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Letter 138
Rack plating with acid zinc
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From a conventional potassium chloride, boric acid system what
affect does high zinc (ex. 5.5 oz/gal) or low zinc -2.5 oz/gal) have
on:
A. Plate thickness distribution from high to low current
areas?
B. Overall rate of plate thickness?
1. What affect does replacing boric acid with ammonium chloride
have on A & B above?
2. What affect does high temp.( 110 deg vs. 85 deg.) have on A &
B.
3. What is recognized as Max. voltage level in chloride zinc rack
system?
4. Is a zinc plate rate of 1/10 Zn in 10 min. at 10 amps/sq.ft.
considered avg., below, above ?
I realize this is a lengthy question, however, any input would be
greatly appreciated.
Erik Esarlano
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A. The theoretical effect of higher metal concentration
is an increased tendency for plating thickness to track the
geometry of the current flux--that is worse thickness
distribution.
B. But faster plating.
1. I think the function of the boric acid is the same as
in a nickel bath--as a pH buffer to offset the tendency of
the bath to rise in pH as water hydrolizes into hydrogen
bubbles and hydroxyl ion (alkali). I don't know how
effective ammonium chloride is in this regard or if it
serves a different function.
2. In theory, raising the temperature has the same effects
described above under raising the metal concentration. But
in actuality, brighteners degrade faster at higher
temperatures; I believe that proprietary brighteners for
ammonium chloride baths can take 110 or more, while those
for potassium chloride baths are much more limited.
3. Voltage depends on anode to cathode distance, but 6 to 12
volts is pretty common.
4. Sounds right on target, but the math can be checked on
page 791 of the Metal Finishing
Guidebook.

Ted Mooney, P.E.
Finishing.com Inc. - Brick, NJ
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