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Letter 3022
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The coating is ZrCN applied by cathodic arc deposition. It is about 150 nm thick. The process is not proprietary, several companies are involved in making equipment. Vapor Technologies, owned by Masco which also owns Baldwin, uses patented deposition equipment. Masco also owns Delta Faucets, so if you want to coat door hardware or plumbing fixtures you can't work with Vapor Technologies, you have to go to Hauzer in Holland for the equipment. Goldstar is offering the coating on a toll basis. The coating does require a plated base, usually of electroless nickel.

Jim Treglio
- San Diego, California
Can anyone verify the coating is ZrCN and not TiN? TiN or Titanium Nitride coloring is another Physical Vapor Deposition (PVD)process for depositing a thin .3-1.0 micron ceramic "lifetime" coating. This coating is currently used in the signage industry as ti-gold. Brass or gold looking channel or dimensional letters that will withstand the weather elements. In my opinion PVD technology was developed by the Russians, perfected by the Japanese and now marketed by many. This is not a propietary technology. Sincerely, Michael Liu Taylor
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Michael Liu
Taylor |
TiN looks like gold and ZrN looks like brass. the basecoat is either electroplated nickel or nickel-chromium for corrosion protection and to seal in the zinc from the brass. PVD is also now being used apply nickel as a basecoat. The titanium nitride and carbonitride and other nitride and carbonitrides have been used as hard tool coatings for longer than they have been used as decorative/functional coatings. The coatings are either deposited by arc vapor deposition or sputter deposition. Don Mattox
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Mike, physical vapor deposition (PVD) is a broad term used for any method by which a material is converted to vapor and condensed on a part as a coating, including thermal spray. In another form called sputtering, the atoms are knocked out of a surface and deposited on another surface. In concept it is as simple as that but not in practice! Materials can be metals, alloys, polymers or ceramics. The process of vapor transport is easier in vacuum so most processes are conducted in vacuum. There are a dozen or so methods by which this vaporization is done. And cathodic arc (e.g. mercury arc lamp) is one of them which was accidently discovered when engineers saw metal being sprayed near contacts by arcing in vacuum switches. But Russians exploited it as a coating method in the 70s for the nuclear industry. Anyway, the TiN, TiCN, ZrCN, etc can be deposited by sputtering, ion-plating as well as cathodic arc (all PVDs). The cathodic arc is becoming more popular because of its simpler nature, I assume.
Mandar
Sunthankar
- Fort Collins, CO

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