Reverse electroplating for gold recovery
Q. How profitable is the aqua regia gold refining project? I am much interested in setting up a gold & platinum recovery project here in South Africa. I have read a lot about aqua regia technique from the material I got from SHOR INTERNATIONAL. As of now I really understand how it works and all the safety precautions to be honored when refining the boards. I also have a large quantity of scrap 486 mother boards. All I really want to know before I invest a lot of money purchasing the necessary chemicals is, is it a project I can rely on? Is it worth the risk? Somebody please advise me before I waste my money.SMART CHIRERU
GOLD FEVER - DURBAN, SOUTH AFRICA
Q. I have the same question but I would like to know a bit more detail. What's the average recovery or what kind of recovery can I expect from refining gold circuit boards? I am also curious about the gold that is used on these boards. What is the gold alloy used? What percentage of gold does it contain?Jared Thibeau
- Toronto, Canada
A. Hi Jared. The gold plating on circuit boards will usually be 24 kt, or very close, but the issue is that the plating is very very thin. On reasonably current computers it's probably something like 20 millionths of an inch on the tabs -- and half of that in other areas. Calculate how many square feet of gold plating it takes to get a worthwhile amount of gold.
Ted Mooney, P.E. RET
Brick, New Jersey
Q. I am interested in the method of gold recovery from mix metal gold using a salt solution and a high current DC source (both of which I have available). Can anyone tell me more or exactly how to go about it? Does it leave the copper, lead and tin behind or are there more steps to the process? What is GC salt?Yogesh Soni
- Ahmedabad, Gujarat, India
A. Hi Yogesh. "GC" probably means gold cyanide, or more exactly, potassium gold cyanide.
Ted Mooney, P.E. RET
Brick, New Jersey
Q. Most electronic chips have a ceramic enclosure. Gold wiring sits inside this enclosure.
research - Cordoba, Argentina
Recovery And Refining Of Precious Metals
A. You must crush the chips in order to get inside of them, a rock crusher works quite well for this, I understand that you can recover between 1/20 and 1/100 of a gram per chip depending on what chips you are processing.Donald Franson
- Tulsa, Oklahoma
A. Hello, these following (non business) hobby websites mention the same article dealing with the security of microprocessors, and details how one might dissolve the packaging materials (using fuming nitric acid) I think.
Now, I don't know how this might affect the following processes for gold extraction, in fact I think it might dissolve everything EXCEPT the silicon wafer - wasting acid and leaving you with a messy sludge! which is why I probably won't be using a method similar. You want to expose as much gold as possible. crushing preferred...
my personal chip website:
and from whence the article came:
My process has been to heat the chip cover over a Bunsen flame, and pop off the gold plated (both sides!) cover. Now very careful - ceramic gets VERY HOT and retains heat for a few minutes! In small 286, and larger 386 and 486 chips, there are many pure gold bonding wires, easily seen and accessible. In ALL gold-top pentiums, and pentium pros, and IBM etc/other CPU's there is the same. Later CPU's have less and less. See my website to view some nice gold-tops. The smaller black chips generally have no gold content worth the trouble. i.e., if you can't see it on the outside, there isn't much on the inside! but if you are dealing in millions of chips, this becomes a differing story!
I initially scraped the fine gold bonding wires off with a fine blade onto a glass plate for collection. Now, there is more gold in them there chips, however it is plated on the pins, it is on both sides of the cover, and it is also internal to the ceramic, you can see the plated traces running into a layer of ceramic, actually many layers.
What I intend to do is crush/grind/pulverize the complete ceramic chip, and extract the gold with the aqua-regia method. I would like to try the electroplate salt-water and ceramic tray method and have finally figured all the steps and chemicals involved. However just trying to source the ceramic dish/tray/cup and chemicals in new Zealand is proving to be a royal pain in the ears!
I hope I may have enlightened and educated some. And please please, take notes of all the concerns of the experts - this isn't really a home hobbyist project, nor is it a great earner for a home hobbyist either. Try and work with a simple cup of water, practicing not to spill a drop in transferring, filtering etc - and see if you can! Remember that simple microscopic drop could mean a serious burn, or blindness from a miss-wiped face.
