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Letter 12589
Magnetic character of stainless steel
explained
I would like to know the chemistry explanation of why when Nickel
is removed from stainless steel, it loses its magnetic
characteristic. For example, stainless steel 430 is magnetic but
304,304L,316 and 316L are not? It is important to know whether this
has to do with the atomic rearrangement that affects the polarity of
the iron.
Adoga Kiharangwa
poultry farm - Delhi, California, U.S.A
Adoga,
I will attempt to answer this question without getting too deep
into the metallurgy.
The difference in magnetic properties is due to the structure of
the material at room temperature. The structure is due to (in most
cases) the chemistry and thermal processing of the steel.
Nickel is added to stainless steel to stabilize the austenitic
phase. Most 300 series stainless steels contain sufficient amounts of
nickel so the structure is austenitic at room temperatures.
300 series stainless steel (also know as Austenitic stainless
steel) has "higher" nickel contents and consists of a single phase,
(austenite) which is non-magnetic.
Most 400 stainless steels have "lower" nickel contents and have a
martensitic or ferritic structure (both of which are magnetic).
As with anything in metallurgy, there are lots of exceptions. As
an example, there are actually five types of stainless steel
(martensitic, austenitic, ferritic, precipitation-hardening and
duplex). To make matters more interesting, 300 series stainless steel
can be made magnetic with sufficient amounts of cold working. The ASM
Metals Handbooks are a great source of additional information.
Matthew Horton
- St. Paul, Minnesota
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