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Letter 42078
Faraday effect in chroming yields
"trouble areas"?
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Could anyone please confirm me, that when a chroming plant tells
me, that because of the Faraday effect my product might suffer from
weaker chrome plating in some trouble ereas, namely around place
where two tubes are welded together.
I take it to understand, that because of the differently distributed
mass of steel in the product, the conducting of electricity varies
and consequently has less "plating effect" in the "trouble
areas?
Thanks in advance.
Morten Hecquet
importer of Towel radiators. - Kolding, Denmark.
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It is true that plating thickness is usually lower in low current
density areas, and that chrome plating may be absent in those areas
if careful attention is not paid. You probably should specify, and
insist upon, full coverage with chrome and some minimum nickel
plating thickness. Regarding the nickel plating thickness, it is
common to specify the minimum thickness for any area that can be
touched by a 3/4" diameter ball rather than debating whether it is
possible to measure the thickness in a weld crevice and things like
that.
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Ted Mooney, P.E.
finishing.com
Brick, New Jersey
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Only to add the mentioned effect is related to the shape of the
part. The current sees the surface and prefers tips and edges
refusing inside corners and cavities. Mass has nothing to do with it.
Guillermo Marrufo
Monterrey, NL, Mexico
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Hexavalent chromium plating solutions are very inefficient and
also require a (relatively) high current density. Consequently, when
there is a wide current density distribution on an article, the
chromium thickness will vary significantly. The combination of poor
efficiency and high cd requiremenst makes the problem worse. As a
rule of thumb, the highest current densities are on the edges of
articles and the lowest is in the middle. Consequently, you will get
chromium build-up on the edges and a much thinner deposit at the
middle. If there is a variable conductivity on the substarte, this
too will ahve an adverse effect on the thickness control. Thickness
can be controlled by careful design of the product and by using
robbers and/or secondary anodes to redirect the current to where it
is needed.
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Trevor Crichton
R&D practical scientist - UK
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