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Etching, deoxidizing, anodizing, sealing issues with 2219 aluminum


ETCHING

Q. I am trying to find an etch (i.e., the ingredients) to clean a 2219 aluminum assembly prior to welding to reduce the amount of porosity in the final weld.

Robert Allen
- El Monte, California, USA



A. If you can't go for proprietary blends, nitric acid with a fluoride salt is needed if you use a silicated non-etch cleaner and no etching in between. If you want to chemically polish you can try mixtures of nitric, phosphoric, acetic acid with water at room temperature or a little higher.

For the alkaline etch or cleaner, it really doesn't pay to try to formulate your own cleaner. Surfactants make all the difference, and it doesn't pay to buy them and mix them yourself. See the Chemicals directory for suppliers.

tom pullizzi portrait
Tom Pullizzi
Falls Township, Pennsylvania



DE-OXIDIZING (1998)

Q. Has anyone had any trouble using a deoxidizer with fluoride as an ingredient on 2219 Aluminum.

Garry Pickett
aerospace - Los Angeles, California


(1998)

A. We are the largest user of 2219 aluminum in the country. We make/made the External Tank for the Space Shuttle. We use fluoride in our deoxidizers successfully for many years.

Michael Campbell, Senior Materials Engineer
Lockheed Martin Manned Space Systems


(2002)

Q. Sir, please help me in providing information regarding removal of copper from aluminium alloy 2219 from its surface.

Thanking you sir,

Ravi Kumar
- Chennai, India



A. Hi Ravi.

The step being discussed here, de-oxidizing (more properly called de-smutting) is about removing the copper, silicon, and other non-aluminum alloying materials from the surface of the aluminum. The simplest, but not only, path forward would be to contact a supplier of metal finishing process chemistry and ask for a de-smutter for series 2xxx aluminum. If I am misunderstanding the question or your situation, please get back to us.

Regards,

Ted Mooney, finishing.com
Teds signature
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey



Surface Treatment & Finishing of Aluminium and Its Alloys
Wernick, Pinner & Sheasby





probert book
Aluminum How-To

by Robert Probert
$89 New
The Chromating - Anodizing - Hardcoating Handbook

ANODIZING

(2006)

Q. I am trying to anodize an aluminum alloy 2219. But it is not getting properly anodized. What type and class of anodizing should I use. I am a lecturer in GIKI and want to demonstrate to the student the process of anodizing.

Muhammad Bashir
GIKI - Pakistan


(2006)

A. Hello Muhammad. Type II is easier than Type III (hardcoating). This type of aluminum requires proper desmutting before anodizing, then a bit higher voltage than the easier aluminums (could push 18 volts); otherwise, standard amperage, chilled to cool room temperature, standard concentration should work even if not optimum. If you tell us the voltage, current, temperature, and concentration you are using we may be able to spot something you are doing wrong; but it is hard to summarize everything that you should be doing right because that subject fills whole books :-)

As a quick tip, though, consider anodizing 1xxx or 6xxx series aluminum for your demonstration instead of 2xxx because the high copper alloys are more difficult; and if you sample is old and the grain boundaries have become more pronounced, it will be even harder. Good luck.

Ted Mooney, finishing.com
Teds signature
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey



SEALING

September 20, 2012

Q. We have some aluminum 2219 forgings that were anodized to Mil-A-8625 [link is to free spec at Defense Logistics Agency, dla.mil] Type II several months ago. Some of the parts that were stored in a damp environment have experienced pitting.

Is there a test that we can perform months after anodizing to confirm that the parts were anodized and sealed properly? An anodizer that we consulted suggested that the parts may not have been sealed adequately. I have looked at ASTM B457 [link by ed. to spec at TechStreet] but too much time has elapsed. We can't use ASTM B680 [link by ed. to spec at TechStreet] because it's destructive and we do not have a test specimen that we can sacrifice (only the finished parts). People mentioned a "Sharpie" or dye test but per ASTM B136-84 [link by ed. to spec at TechStreet] , the dye test is not applicable to alloys with greater than 2% copper.

Matt Terrell
Engineer - Pittsburgh, Pennsylvania, USA


September 22, 2012

A. Neither of the tests you mention are in accordance with Mil-8625-F. That spec calls out two tests that pertain to seal quality: Salt spray (ASTM B117 [link by ed. to spec at TechStreet] ), and light fastness. I'm assuming your parts are class 1, not 2 (dyed). If they are class 1, the light fastness test would not apply.

I'm not sure why you're hesitant to perform a potentially damaging test to your part(s) if they are no good as it stands now.

To add a bit of defense to the anodizer: The alloy you mentioned potentially can be up to 6.8% Cu. It's very possible that your lot of material was not very homogenous, and the pitting you are seeing is the result second phase Cu particles.

Sorry I can't be much assistance in recommending any additional testing outside of the ones you mentioned, but keep in mind that you can't hold your anodizer responsible for meeting testing requirements that are not listed in the specification, unless you specified that on your purchase order. Also keep in mind that most, if not all, seal quality testing (except impedance, or admittance) will damage the coating in some way if the parts are not properly sealed.

