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Bronze anodizing colour fading



Hello Everyone:

Very informative site!

We are having an issue with a shipment from our anodizer. The alloy was anodized medium bronze, with a hint of pinkish appearance ( twist part in light and it changes shade). As we were installing the parts to our equipment, over a span of 3 weeks, we suddenly noticed that the colour is starting to blotch and fade. Whats being left over, is basically a lighter shade of what is started. We have overhead fluorescent tubes in our assembly department ( could it be the cause?). Anodizer claims to have sealed the parts with a (nitric ?) sealer. He did a quick test, where he immersed the part in hot water. The colour remained the same.

What could be the cause and any suggestions as to what we should ask from the anodizer?

Thanks in advance,

Sulaman Khan
Engineer - Ville St-Laurent, Quebec, Canada
2007



simultaneous replies

Most bronze colored anodizing that I have seen is done with a process using ferric ammonium oxalate [FAO]. It's used a lot because the coloring matter is inorganic, hence, lightfast. Perhaps, a dye was used instead, this time?

Nitric acid is used in an ASTM test to see whether sealing was carried out properly. Nitric is applied to the part after coloring with a particular blue dye - lack of sealing on an area is revealed if there's an attack on the surface.

dave wichern
Dave Wichern
Consultant - The Bronx, New York
2007



Questions for your anodizer: (1) nitric? seal or was it nickel acetate which is standard for colored anodic coatings, (2) was organic dye or 2-step process used [organic dyes subject to fading due to light exposure whereas 2-step resists fading], (3) thickness of anodize [amount of color is dependent on depth of penetration whether dyed or 2-step], (4) what is hot water test? only will tell if totally not sealed or very poorly sealed - a better seal integrity test would be ASTM B136. Hope that helps for now.

milt stevenson jr.
Milt Stevenson, Jr.
Syracuse, New York
2007




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