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Letter 4884
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Raymond Hendrix H&H Equipment Troy, Tennessee |
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I believe we should take a step back here and look a little closer at this question. I don't know Chris's background from his brief letter, but with all due respect to him, if he is concerned about handling nitric acid (which won't strip anodize anyway) he obviously is not a person used to handling chemicals, as nitric acid is only one of many nasty chemicals in any typical metal finishers' shop. Hot caustic, even at 10%, is not something an inexperienced person would want to handle any more than he would want to handle nitric.
To me, telling Chris to use caustic for stripping is like telling an Indy race car driver who was just in a bad accident to switch to NASCAR- the odds are good that he can still get hurt.
The first sentence of Jim Watts' second letter expresses my advice to Chris- leave the stripping and refinishing to an experienced anodizer. If you are in a position where you must do this yourself, learn the proper handling procedures for hazardous chemicals. One reason that anodizing is done in the first place is because it is a relativley inert, chemically-resistant oxide. This means that removing it when necessary is not an easy task, and is almost impossible without handling something hazardous.
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Phil Johnson |
CHRIS,
I BOUGHT SOME ANODIZE REMOVER AT A CAR SHOW A COUPLE OF WEEKS AGO, IT IS CALLED SIMPLY ANODIZE REMOVER. THIS PRODUCT WORKS VERY WELL BUT PRECAUTIONS NEED TO BE TAKEN AS WITH ANY CHEMICAL. I USED IT ON ALUMINUM TRIM ON A 1960 CHEVY AND WAS AMAZED AT THE RESULTS. YOU SHOULD BE ABLE TO FIND IT AT ANY CAR SHOW WHERE VENDORS ARE PRESENT.
Brian Allison
- Shelby, North Carolina
Anodize coatings can be stripped using a dilute aqueous solution of phosphoric and chromic acid. There will be no etching of the parent metal. See Mil-A-8625 [link is to spec at TechStreet], especially the section on measuring the coating weight. The solution used for stripping the test panels can be used for production parts. Be sure to consider the dimensional change, Hard anodize can be in excess of 0.002". Don't mess with either chemical without proper safety precautions.
Sodium Hydroxide will strip the anodize coating (aluminum oxide) but will strip the aluminum even faster. I wouldn't do this in a production setting. I strongly reccomend you don't do this, but Drano [link is to product info at Amazon] (the plumbing cleaner) is a relatively strong NaOH solution. I know for a fact it etches aluminum in a hurry. As always, the resulting gas with Al and NaOH is hydrogen, which is highly explosive.
William Beeson
- Phoenix, AZ, USA
I Tried stripping a clear anodize with KOH (I didn't heat the
water though??) It seemed to strip it ok but left a dark film on the
part which would not rinse off with water but would wipe off with a
rag. The problem is there's a lot of engraving I can't clean the
residue out of. How can I clean these parts so they can be
re-anodized? Is the problem the KOH?
Thanks for your time.
Jeff A. Chapman
- Rochester, New York
Hi, Jeff. It would go a long way if you explained your situation and experience because we don't know the alloy, and whether it's a casting or extrusion or whatever, and we don't know your previous experience. It would be good if we had some idea whether this one particular part was a fluke that you encountered after previously stripping hundreds of parts, or whether you have no idea what to expect.
But a principle here is that KOH will dissolve aluminum but it will not dissolve the copper, silicon, and other alloying materials that are usually present to greatly varying degrees in aluminum parts. They remain and become concentrated and turn the part gray or black. An anodizer removes them with desmutting compounds which can dissolve copper and silicon, often including quite dangerous nitric acid and horribly dangerous hydrofluoric acid.
If you are not an anodizing shop it might be best to just leave the parts as is and let the anodizing shop do the desmutting. Good luck!
Regards,
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