Here's a link to the spec which details the testing requirements to insure parts meet the specification.

http://www.wbdg.org/ccb/FEDMIL/a8625.pdf [ed. note Nov. 2016: sorry that link is now broken].


Marc Green
anodizer - Boise, Idaho


October 1, 2012

A. Dear,
Alloy 2219 and all 2xxx Alloys are more susceptible to pitting corrosion than other Aluminum Alloys even though the samples are sealed. 2219 alloys are Graded C in Anodizing process (Poor Protection) and show also some conductivity even after anodizing due to copper content on the surface. Those areas which have copper will have no protective layer, making a suitable dig for pitting corrosion. So it's not the matter of sealing.
Thanks

Hammad Haseeb
- Islamabad, Pakistan



January 8, 2016

Q. Hello Friends,

We are getting more and more 2219 for hard anodize and we are still having issues. The customer wants 1.8-2.2 mil of coating. Our process parameters are the following:

Clean
Etch
Deox

Hard Anodize is at 16% w/w sulfuric acid at 32 °F and we have a proprietary additive as well.

I tried a sample rack of 9 parts. I meticulously measured the surface area I had as best as I could (3.05 ft2) and calculated that to get 24 asf, I would need about 73 Amps. I ramped up to 73 amps in 5 minutes and I was going to hold at 73 amps for 54 mins to get 1.8 mil per the 720 rule. We don't have a hold amperage feature on our controller yet so we were manually adjusting the voltage as needed to hold the 73 amps. A strange thing would happen during the run. It would be holding fine at 73 amps and then out of nowhere it would start to run away and increase in amps rapidly to 50 or 60 amps higher. I would drop the voltage back down to prevent the burning and it would stabilize again at the 73 amps. It did that 3 or 4 times during the whole run. I thought it was very strange. I've never seen anodize do that before. At about 30 mins, I stopped the run to take the parts out and see how they were doing. I was baffled when I took them out and I saw all these spots on them (I called them measles). It almost seemed like it was anodizing selectively at certain spots and not on others. I continued the run to see if it would fill in but that never happened. I decided to measure them anyway and I had some parts with almost 3.0 in thickness and some with 0.8. I only had one burned part.

We tried again yesterday with a full load of parts but ramped them slower and we were only anodizing at about 20 ASF to see if the slow coating buildup would help the problem but the same pattern occurred. The parts were holding at amperage and would run away high again to about twice the amps it should be. This time we would wait to see if the amps would go down back to where they were before and eventually it did after a few minutes. We checked the parts and didn't see any burning. Super strange. It still had the measles spots but we just kept running it slowly until the parts looked all anodized. We measured them and they were over 3.0 mils

Does anybody have any suggestions? Why does it spot up and run away in amps? Any advice would be welcome.

Thanks!
Geronimo

Geronimo Cebrero
- Oxnard, California USA


January 2016

A. Hi Geronimo. In my limited experience those current fluctuations are the result of poor contact. What happens is the voltage is low and the contact is weak, so one part is not anodizing. Then you gradually raise the voltage and you reach a point where it's high enough to break through whatever insulating film was keeping current from flowing to that part. Now you not only have more parts drawing current, but one of them has no anodizing built up on it, and the voltage is already high, so it's draws too much current and burns, while starving the other parts.

The racks we see in the photo don't appear to be the anodizing racks but racks for some subsequent process. [ed. note: Photos were removed at request] Are you sure the anodizing racks make good contact with all parts all the time?

Regards,

pic of Ted Mooney
Teds signature
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey



Is it possible to hard anodize 2219 with a coating thickness of .001"?

November 29, 2016

Q. We have a drawing showing a .001" hard coat on a 2219 part. We're only able to achieve .0001 - .00015" of build up (with a total anodized thickness of about .0005" tops). Should we keep trying or have we reached the limit of what we're likely to achieve with this material? I believe our anodizer is using additions in the anodizing solution to reduce breakdown by sulfuric acid during the process but not sure what those are or what concentrations. Anyone able to offer any help/suggestions?!

Lucy Parker
- Seattle, Washington USA


November 30, 2016

RFQ: Well, from looking at previous responses to questions on this topic, it would appear that we absolutely should be able to achieve .001" anodized coating on 2219. Can anyone recommend an anodizer who might be capable of doing this?
Thanks,
Lucy

Lucy Parker [returning]
Aerospace - Seattle, Washington, USA
  ^- Privately contact this inquirer -^


November 2016

A. Hi Lucy. People are welcome to suggest what might be done to improve the anodizing, but this forum of camaraderie and technical help is only available to us all through the generosity of our supporting advertisers. We can't ask them to pay the cost of postings which steer potential customers to their competitors. Our supporting advertisers are invited to contact you, and you may review the list of anodizing shops supporting the site. It looks like putting "hardcoat" into the shop search will offer 6 places you can talk to. Good luck.

Regards,

pic of Ted Mooney
Teds signature
Ted Mooney, P.E. RET
finishing.com
Pine Beach, New Jersey

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