Also, personally, I would not attempt the cyanide processing method unless you are prepared to invest into a serious refinery, requiring serious people with serious knowledge and expertise, the cutting of lots of red-tape, lawyers, legalities, zoning, health and safety, etc etc....
elements collector - Auckland, New Zealand
Q. I have several thousand small bus-bars that were apparently used in a 1960's era PBX telephone system.The base metal is magnetic, but they are 24 carat gold plated.
I would like to remove the gold in the most economical, efficient , and safest possible method.
Any suggestions will be appreciated.
hobbyist - Dublin, North Carolina
Q. TEE SIM,
I also have gold plated computer/telephone system parts. It seems very difficult for hobbyist like us to find a cheap, safe way to remove the gold. I have cleaned about 50 pounds worth of pure gold parts. Clean meaning just the gold part itself. If you find an answer please let me know please, and if I find anything I'll do the same for you.
- Blythewood, South Carolina
A. Hey TEE SIM & DAVID A. HARTNESS
I have idea for you just strip the isolation and keep the core inside sale those to the people who making jewelry , they can use that to make gold plating necklace etc. Easier and better for you
- San Jose, California
Q. Does anyone know how much gold is in a average desk top computer and what percent can be recovered. thanksBill Walden
hobbyist - Burleson, Texas
Q. Hi everyone, I've been refining my own gold from computer scrap for years now. I use a nitric digest on gold pins and components that are gold plated, that puts almost all the other metals into solution (except the gold), which I pour off most of, then filter the rest. What is left on the filter is "dirty gold". Then I take that and put it into aqua-regia solution. Makes a pretty bright yellow solution. Then I drop the gold out of the solution with sodium sulfite. That leaves the gold looking like a nice reddish brown dirt on the bottom of the jar. I filter this out using Whatman ashless filter paper. Then I burn off the filter paper and I'm left with 99.999% pure gold! Some times, however, I have to deal with "the blue goo" which plugs up my filtering, (in the nitric digest phase).This happens when I haven't gotten all the solder off the parts. You can't have solder on anything. That's my method in a nutshell. Any feed back is welcome.Yvonne Torburn-Clark
- Mountain Ranch, California
Chemistry of Gold Extraction
Q. In response to Yvonne's post, Question: What is the composition of your nitric "digest". Your post seems the most sane for my hobby pursuit and quest for a solution to all this stuff laying on my workbench.
- Springfield, Illinois
A. In response to Dennis Nichols question; I just use nitric acid and distilled water, about 60-40 ratio. Eats up almost (but not all) metals but the gold. And thanks for the compliment, YvonneYvonne Torburn-Clark
- Mtn. Ranch, California
Q. Hey all, just looking at the thread and see a lot of interesting information. Very informative. I work/volunteer at the local computer recycling center here in Oregon and was looking for a way to boost profit margins. Currently we are stripping computers and shipping parts (by the 4x4x4 foot pallet) to various locations for precious metal recovery. My questions is, what is the #1 recommended way for the average hobbyist to recover the gold. Is that method something that can be used as a lesson for a class? Say 2-4 hours? What is the average amount of AU in the average processor? Easiest method of recovering gold scrap? Shall I scrape gold fingers off of circuit boards? What should I store those scrapings in? Glass, plastic, or metal container? Recommendations? Is it really worth all the time and expense? What is the average ROI for example if I use the aqua regia method? Any input would be nice as I really am interested in the recovery process (and keeping e-waste out of the landfills) and also the end product... GOLD. Any input would be nice. Thank you.Rian Smith
hobbyist/e-waste recycler - Portland, Oregon
My short answer is that mechanical separation & sorting sound worthwhile and may extend to such measures as smashing plastic connectors to get to the gold, cutting circuit boards to separate gold contact areas from the bulk of the board, etc. But please remember that all of the major environmental organizations are begging you not to do this for two reasons: first, amateur recycling is a wrecking ball that spreads the e-waste toxins everywhere instead of keeping them in manageable units like a computer or TV; second, when people "cherry pick" the waste, the recovery of the balance of the equipment becomes economically prohibitive which means it will not be recycled, but these toxins will be left to contaminate the earth.
