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52068
I want to plate copper jewelry with gold
color via p.v.d. coating process
May 7, 2009
I want to plate gold on copper finish jewelry with high durability
of gold plating with lower cost than real gold direct forming by
rectifier .
Agrawal Abhishek
- Khirkiya-M.P.INDIA

May 15, 2009
Firstly, PVD is more expensive than conventional electroplating
becuase you need a high capital expenditure on a vacuum system and
chamber. Assuming you have access to a PVD system you need to deposit
a thin layer of TiN (titanium nitride) - this will give you your gold
colour. However, it may not be the right colour for you, so you can
then plate the TiN with a thin layer of gold. If your TiN is too
thick, you will have problems depositing the gold, becqause TiN is
rather non conducting. The trick to it is to use the substrate's
conductivity to deposit a thin layer of gold over the TiN, using
discontinuities in the TiN layer to allow the current to pass through
the TiN. You will get increased wear resistance this way, because the
gold will be deposited over a rough TiN surface and it will fill in
the "valleys" in the TiN. The gold on the "peaks" will wear away to
expose the much harder TiN and this will then protect the gold still
left in the valleys.
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Trevor Crichton
R&D practical scientist - UK
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May 18, 2009
Actually, TiN is a very good electrical conductor. As noted, you
may have to add a gold layer on top to get the exact color that you
want. Another way is to deposit an alloy nitride, mixing the titanium
with zirconium. ZrN is more of a champagne gold. Addition of a little
carbon to either will darker the hue. You have to be careful with the
carbon, though -- too much and you get magenta.

Jim Treglio
- San Diego, California
June 1, 2009
A layer of gold on TiN is generally deposited on watch straps,
cases etc in the same chamber by PVD. However depositing gold by PVD
requires huge investment in gold and recovery of unused gold is
difficult. It would be ideal if gold can be electroplated on TiN. But
it appears to be difficult.
H.R. Prabhakara
H.R. Prabhakara
- Bangalore, Karnataka, India
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