chromates chemically react
with the surface, and having done so they become exhausted
contaminants which should not be returned to the tank, whereby they
only would spoil it that much sooner.
I have seen more exotic and expensive systems where the regenerant
and backwash from the ion-exchange systems goes into an electrolytic
membrane separation system for regeneration, and it's probably a fine
idea. But when you say "inexpensive", uh, I don't think so.
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Ted Mooney, P.E.
finishing.com
Brick, New Jersey
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