Any operation which involves burning or chemical treatment should be left for a real refinery anyway. Proper refineries cost tens to hundreds of millions of dollars.
I realize that others may disagree, but in viewing pictures from China and India, you see the human toll and environmental toll of e-waste recycling by amateurs; you also realize that your competition works almost for free.
The best long-term solution to e-waste (as far as I can see, and not taking into account the law of unintended consequences) seems to be laws that require the manufacturer to take it back at no charge for disposal at end of life.
Ted Mooney, P.E. RET
Brick, New Jersey
Wow... after reading all this, I've decided to pay someone else to do it!Mark Sullivan
- San Jose, California
The subject of do-it-yourself gold refining has raised it's ugly head on this forum many times. With the present high gold prices, interest in this subject is building and isn't going to go away. There is very much dangerous misinformation on the internet. On Ebay, there is a fair sized cottage industry providing gold refining info, some good and some bad - mostly overpriced. Several months ago, a gold refining forum was set up (not by me) to provide honest, free information, keep amateurs safe, and properly handle waste. In 6 months, there are over 700 members and over 8,000 posts. There are 2 or 3 of us on the forum who have been professional gold refiners for many years, that attempt to act as a stabilizing factor. Personally, I feel that refining should be done by the pros but, if amateurs are going to do it, they should do it right: goldrefiningforum.com. I would imagine that this forum has already taken some of the burden off of finishing.com.Chris Owen
Ed. note: Chris has been a great responder at finishing.com and we thank him for his efforts and the education! Also a number of people have been very complimentary about his forum.
February 23, 2008
Q. I found 1/2 pound of white color of gold salt, from an old plating company. How can I recover the gold from this formationHarry Kaspar
melter - Los Angeles, California
March 3, 2008
Q. Yvonne's method sounds good, how do you retrieve other metals, like silver? Bill.bill douglas
gold prospector - gold beach, Oregon
May 12, 2008
THANK YOU BROTHERS AND SISTERS,
I've got it. I've been reading this page and others to figure out the process and I've got gold from old e-scrap that I collected for 3 years and got a nugget the size of a quarter and 3/16 of an inch thick. Well here's your answer: titanium metal, a white flame heat source and borax [linked by editor to product info] is all you need, these chemicals. Please work in fresh air also butane don't waste your time and money, think hot heat and even consistent heat does a nice easy job.
PS. I've got gold so let this economy go to double tooth picks RRRReal money!
- St. C., Ohio
June 3, 2008
A. This is Very Simple and is the basis of all Chemical Gold recovery in the Au gold mines in the early days.
Take the gold coated item , (we do this with gold tailings in exploration) Boil it in a solution of Concentrated household bleach,50% water to bleach 50% for 45 Min.
Drain off the solution
Put in plastic pail
Put in stainless Steel rod (one side)
Put in roll of wire wool (other side)
get a powerful battery charger
Attach (plus) to wool and minus to SS rod.
Turn on Battery Charger .
leave 40 mins, Gold will be converted from solution to the wire wool.
Take wire wool and dissolve in crucible in hydrochloric acid, carefully drain off the acid and keep sludge at bottom.
Place crucible over Bunsen burner and melt.
Small gold nugget will form in the bottom.
PS be careful to vent off the hydrogen gas with the electrowinning stage.
- Fremantle, West Australia
November 23, 2008
Q. To the gentleman from Australia- will this process (boiling in bleach solution) work to strip/recover the gold from gold plated items such as jewelry? Thank you in advance for your answer.Terry Larson
- Evansville, Indiana
February 11, 2009
Q. My question goes along with Mark Strologo of Fremantle, West Australia --
I already have my gold (as gold chloride) in a salt solution (as in sea salt). Do I go ahead and electroplate the gold out and skip the boiling procedure?
