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43074
Resistance of Rhodium Plating
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Rhodium can wear off gradually on rhodium plated silver jewelry.
It is said to depend on the plating thickness and the actual "wear"
the jewelry is subjected to how long it takes. Is it possible to
explain a little about the relations betwen thickness in micron and
resistance to wear.
What thicknesses are primarily used for rhodium plating of silver
jewelry (rings and bracelets).
Does Platinum plating generally provide a better resistance against
wear as Rhodium - or the same.
Kind Regards,
Knud Torbol
- Denmark
First of two simultaneous responses -- ++++++
Hello Knud,
It has been evident that a thicker Rh deposit will wear longer. As
far as specific wear cycle testing based on thickness plated, I don't
know of any tests conducted with conclusive results. It's hard to
define "wear". Is a farmer going to wear the ring, or a computer
programmer? The common Rh plated thickness in the jewelry industry
should be .05 - 1.5 micron. Being that Rh is so expensive the
thickness is usually on the lower part of the scale. A Rh plated
deposit is harder than Pt, so Rh would have better wear resistance.
If going over Ag I would plate no less than half a micron. Good Luck!
Mark Baker
Process Engineer - Syracuse, New York
Second of two simultaneous responses -- ++++++
Rhodium plating is usually in the neighborhood of .1 to .2 micron
and naturally thicker deposits will wear longer. Platinum and Rhodium
and similar metals and share many properties.
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It is extremely difficult to electroplate rhodium without stress
cracks. The silver migrates right through the cracks and the
corrosion eats away underneath. You have two choices. (1) Buy your
Rhodium Plating process from a vendor who has a stress reducer in the
formulation and keep the whole preparation process perfectly clean.
Or (2) put a difusion barrier between the silver and rhodium: use
paladium or nickel.
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Silver Rh plated jewelery it is giving problem later on, when Rh
comes off then it's difficult to strip Rh and undercoat is done by Ni
it's hard to make new brand. I'm doing this kind of stuff. I advice
to do clear coat which is best lasting longer.

Dipen Pattni
jeweler/goldsmith - Dar-Es-Salaam, Tanzania


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