Any help is appreciated.
hobbyist - the woodlands, Texas
November 2, 2008
Q. I HAVE BEEN USING NITRIC ACID TO RECOVER MY GOLD AND HAS WORKED GREAT FOR YEARS I COLLECT 100% OF ALL MY GOLD. NOW WHERE I BUY MY NITRIC ACID HAS DECIDED TO TAKE THE PRICE UP TO WHERE IT IS NO LONGER EVEN CLOSE TO BE PROFITABLE. I WANT TO USE REVERSE ELECTROPLATE SINCE I HAVE THE MACHINE ANYONE KNOW WHAT ACID I USE FOR THIS? THANKS ANDYANDY BOYTOR
HOBBYIST - HOUSTON, Texas
December 1, 2008
Q. May I have the following questions and thank you for your kindly answer and suggestion
1. How many percentage of gold can be recovered from electronic scrap?
2. How many miligram contents of gold in separated CPU per kilogram?
3. How many miligram contents of gold in PCB?
4. What are the needed tools to start the recovery job?
5. What kind of scrap can be recover the precious metal except computer parts or cell phone?
hobbyist - Bangkok, Thailand
December 29, 2008
The answer to most of those questions are trade secrets of sorts, so it seems. If you discovered a gold vein, would you go broadcasting it and start a stampede to it?
- Penticto BC, Canada
May 9, 2009
Q. What are your feelings on using a solution of 1/3 muriatic acid, 2/3 Hydrogen Peroxide and taking the gold flake recovered and superheat it with a butane minitorch and some flux. I am having difficulties with the flux (how to make it/utilize it} any suggestions?James Franklin
- Indianapolis, Indiana
June 20, 2009
Q. Hi Guys,
Just a quick question for you all and being totally naive:
Recovering metals such as gold & copper from circuit boards, can electrowinning be used? If so, how does the process work? Do you crush and pulverize the PCB's, put them in the electrolyte solution, then that solution is processed by sending a charge through the cathodes and anodes. Finally you pull out either the plating or the powder and discard the electrolyte solution after neutralizing it?
Is this correct or am I way out?
Thanks for your replies in advanced
student - New Zealand
July 11, 2009
Hello, will the Aqua Regia method work with gold filled jewelry to extract the gold? If not, how would I go about that?
- Gilbert, Arizona
November 6, 2009
A delightful blog but I am concerned about the cyanide phobia evinced here. Certainly a serious substance but, in the matter of science, exaggeration is unwarranted.
November 6, 2009
The owner and plant manager of Film Recovery Systems in Chicago made the front cover of the national news magazines some years ago when they were convicted of 1st degree murder over the death of one of their employees. They claim the man (59 years old) simply had a heart attack; the prosecution claimed a reckless death from cyanide.
I've spent my entire career in the plating industry, and until fairly recently, most shops used cyanide plating solutions, many still do. The concept doesn't frighten me at all, but it is SO easy to make a serious mistake. I can't count the times I heard of people accidentally adding dry acid salts to a cyanide tank, or cyanide powder to an acid tank, making the area a California Gas Chamber if not INSTANTLY evacuated.
November 17, 2009
WOW! Talk about serious fear mongering. While it is true that cyanide is a serious poison, it is far safer than Aqua Regia. Proper safety protocols and common sense allow cyanide to be used quite safely. It is by far the safest and most economical method for extracting gold from most ores and stripping scrap and etching metals for plating. It is easily destroyed by oxidizing with bleach or peroxide and will breakdown rapidly when exposed to sunlight and air. Mining companies use many thousands of tons of the stuff with virtually no problems (except when someone screws up bad). How many people drown in water every year? How many die from gasoline fires and ingestion? Pesticides?
- Bishop, California
November 19, 2009
Hi, Roger. In addition to working with sodium cyanide and potassium cyanide in electroplating processes for brass, cadmium, copper, gold, silver and zinc plating for 40 years, I designed & installed many wastewater treatment systems for cyanide destruction. I don't fear cyanide, I have proper respect for it.
People who work with cyanide in industry usually:
This thread includes many entries by amateurs with no appreciation of the hazards of cyanide, and educating them that it is an extremely powerful and fast acting poison, both by ingestion and accidental acidification, is not fear-mongering but a reasonable attempt to instill healthy respect.
February 16, 2010
What about this Electrolytic action for removing gold from E-Waste. Is this a good process for a small 1 bdrm operation?Will Davis
Hobbyist - Springfield, Michigan
November 6, 2011
I recently purchased a thumb cell refiner with the intent of refining sterling silver. I am writing this in hopes of shedding some light on there advertised statement "Requires no experience". Lets see, how do I say this...HORSE HOCKEY!
First of all, the 'instructions' which they admit are the heart of the product you are buying, are vague at best. Prior to the purchase, I did a lot of reading and fortunately, am equipped with all the proper safety accessories. That being said, I am going ahead with a run. They say in the massive 2 page instructions (without diagram 1, or photos!) to use "... a flat thin piece of pure silver (your cathode)." 3 paragraphs later they say "...assemble the unit and connect your silver anode and graphite cathode to your rectifier." So, is it best to use pure silver for a cathode, or the graphite rod? They NEVER mention ratio of area between anode and cathode. I might mention the 'kit' comes with a 5/8" x 12" round graphite rod.
Also, if someone would be so kind and would offer some help, they say NOTHING about recovery of the 250 grams of pure silver used to make the bath, nor do they mention anything about neutralizing the bath for safe disposal once it is no longer able to produce pure silver.
Now I know you're all wondering, did I contact the seller for better instructions?....Yes I did, and the resulting 'answers' served to confuse me more than inform me.
I am logging the entire process as I go, and when I complete this process, I'll offer to sell them back a REAL set of instructions, complete with a diagram, suited for the "Requires no experience" crowd. I know, I'm dreaming, but I thought everyone could use a little humor.
- Atascadero, California USA
Ed. note: Thanks Mark. For a bunch of reasons we strive to keep the discussion generic and to not slam individual products, so we have removed the name of the thumb cell refiner vendor.
January 11, 2012
Hello have you tried a PCB etching solution like ferric chloride this will dissolve the copper under the gold leaving the gold flakes. The bad thing is that this will dissolve other metals like the lead silver and it will exhaust itself very quickly but if you protect the other metals with a lacquer leaving the gold exposed this would result very cheap
- Albuquerque, New Mexico
March 10, 2012
I'm new here, stumbled on this site looking for a simple way of collecting Gold off of plated jewelry ...
I do not want some big production... a small and simple procedure would be fine. I am not a chemist but I've worked with some nasty stuff, I know how to be safe and environmentally friendly.
It seems Reverse electroplating is the answer... the chemicals seems to be expensive and needs to be purchased in large amounts and some are hard to find. The aqua regia process seems dangerous and tricky, there has got to be a simpler way... I've seen it on YouTube, a glass dish Reverse electroplating jewelry... What is needed for that?
- Paramus, New Jersey, USA
May 2, 2012
Q. Lately, several plating companies tell me they DO NOT do reverse deplating. I am suspicious but don't know what else to ask. I have quite a bit of gold plated objects, and I don't want to start a new business just to sell it. Can anyone tell me who buys gold in plate form, or who will strip it and buy the gold?Al Pelletier
- Sekiu, Washington, USA
A. Hi Al.
In these days of prolonged recession there are "We buy gold" stores on every other street corner in the cities and suburbs. If they are uninterested in buying it, it should give you a sense of its value. Modern gold plating tends to be from 10 to 40 millionths of an inch thick, often even thinner. You will see many costume jewelry manufacturers rejecting the idea of "micron gold" (coatings of 40 millionths thick) as being thicker than they are willing to apply. Please do a simple volume calculation of how much gold you actually have. Good luck.
Ted Mooney, P.E. RET
Brick, New Jersey
August 20, 2012
I have reversed plating of gold in an acid bath; now how do I get it to gold bullion?toni parker
- TUCSON, Arizona, usa
September 17, 2012
Q. Where can I buy the acids for the extraction of gold from computer/cell phone parts. I have so many cell phones and would be willing to sacrifice them but would not do me any good if I can't extract the gold, and would it be worth it? Any help or info would be appreciated.sam serna
- san jose ,california u.s.a.
September 18, 2012
A. Hi Sam.
Acids are readily available =>
October 29, 2013
A. Firstly, I am not an authority on this subject. That said, is abrasion an option? A firearms cartridge tumbler with an aggressive abrasive. Pan the residue, then melt it. Gold will be at the bottom, won't it? Perhaps just skip to the melting. Even the copper will have value.Jonathan Cochran
- Pyeongtaek, S.Korea